Abstract
The reactivity of chlorohydrocarbons with different electron affinities (A e) and C-Cl bond dissociation energies (E C-Cl) in the oxidation of copper(I) chloride complexes was studied. The rate of oxidation depends only on Ae. Chain initiation, involving Cu(I), occurs by an electron-transfer mechanism.
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Translated from Kinetika i Kataliz, Vol. 46, No. 1, 2005, pp. 59–63.
Original Russian Text Copyright © 2005 by Kharitonov, Golubeva.
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Kharitonov, D.N., Golubeva, E.N. Mechanism of one-electron reactions of copper(I) chloride complexes with chlorohydrocarbons. Kinet Catal 46, 52–55 (2005). https://doi.org/10.1007/s10975-005-0041-8
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DOI: https://doi.org/10.1007/s10975-005-0041-8