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MBE growth of high quality AlInSb/GaSb compound buffer layers on GaAs substrates

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Abstract

The epitaxy properties of GaAs-based GaSb thin films were investigated under different growth conditions to identify suitable smooth areas on GaSb epilayer surface for growing high-quality AlInSb metamorphic buffers. The results showed notable reduction in threading dislocation densities (TDDs) and hillocks densities (HDs) of GaSb buffer layer when the temperature of substrates rising to Tc (surface reconstruction conversion temperature) + 110 °C and growth rate decreasing to 0.25 mono layer per second (ML/s). These conditions led to gradual changes in GaSb epilayer surface morphologies from tiny hillocks to near-parallel steps. The AlInSb/GaSb compound buffers were studied by employing five different structures of AlInSb metamorphic buffer layers grown on optimized GaSb layers, and then analyzed by various analytical methods. The influence of various structural buffer layers on defects were evaluated in order to suppress the formation of defects. It was shown that the buffer layer with low-temperature interface layer and superlattice structure presents obvious inhibitory effects on defects. Among these, specimens with superlattice interface exhibits the lowest TDDs of 3.1 × 107 cm−2 and moderate HDs of 2.4 × 107 cm−2.

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References

  • Blank, H.R., Thomas, M., Wong, K.C., Kroemer, H.: Influence of the buffer layers on the morphology and the transport properties in InAs/(Al, Ga)Sb quantum wells grown by molecular beam epitaxy. Appl. Phys. Lett. 69, 2080–2082 (1996). https://doi.org/10.1063/1.116886

    Article  ADS  Google Scholar 

  • Brar, B., Leonard, D.: Spiral growth of GaSb on (001) GaAs using molecular beam epitaxy. Appl. Phys. Lett. 66, 463–465 (1995). https://doi.org/10.1063/1.114057

    Article  ADS  Google Scholar 

  • Burton, W.K., Cabrera, N., Frank, F.C.: The growth of crystals and the equilibrium structure of their surfaces. Philos. Trans. R. Soc. 243(866), 299–358 (1951). https://doi.org/10.1098/rsta.1951.0006

    Article  ADS  MathSciNet  MATH  Google Scholar 

  • Dastjerdi, M.H.T., Boulanger, J.P., Kuyanov, P., et al.: Methods of Ga droplet consumption for improved GaAs nanowire solar cell efficiency. Nanotechnology. 27(47), 475403–475406 (2016)

    Article  Google Scholar 

  • Deng, Z., Chen, B., et al.: Optical properties of beryllium-doped GaSb epilayers grown on GaAs substrate. Infrared Phys. Technol. 90, 115–121 (2018)

    Article  ADS  Google Scholar 

  • Deng, Z., Guo, D., Huang, J., Liu, H., Wu, J., Chen, B.: Mid-wave infrared InAs/GaSb type-II superlattice photodetector with n-B-p design grown on GaAs substrate. IEEE J. Quantum Electron. 55(4), 1–5 (2019). https://doi.org/10.1109/jqe.2019.2917946

    Article  Google Scholar 

  • Grandjean, N., Massies, J.: Epitaxial growth of highly strained InxGa1-xAs on GaAs(001): the role of surface diffusion length. J. Cryst. Growth 134(1–2), 51–62 (1993). https://doi.org/10.1016/0022-0248(93)90008-K

    Article  ADS  Google Scholar 

  • Heremans, J.: Solid state magnetic field sensors and applications. J. Phys. D Appl. Phys. 26(8), 1149–1151 (1999)

    Article  ADS  Google Scholar 

  • Kasturiarachchi, T., Brown, F., Dai, N., Khodaparast, G.A., Doezema, R.E., Goel, N.: Exciton determination of strain parameters in InSb/Al1−xInxSb quantum wells. J. Vac. Sci. Technol. B Microelectron. Nanometer Struct. 24(5), 2429–2431 (2006). https://doi.org/10.1116/1.2348885

    Article  ADS  Google Scholar 

  • Korkmaz, M., Arikan, B., Suyolcu, Y.E., et al.: Performance evaluation of InAs/GaSb superlattice photodetector grown on GaAs substrate using AlSb interfacial misfit array. Semicond. Sci. Technol. 33(3), 035002–035004 (2018)

    Article  ADS  Google Scholar 

  • Kunets, V.P., Black, W.T., Mazur, Y.I., Guzun, D., Santos, M.B.: Highly sensitive micro-Hall devices based on Al0.12In0.88Sb/InSb heterostructures. J. Appl. Phys. 98, 014506–014508 (2005)

    Article  ADS  Google Scholar 

  • Lehner, C.A., Tschirky, T., Ihn, T., Dietsche, W., Keller, J., Fält, S.: Limiting scattering processes in high-mobility InSb quantum wells grown on GaSb buffer systems. Phys. Rev. Mater. 2, 054601–054604 (2018)

    Article  Google Scholar 

  • Li, X., Du, Q., Héroux, J.B., Wang, W.I.: n-channel AlSbGaSb modulationdoped field-effect transistors. Solid State Electron. 41, 1853–1856 (1997)

