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Voltammetric determination of norepinephrine in the presence of tryptophan using a modified carbon nanotube paste electrode

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Abstract

The redox responses of a carbon nanotube paste electrode modified with vinylferrocene was investigated. The mediated oxidation of norepinephrine at the surface of modified electrode was investigated by cyclic voltammetry (CV). Square wave voltammetry (SWV) of norepinephrine at the modified electrode exhibited two linear dynamic ranges with a detection limit of 4.0 × 10−8 M. The diffusion coefficient (D = 1.06 × 10−6 cm2 s−1) and the kinetic parameters such as the electron transfer coefficient (α = 0.38) for norepinephrine were determined using electrochemical approaches. SWV was used for simultaneous determination of norepinephrine and tryptophan at the modified electrode, and quantification of norepinephrine and tryptophan in some real samples by the standard addition method.

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Authors and Affiliations

  1. Department of Chemistry, Shahid Bahonar University of Kerman, P. O. Box 76175-133, Kerman, Iran

    Anis Hosseini & Mohammad Ali Taher

  2. Young Researchers Society, Shahid Bahonar University of Kerman, P. O. Box 76175-133, Kerman, Iran

    Anis Hosseini

  3. Environment Department, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran

    Hadi Beitollahi

Authors
  1. Anis Hosseini
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  2. Mohammad Ali Taher
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  3. Hadi Beitollahi
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Correspondence to Hadi Beitollahi.

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Hosseini, A., Taher, M.A. & Beitollahi, H. Voltammetric determination of norepinephrine in the presence of tryptophan using a modified carbon nanotube paste electrode. Res Chem Intermed 41, 5995–6007 (2015). https://doi.org/10.1007/s11164-014-1716-4

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  • DOI: https://doi.org/10.1007/s11164-014-1716-4

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