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Synthesis and evaluation of some quinoline Schiff bases as a corrosion inhibitor for mild steel in 1 N HCl

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Abstract

N-((2-chloroquinolin-3-yl)methylene)aniline (CQM) and N-((2-chloroquinolin-3-yl)methylene)-5-methylthiazol-2-amine (CQMA) were synthesized. The effect of CQM and CQMA have been investigated against mild steel (MS) in 1 N HCl solutions using conventional weight loss, potentiodynamic polarization, linear polarization, electrochemical impedance spectroscopy, UV–Vis spectroscopy and scanning electron microscopic studies. The losses in the weights of MS samples have proved that both CQM and CQMA are efficient inhibitors. The mixed mode of inhibition was confirmed by electrochemical polarizations. The adsorptions of these inhibitors are found to follow the Langmuir adsorption isotherm. CQM and CQMA adsorbs on the MS sample by chemisorptions.

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References

  1. D.A. Jones, Principles and Prevention of Corrosion, 2nd edn. (Prentice-Hall Inc., Upper Saddle River, 1996)

    Google Scholar 

  2. V.S. Sastry, Corrosion Inhibitors. Principles and Applications (Wiley, New York, 1998)

    Google Scholar 

  3. F. Bentiss, M. Traisnel, M. Lagrenee, J. Appl. Electrochem. 31, 41 (2001)

    Article  CAS  Google Scholar 

  4. G. Schmitt, Br. Corros. J. 19, 165 (1984)

    CAS  Google Scholar 

  5. S. John, B. Joseph, K.V. Balakrishnan, K.K. Aravindakshan, A. Joseph, Mater. Chem. Phys. 123, 218 (2010)

    Article  CAS  Google Scholar 

  6. A.S. Fouda, H.A. Mostafa, H.M. El-Abbasy, J. Appl. Electrochem. 40, 163 (2010)

    Article  CAS  Google Scholar 

  7. M.J. Bahrami, S.M.A. Hosseini, P. Pilvar, Corros. Sci. 52, 2793 (2010)

    Article  CAS  Google Scholar 

  8. M.A. Quraishi, I. Ahamada, A. Singha, S. Shuklaa, B. Lal, V. Singh, Mater. Chem. Phys. 112, 1035 (2008)

    Article  CAS  Google Scholar 

  9. K.M. Govindaraju, D. Gopi, L. Kavitha, J. Appl. Electrochem. 39, 2345 (2009)

    Article  CAS  Google Scholar 

  10. R. Solmaza, E. Altunbas, G. Kardas, Mater. Chem. Phys. 125, 796 (2011)

    Article  Google Scholar 

  11. G. Trabanelli, in Chemical Industries: Corrosion Mechanism, ed. by F. Mansfeld (Marcel Dekker, New York, 1987), p. 120

    Google Scholar 

  12. I.B. Obot, N.O. Obi-Egbedi, Curr. Appl. Phys. 11, 382 (2011)

    Article  Google Scholar 

  13. S. Deng, X. Li, H. Fu, Corros. Sci. 53, 822 (2011)

    Article  CAS  Google Scholar 

  14. M.G. Hosseini, H. Khalilpur, S. Ershad, L. Saghatforoush, J. Appl. Electrochem. 40, 215 (2010)

    Article  CAS  Google Scholar 

  15. P. Xuehui, R. Xiangbin, K. Fei, X. Jiandong, H. Baorong, Chin. J. Chem. Eng. 18, 337 (2010)

    Article  Google Scholar 

  16. I. Ahamad, C. Gupta, R. Prasad, M.A. Quraishi, J. Appl. Electrochem. 40, 2171 (2010)

    Article  CAS  Google Scholar 

  17. M. Lashgaria, M. Arshadib, S. Miandaria, Electrochim. Acta. 55, 6058 (2010)

    Article  Google Scholar 

  18. D. Gopi, K.M. Govindaraju, L. Kavitha, J. Appl. Electrochem. 40, 1349 (2010)

    Article  CAS  Google Scholar 

  19. A. Yurt, G. Bereket, A. Kivrak, A. Balaban, B. Erk, J. Appl. Electrochem. 35, 1025 (2005)

    Article  CAS  Google Scholar 

  20. S. Bilgice, N. Cealiskan, J. Appl. Electrochem. 31, 79 (2001)

    Article  Google Scholar 

  21. E. Bayol, T. Gurtenb, A.A. Gurtena, M. Erbil, Mater. Chem. Phys. 112, 624 (2008)

    Article  CAS  Google Scholar 

  22. G.K. Nagaraja, G.K. Prakash, M.N. Kumaraswamy, V.P. Vaidya, K.M. Mahadevan, ARKIVOC xv, 160 (2006)

    Google Scholar 

  23. S.D. Srivastava, J.P. Sen, Indian J. Chem. 47B, 1583 (2008)

    CAS  Google Scholar 

  24. S.K. Sonwane, S.D. Srivastava, S.K. Srivastava, Indian J. Chem. 47B, 633 (2008)

    CAS  Google Scholar 

  25. E. Barsoukov, J.R. Macdonald, Impedance Spectroscopy; Theory, Experiment, and Applications, 2nd edn. (Wiley Interscience Publications, Hoboken, 2005)

    Book  Google Scholar 

  26. A.J. Bard, L.R. Faulkner, Electrochemical Methods; Fundamentals and Applications (Wiley Interscience Publications, New York, 2000)

