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Thermoluminescence study of ZnS:Cu nanoparticles

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Abstract

In this paper, we report on the TL glow curves and kinetic parameters, activation energy, order of kinetics, and the frequency factor of copper-doped zinc sulfide nanophosphor under UV irradiations. The sample was prepared by the chemical precipitation method; thereafter, the TL glow curves were recorded for different doses of UV exposure at a heating rate of 10 °C/s. The synthesized nanophosphor exhibited TL glow peaks at 241, 255, and 281 °C for the heating rate 10 °C/s at different doses of 5, 10, and 15 min of UV exposure. The kinetic parameters activation energy E, the order of kinetics b, and the frequency factor S of synthesized nanophosphor of ZnS:Cu have been calculated by using a peak shape method while the trap depth was determined using different formulae. The sample was characterized by XRD (X-ray diffraction) and SEM (scanning electron microscope).

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Acknowledgments

We are grateful to UGC for funding through a Minor Research Project. The XRD part of the paper is related to IUC Indore, and we are grateful to Dr. Mukul Gupta for his support.

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Correspondence to Vikas Dubey.

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Kaur, J., Dubey, V., Suryanarayana, N.S. et al. Thermoluminescence study of ZnS:Cu nanoparticles. Res Chem Intermed 39, 3895–3900 (2013). https://doi.org/10.1007/s11164-012-0905-2

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  • DOI: https://doi.org/10.1007/s11164-012-0905-2

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