Skip to main content
Log in

Nanometric core-shell-shell γ-Fe2O3/SiO2/TiO2 particles

  • Brief Communication
  • Published:
Journal of Nanoparticle Research Aims and scope Submit manuscript

Abstract

The preparation of core-shell-shell γ-Fe2O3/SiO2/TiO2 nanoparticles of few tens nanometers is performed by successively coating onto magnetic nanoparticles a SiO2 layer and a TiO2 layer, using sol–gel methods. The thickness of the two layers and the aggregation state of the particles can be controlled by the experimental conditions used for the two coatings. These composite nanoparticles may find application as magnetic photocatalysts, since they are characterized by their small diameters which allow a good accessibility to the TiO2 shell.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme 1
Fig 1
Fig 2
Fig 3

References

  • Bacri J-C, Perzynski R, Salin D, Cabuil V, Massart R (1986) Magnetic colloidal properties of ionic ferrofluids. J Magn Magn Mater 62:36–46. doi:10.1016/0304-8853(86)90731-6

    Article  ADS  CAS  Google Scholar 

  • Bacri J-C, Perzynski R, Salin D, Cabuil V, Massart R (1990) Ionic ferrofluids: a crossing of chemistry and physics. J Magn Magn Mater 85:27–32. doi:10.1016/0304-8853(90)90010-N

    Article  ADS  CAS  Google Scholar 

  • Barringer EA, Bowen HK (1985) High-purity, monodisperse TiO2 powders by hydrolysis of titanium tetraethoxide. 2. Aqueous interfacial electrochemistry and dispersion stability. Langmuir 1:420–428. doi:10.1021/la00064a006

    Article  CAS  Google Scholar 

  • Beydoun D, Amal R, Low GKC, Mc Evoy S (2000) Novel photocatalyst: titania-coated magnetite. Activity and photodissolution. J Phys Chem B 104:4387–4396. doi:10.1021/jp992088c

    Article  CAS  Google Scholar 

  • Beydoun D, Amal R, Low G, Mac Evoy S (2002) Occurrence and prevention of photodissolution at the phase junction of magnetite and titanium dioxide. J Mol Catal A 180:193–200. doi:10.1016/S1381-1169(01)00429-0

    Article  CAS  Google Scholar 

  • Brock T, Groteklaes M, Mischke P (2002) Titanium dioxide pigments. Eur Coat J 92–94.

  • Charlot G (1966) Les méthodes de la chimie analytique (Ch. 52). Masson et Cie, Paris.

  • Fu W, Yang H, Li M, Li M, Yang N, Zou G (2005) Anatase TiO2 nanolayer coating on cobalt ferrite nanoparticles for magnetic photocatalyst. Mater Lett 59:3530–3534. doi:10.1016/j.matlet.2005.06.071

    Article  CAS  Google Scholar 

  • Guo X-C, Dong P (1999) Multistep coating of thick titania layers on monodisperse silica nanospheres. Langmuir 15:5535–5540. doi:10.1021/la990220u

    Article  CAS  Google Scholar 

  • Hanprasopwattana A, Srinivasan S, Sault AG, Datye AK (1996) Titania coatings on monodisperse silica spheres (characterization using 2-propanol dehydration and TEM). Langmuir 12:3173–3179. doi:10.1021/la950808a

    Article  CAS  Google Scholar 

  • Hoffmann MR, Martin ST, Choi W, Bahnemann DW (1995) Environmental applications of semiconductor photocatalysis. Chem Rev 95:69–96. doi:10.1021/cr00033a004

    Article  CAS  Google Scholar 

  • Holgado M, Cintas A, Ibisate M, Serna CJ, Lopez C, Meseguer F (2000) Three-dimensional arrays formed by monodisperse TiO2 coated on SiO2 spheres. J Colloid Interface Sci 229:6–11. doi:10.1006/jcis.2000.6973

    Article  PubMed  CAS  Google Scholar 

  • Iler RK (1979) The chemistry of silica (Ch 3), 1st edn. Wiley VCH, New York

  • Jean JH, Ring TA (1986) Nucleation and growth of monosized TiO2 powders from alcohol solution. Langmuir 2:251–255. doi:10.1021/la00068a025

    Article  CAS  Google Scholar 

  • Jeong U, Teng X, Wang Y, Yang H, Xia Y (2007) Superparamagnetic colloids: controlled synthesis and niche applications. Adv Mater 19:33–60.