    Google Scholar 

  27. J.R. Scully, D.C. Silverman, M.W. Kendig (eds.), Electrochemical Impedance: Analysis and Interpretation (ASTM, West Conshohocken, 1993)

    Google Scholar 

  28. F. Mansfeld, Electrochim. Acta. 35, 1533 (1990)

    Article  CAS  Google Scholar 

  29. S. Fletcher, J. Electrochem. Soc. 141, 1823 (1994)

    Article  CAS  Google Scholar 

  30. S. Zhang, Z. Tao, W. Li, B. Hou, Appl. Surf. Sci. 255, 6757 (2009)

    Article  CAS  Google Scholar 

  31. G.E. Badr, Corros. Sci. 51, 2529 (2009)

    Article  CAS  Google Scholar 

  32. E. McCafferty, N. Hackerman, J. Electrochem. Soc. 119, 146 (1972)

    Article  CAS  Google Scholar 

  33. C. Cao, Corros. Sci. 38, 2073 (1996)

    Article  CAS  Google Scholar 

  34. M. Lebrini, M. Lagrenee, H. Vezin, M. Traisnel, F. Bentiss, Corros. Sci. 49, 2254 (2007)

    Article  CAS  Google Scholar 

  35. M.El. Azhar, B. Mernari, M. Traisnel, F. Bentiss, M. Lagrenee, Corros. Sci. 43, 2229 (2001)

    Article  Google Scholar 

  36. A. Yurt, A. Balaban, S.U. Kandemir, G. Bereket, B. Erk, Mater. Chem. Phys. 85, 420 (2004)

    Article  CAS  Google Scholar 

  37. J.R. Macdonald, W.B. Johnson, in Theory in Impedance Spectroscopy, ed. by J.R. Macdonald (Wiley, New York, 1987)

    Google Scholar 

  38. O.L. Riggs Jr, in Corrosion Inhibitors, ed. by C.C. Nathan (NACE, Houston, 1973), p. 7

    Google Scholar 

  39. J. Fu, S. Li, Y. Wang, L. Cao, L. Lu, J. Mater. Sci. 45, 6255 (2010)

    Article  CAS  Google Scholar 

  40. S. Martinez, I. Stern, Appl. Surf. Sci. 199, 83 (2002)

    Article  CAS  Google Scholar 

  41. T. Szauer, A. Brand, Electrochim. Acta 26, 1253 (1981)

    Article  Google Scholar 

  42. J. Aljourani, K. Raeissi, M.A. Golozar, Corros. Sci. 51, 1836 (2009)

    Article  CAS  Google Scholar 

  43. F.M. Donahue, K. Nobe, J. Electrochem. Soc. 112, 886 (1965)

    Article  CAS  Google Scholar 

  44. E. Kamis, F. Bellucci, R.M. Latanision, E.S.H. El-Ashry, Corrosion 47, 677 (1991)

    Article  Google Scholar 

  45. B.M. Mistry, N.S. Patel, M.J. Patel, S. Jauhari, Res. Chem. Intermed. 37, 659 (2011)

    Article  CAS  Google Scholar 

  46. K. Mallaiyaa, R. Subramaniama, S.S. Srikandana, S. Gowria, N. Rajasekaranb, A. Selvaraj, Electrochim. Acta 56, 3857 (2011)

    Article  Google Scholar 

  47. X. Li, S. Deng, H. Fu, T. Li, Electrochim. Acta 54, 4089 (2009)

    Article  CAS  Google Scholar 

  48. T.P. Zhao, G.N. Mu, Corros. Sci. 41, 1937 (1999)

    Article  CAS  Google Scholar 

  49. F. Bentiss, M. Lebrini, M. Lagrenee, Corros. Sci. 47, 2915 (2005)

    Article  CAS  Google Scholar 

  50. E.A. Noor, A.H. Al-Moubaraki, Mater. Chem. Phys. 110, 145 (2008)

    Article  CAS  Google Scholar 

  51. R. Solmaz, G. Kardas, M. Culha, B. Yazici, M. Erbil, Electrochim. Acta 53, 5941 (2008)

    Article  CAS  Google Scholar 

  52. X. Li, S. Deng, H. Fu, G. Mu, Corros. Sci. 51, 620 (2009)

    Article  CAS  Google Scholar 

  53. F. Xu, J. Duan, S. Zhang, B. Hou, Mater. Lett. 62, 4072 (2008)

    Article  CAS  Google Scholar 

  54. Q.B. Zhang, Y.X. Hua, Electrochim. Acta 54, 1881 (2009)

    Article  CAS  Google Scholar 

  55. S.A. Abd El-Makoud, Appl. Surf. Sci. 206, 129 (2003)

    Article  Google Scholar 

  56. R. Solmaz, G. Kardas, B. Yazici, M. Erbil, Colloids Surf. A. 312, 7 (2008)

    Article  CAS  Google Scholar 

  57. H. Keles, M. Keles, I. Dehri, O. Serindag, Mater. Chem. Phys. 112, 173 (2008)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors thank Director, S V National Institute of Technology, Surat for encouragement and for providing necessary research facilities.

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Correspondence to Smita Jauhari.

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Mistry, B.M., Jauhari, S. Synthesis and evaluation of some quinoline Schiff bases as a corrosion inhibitor for mild steel in 1 N HCl. Res Chem Intermed 39, 1049–1068 (2013). https://doi.org/10.1007/s11164-012-0666-y

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