Abstract
A model of an atmospheric pressure nitrogen glow discharge in high-gas temperature regimes is developed. The model considers a fairly complete set of chemical reactions, including several processes with the participation of electronically exited nitrogen atoms describing the energy balance and charged particles kinetic processes in the discharge. It is shown that the thermal dissociation of vibrationally excited molecules plays an essential role in the production of N(4 S) atoms. The dominant ion within the investigated current range (52–187 mA) is the molecular N2 + with an increasing proportion of atomic N+ towards high-current values. The process of production of electrons within the almost whole current range is controlled predominantly by associative ionization in atomic collisions N(2 P) + N(2 P) → N2 + + e; being the N(2 P) atoms mainly produced via quenching of N2(A 3∑ +u ) electronically excited molecules by N(4 S) atoms. The results of calculations are compared with the available experimental data and a good agreement is found.
Similar content being viewed by others
References
Park GY, Park SJ, Choi MY, Koo IG, Byun JH, Hong JW, Sim JY, Collins GJ, Lee JK (2012) Plasma Sources Sci Technol 21:21
Fridman A, Chirokov A (2005) J Phys D Appl Phys 38:R1–R24
Kunhardt EE (2000) IEEE Trans Plasma Sci 28:189–200
Gambling WA, Edels H (1954) Br J Appl Phys 5:36–39
Machala Z, Marode E, Laux CO, Kruger CH (2004) J Adv Oxid Technol 7:133–137
Staack D, Farouk B, Gutsol A, Fridman A (2008) Plasma Sources Sci Technol 17:13
Verreycken T, Schram DC, Leys C, Bruggeman P (2010) Plasma Sources Sci Technol 19:9
Machala Z, Laux CO, Kruger CH (2005) IEEE Trans Plasma Sci 33:320–321
Staack D, Farouk B, Gutsol A, Fridman A (2005) Plasma Sources Sci Technol 14:700–711
Wilson A, Staack D, Farouk T, Gutsol A, Fridman A, Farouk B (2008) Plasma Sources Sci Technol 17:12
Prevosto L, Kelly H, Mancinelli B, Chamorro JC, Cejas E (2015) Phys Plasmas 22:8
Staack D, Farouk B, Gutsol A, Fridman A (2009) J Appl Phys 106:7
Bayle P, Bayle M, Forn G (1985) J Phys D Appl Phys 18:2395–2415
Hsu CC, Wu CY (2009) J Phys D Appl Phys 42:8
Akishev Yu, Goossens O, Callebaut T, Leys C, Napartovich A, Trushkin N (2001) J Phys D Appl Phys 34:2875–2882
Raizer YP (1991) Gas discharge physics. Springer, Berlin
Boeuf JP, Kunhardt EE (1986) J Appl Phys 60:915–923
Capitelli M, Ferreira CM, Gordiets BF, Osipov AI (2000) Plasma kinetics in atmospheric gases. Springer, New York
Velikhov EP, Golubev VS, Pashkin SV (1982) Sov Phys Usp 25:340–358
Eletskii AV, Smirnov BM (1996) Phys Usp 39:1137–1156
Akishev Y, Grushin M, Karalnik V, Petryakov A, Trushkin N (2010) J Phys D Appl Phys 43:11
Kruger CH, Laux CO, Yu L, Packan DM, Pierrot L (2002) Pure Appl Chem 74:337–347
Yu L, Laux CO, Packan DM, Kruger CH (2002) J Appl Phys 91:2678–2686
Yalin AP, Laux CO, Kruger CH, Zare RN (2003) Plasma Sources Sci Technol 11:248–253
Akishev Y, Grushin M, Karalnik V, Petryakov A, Trushkin N (2010) J Phys D Appl Phys 43:18
Pierrot L, Yu L, Gessman RJ, Laux CO, Kruger CH (1999) In: Proceedings of 30th AIAA plasmadynamics and lasers conference, AIAA 99-3478, Norfolk, VA
Hugill J, Saktioto T (2001) Plasma Sources Sci Technol 10:38–42
Saporoschenko M (1965) Phys Rev 139:352–356