    Article  CAS  Google Scholar 

  • Lee S-W, Drwiega J, Wu C-Y, Mazyck D, Sigmund WM (2004) Anatase TiO2 nanoparticle coating on barium ferrite using titanium bis-ammonium lactato dihydroxide and its use as a magnetic photocatalyst. Chem Mater 16:1160–1164. doi:10.1021/cm0351902

    Article  CAS  Google Scholar 

  • Lee S-W, Drwiega J, Mazyck D, Wu C-Y, Sigmund WM (2006) Synthesis and characterization of hard magnetic composite photocatalyst-Barium ferrite/silica/titania. Mater Chem Phys 96:483–488. doi:10.1016/j.matchemphys.2005.07.039

    Article  CAS  Google Scholar 

  • Li Y, Wu J, Qi D, Xu X, Deng C, Yang P, et al. (2008) Novel approach for the synthesis of Fe3O4@TiO2 core-shell microspheres and their application to the highly specific capture of phosphopeptides for MALDI-TOF MS analysis. Chem Commun (Camb) 564–566. doi:10.1039/b716055k

  • Lu A-H, Slabas EL, Schüth F (2007) Magnetic nanoparticles: synthesis, protection, functionalization, and application. Angew Chem Int Ed 46:1222–1244. doi:10.1002/anie.200602866

    Article  CAS  Google Scholar 

  • Marutini E, Yamamoto S, Ninjbadgar T, Tsuji Y, Fukuda T, Takano M (2004) Surface-initiated atom transfer radical polymerization of methyl methacrylate on magnetite nanoparticles. Polymer (Guildf) 45:2231–2335. doi:10.1016/j.polymer.2004.02.005

    Article  Google Scholar 

  • Massart R (1981) Preparation of aqueous magnetic liquids in alkaline and acidic media. IEEE Trans Magn 17:1247–1248. doi:10.1109/TMAG.1981.1061188

    Article  ADS  Google Scholar 

  • Mori S, Yanagida S (2006) TiO2-based dye-sensitized solar cell. In: Soga T (ed) Nanostructured materials for solar energy conversion. Elsevier, Amsterdam

    Google Scholar 

  • Philipse AP, Van Bruggen MPB, Pathmamanoharan C (1994) Magnetic silica dispersions—preparation and stability of surface-modified silica particles with a magnetic core. Langmuir 10:92–99. doi:10.1021/la00013a014

    Article  CAS  Google Scholar 

  • Scolan E, Sanchez C (1998) Synthesis and characterization of surface-protected nanocrystalline titania particles. Chem Mater 10:3217–3223. doi:10.1021/cm980322q

    Article  CAS  Google Scholar 

  • Shchukin DG, Kulak AI, Sviridov DV (2002) Magnetic photocatalysts of the core-shell type. Photochem Photobiol Sci 1:742–744. doi:10.1039/b207477j

    Article  PubMed  CAS  Google Scholar 

  • Tartaj P, Serna CJ (2003) Synthesis of monodisperse superparamagnetic Fe/silica nanospherical composites. J Am Chem Soc 125:15754–15755. doi:10.1021/ja0380594

    Article  PubMed  CAS  Google Scholar 

  • Vestal CR, Zhang ZJ (2002) Atom transfer radical polymerization synthesis and magnetic characterization of MnFe2O4/polystyrene core/shell nanoparticles. J Am Chem Soc 124:14312–14313. doi:10.1021/ja0274709

    Article  PubMed  CAS  Google Scholar 

  • Wan SR, Zheng Y, Liu YQ, Yan HS, Liu KL (2005) Fe3O4 nanoparticles coated with homopolymers of glycerol mono(meth) acrylate and their block copolymers. J Mater Chem 15:3424–3430. doi:10.1039/b504607f

    Article  CAS  Google Scholar 

  • Watson S, Beydoun D, Amal R (2002) Synthesis of a novel magnetic photocatalyst by direct deposition of nanosized TiO2 crystals onto a magnetic core. J Photochem Photobiol A 148:303–313. doi:10.1016/S1010-6030(02)00057-6

    Article  CAS  Google Scholar 

  • Xiao H-M, Liu X-M, Fu S-Y (2006) Synthesis, magnetic and microwave adsorbing properties of core-shell structured MnFe2O4/TiO2 nanocomposites. Compos Sci Technol 66:2003–2008. doi:10.1016/j.compscitech.2006.01.001

    Article  CAS  Google Scholar 

  • Xu S, Shangguan W, Yuan J, Chen M, Shi J, Jiang Z (2008) Synthesis and performance of novel magnetically separable nanospheres of titanium dioxide photocatalyst with egg-like structure. Nanotechnology 19:095606. doi:10.1088/0957-4484/19/9/095606

    Article  ADS  Google Scholar 

  • Yi DK, Selvan ST, Lee SS, Papaefthymiou GC, Kundaliya D, Ying JY (2005) Silica-coated nanocomposites of magnetic nanoparticles and quantum dots. J Am Chem Soc 127:4990–4991. doi:10.1021/ja0428863

    Article  PubMed  CAS  Google Scholar 

Download references

Acknowledgment

The authors acknowledge Olivier Sandre for fruitful discussions, and Delphine Talbot and Aude Michel for technical support.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sébastien Abramson.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Cite this article

Abramson, S., Srithammavanh, L., Siaugue, JM. et al. Nanometric core-shell-shell γ-Fe2O3/SiO2/TiO2 particles. J Nanopart Res 11, 459–465 (2009). https://doi.org/10.1007/s11051-008-9484-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11051-008-9484-y

Keywords

Navigation