    Article  ADS  Google Scholar 

  • Liu, W.K.: Molecular-beam epitaxial growth and characterization of Al1-xInxSb/InSb quantum well structures. J. Vac. Sci. Technol., B 14(3), 2339–2342 (1996)

    Article  MathSciNet  Google Scholar 

  • McIndo, C.J., Hayes, D.G., Papageorgiou, A., Hanks, L.A., Smith, G.V., Allford, C.P.: Optical microscopy as a probe of the rate limiting transport lifetime in InSb/Al1-xInxSb quantum wells. J. Phys: Conf. Ser. 964, 012005–012007 (2018)

    Google Scholar 

  • Meyer, R.C., Zhang, X.H., Kasturiarachchi, T., Khodaparast, G.A., Doezema, R.E., Chung, S.J.: Spin dependent magneto-optical properties of InSb quantum wells. APS Meet. Am. 3, 3–7 (2003)

    Google Scholar 

  • Min, X.: Structure and Properties of GaAs-Based InSb Films by Molecular Beam Epitaxy. Doctoral dissertation. Harbin Institute of Technology. Harbin (2006) (in Chinese)

  • Pooley, O.J., Gilbertson, A.M., Buckle, P.D., Hall, R.S., Emeny, M.T., Fearn, M.: Quantum well mobility and the effect of gate dielectrics in remote doped InSb/Al1-xInxSb heterostructures. Semicond. Sci. Technol. 25(12), 125005–125011 (2010)

    Article  ADS  Google Scholar 

  • Pour, S.A., Huang, E.K., Chen, G., Haddadi, A., Nguyen, B.-M., Razeghi, M.: High operating temperature midwave infrared photodiodes and focal plane arrays based on type-II InAs/GaSb superlattices. Appl. Phys. Lett. 98, 143501–143504 (2011)

    Article  ADS  Google Scholar 

  • Sato, T., Akabori, M., Yamada, S.: High-quality highly mismatched InSb films grown on GaAs substrate via thick AlSb and Al1-xInxSb step-graded buffers. Physica E Low Dimens. Syst. Nanostruct. 21(2–4), 615–619 (2004). https://doi.org/10.1016/j.physe.2003.11.088

    Article  ADS  Google Scholar 

  • Shi, Y., Gosselink, D., Gharavi, K., Baugh, J., Wasilewski, Z.: Optimization of Metamorphic Buffers for Molecular Epitaxial Growth of High Quality AlInSb/InSb Quantum Structures. In: North American Molecular Beam Epitaxy. APS March Meeting (2016). https://doi.org/10.1063/1.325238

  • Shi, Y., Gosselink, D., Gharavi, K., Baugh, J., Wasilewski, Z.R.: Optimization of metamorphic buffers for MBE growth of high quality AlInSb/InSb quantum structures: suppression of hillock formation. J. Cryst. Growth 477, 7–11 (2017). https://doi.org/10.1016/j.jcrysgro.2017.03.043

    Article  ADS  Google Scholar 

  • Wei-Da, H., Qing, L., Shuang-Xiao, C.: Recent progress on advanced infrared photodetectors. J. Phys. 68(12), 7–41 (2019)

    Google Scholar 

  • Weng, X., Goldman, R.S., Partin, D.L., Heremans, J.P.: Evolution of structural and electronic properties of highly mismatched InSb films. J. Appl. Phys. 88, 6276–6286 (2000). https://doi.org/10.1063/1.1324702

    Article  ADS  Google Scholar 

  • Weng, X., Rudawski, N.G., Wang, P.T., Goldman, R.S., Partin, D.L., Heremans, J.: Effects of buffer layers on the structural and electronic properties of InSb films. J. Appl. Phys. 97, 043713–043716 (2005). https://doi.org/10.1063/1.1841466

    Article  ADS  Google Scholar 

  • Wu, Y., Yang, P.: Direct observation of vapor–liquid–solid nanowire growth. J. Am. Chem. Soc. 123(13), 3165–3166 (2001)

    Article  Google Scholar 

  • Zhao, S., Connie, A.T., Dastjerdi, M.H.T., et al.: Aluminum nitride nanowire light emitting diodes: breaking the fundamental bottleneck of deep ultraviolet light sources. Sci. Rep. 5, 8332–8335 (2015)

    Article  Google Scholar 

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Acknowledgements

This study was supported by the National Natural Science Foundation of China (No. 61774130, 11474248, 61534008, 61790581), and the Ph.D. Programs Foundation of Ministry of Education of China (No. 20105303120002), National Key Technologies R&D Program of China 2018YFA0209101.

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Correspondence to Ruiting Hao, Jie Guo or Guowei Wang.

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Li, Y., Li, X., Hao, R. et al. MBE growth of high quality AlInSb/GaSb compound buffer layers on GaAs substrates. Opt Quant Electron 52, 138 (2020). https://doi.org/10.1007/s11082-020-2247-4

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