Mehr FJ, Biondi MA (1969) Phys Rev 181:264–271
Lin CL, Kaufman F (1971) J Chem Phys 55:3760–3770
Naidis GV (2007) Plasma Sources Sci Technol 16:297–303
Kossyi IA, Kostinsky AY, Matveyev AA, Silakov VP (1992) Plasma Sources Sci Technol 1:207–220
Brunet H, RocaSerra J (1985) J Appl Phys 57:1574–1581
Guerra V, Sa PA, Loureiro J (2004) Eur Phys J Appl Phys 28:125–152
Hagelaar GJM, Pitchford LC (2005) Plasma Sources Sci. Technol. 14:722–733; freeware code BOLSIG+ version 07/2015. www.bolsig.laplace.univ-tlse.fr (2015)
SIGLO database, http://www.lxcat.laplace.univ-tlse.fr. Retrieved June 4, 2013
Macheret SO, Rich JW (1993) Chem Phys 174:25–43
Fridman AA, Kennedy LA (2004) Plasma physics and engineering. Taylor & Francis, London
Chernyi GG, Losev SA, Macheret SO, Potapkin BV (2002) Physical and chemical processes in gas dynamics: cross sections and rate constants, vol 1. AIAA, New York
da Silva ML, Guerra V, Loureiro J (2007) Chem Phys 342:275–287
Andre P, Abbaoui M, Lefort A, Parizet MJ (1996) Plasma Chem Plasma Process 16:379–397
Huber KP, Herzberg G (1979) Molecular spectra and molecular structure: IV constants of diatomic molecules. Springer, Berlin
D’Ammando G, Colonna G, Pietanza LD, Capitelli M (2010) Spectrochim Acta Part B 65:603–605
Bacri J, Medani A (1982) Phys C 112:101–118
Benilov MS, Naidis GV (2003) J Phys D Appl Phys 36:1834–1841
Boulos M, Fauchais P, Pfender E (1994) Thermal plasmas, fundamentals and applications, vol 1. Plenum Press, New York and London
Popov NA (2001) Plasma Phys Rep 27:886–896
Popov NA (2011) J Phys D Appl Phys 44:16
Mintoussov EI, Pendleton SJ, Gerbault FG, Popov NA, Starikovskaia SM (2011) J Phys D Appl Phys 44:13
Matveyev AA, Silakov VP (1999) Plasma Sources Sci Technol 8:162–178
Itikawa Y (2006) J Phys Chem Ref Data 35:31–53
Aleksandrov NL, Bazelyan EM, Kochetov IV, Dyatko NA (1997) J Phys D Appl Phys 30:1616–1624
Brunet H, Vincent P, RocaSerra J (1983) J Appl Phys 54:4951–4957
Cao YS, Johnsen R (1991) J Chem Phys 95:7356–7359
Bourdon A, Vervisch P (1996) Phys Rev E 54:1888–1898
Dunn MG, Lordi JA (1970) AIAA J. 8:339–345
Piper LG (1988) J Chem Phys 88:6911–6921
Hays GN, Oskam HJ (1973) J Chem Phys 59:1507–1516
Piper LG (1988) J Chem Phys 88:231–232
Clark WG, Setser DW (1980) J Chem Phys 84:2225–2233
Tatarova E, Dias FM, Gordiets B, Ferreyra CM (2005) Plasma Sources Sci Technol 14:19–31
Piper LG (1989) J Chem Phys 90:7087–7095
Heidner RF, Sutton DG, Suchard SN (1976) Chem Phys Lett 37:243–248
Piper LG (1987) J Chem Phys 87:1625–1629
Gordiets BF, Ferreira CM, Guerra VL, Loureiro JMAH, Nahorny J, Pagnon D, Touzeau M, Vialle M (1995) IEEE Trans Plasma Sci 23:750–768
Gordiets B, Ferreira CM, Pinheiro MJ, Ricard A (1998) Plasma Sources Sci Technol 7:363–378
Acknowledgments
This work was supported by Grants from the CONICET (PIP 11220120100453) and Universidad Tecnológica Nacional (PID 2264). L. P. and H. K. are members of the CONICET.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Prevosto, L., Kelly, H. & Mancinelli, B. Modelling of an Atmospheric Pressure Nitrogen Glow Discharge Operating in High-Gas Temperature Regimes. Plasma Chem Plasma Process 36, 973–992 (2016). https://doi.org/10.1007/s11090-016-9716-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11090-016-9716-3