Abstract
Ammonium nitrate (AN) has been extensively used as an oxidizer in energetic compositions, and is a promising compound as a propellant and gas generator. It is well-known that metal oxides help to address some of the disadvantages of AN, such as low stability and a low burning rate in these applications. In order to investigate the effects of copper(II) oxide (CuO) on the thermal decompostion of AN mixtures, the thermal characteristics of AN, carbon, and CuO mixtures were measured using simultaneous differential scanning calorimetry and thermogravimetry–differential thermal analysis connected with infrared spectroscopy and mass spectrometry. As a combustible material, activated carbon (AC), and carbon black (CB) were used in this study. In the TG–DTA results for AN/AC/CuO and AN/CB/CuO mixtures in an open cell, an exotherm was observed at approximately 210 and 230 °C, respectively. In addition, the IR and mass spectra of the gases produced from the AN/AC/CuO and AN/CB/CuO mixtures indicated the presence of CO2. Notably, the effect of CuO addition on the oxidation of the AN/AC/CuO mixture was different from that on the AN/CB/CuO mixture; the oxidation of AC shifted to a lower temperature, while the oxidation of CB shifted to a higher temperature. These results suggest that the effect of CuO on the oxidation of different types of carbon depends on the chemical reactivity of the carbon, which is derived from its physical properties.
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References
Oxley JC, Smith JL, Wang W. Compatibility of ammonium nitrate with monomolecular explosives. Part II Nitroarenes. J Phys Chem. 1994;98:3901–7.
Brower KR, Oxley JC, Tewari MP. Evidence for homolytic decomposition of ammonium nitrate at high temperature. J Phys Chem. 1989;93:4029–33.
Oommen C, Jain SR. Ammonium nitrate: a promising rocket propellant oxidizer. J Hazard Mater. 1999;67:253–81.
Brill TB, Brush PJ, Patil DG. Thermal decomposition of energetic materials 58. Chemistry of ammonium nitrate and ammonium dinitramide near the burning surface temperature. Combust Flame. 1993;92:178–86.
Vyazovkin S, Clawson JS, Wight CA. Thermal dissociation kinetics of solid and liquid ammonium nitrate. Chem Mater. 2001;13:960–6.
Klimova I, Kaljuvee T, Türn L, Bender V, Trikkel A, Kuusik R. Interactions of ammonium nitrate with different additives. J Therm Anal Calorim. 2011;105:13–26.
Sinditskii VP, Egorshev VY, Levshenkov AI, Serushkin VV. Ammonium nitrate: combustion mechanism and the role of additives. Propellants Explos Pyrotech. 2005;30:269–80.
Wada Y, Arai M. A study on ammonium nitrate-metal nitrate double salts as oxidizers for gas generating agent. Sci Technol Energ Mater. 2010;71:39–43.
Miyata Y, Hasue K. Burning characteristics of aminoguanidinium 5,5′-azobis- 1H tetrazolate/ammonium nitrate mixture-effects of particle size and composition ratio on burning rate. J Energ Mater. 2011;29:344–59.
Kohga M, Okamoto K. Thermal decomposition behaviors and burning characteristics of ammonium nitrate/polytetrahydrofuran/glycerin composite propellant. Combust Flame. 2011;158:578–82.
Nakamura H, Saeki K, Akiyoshi M, Takahasi K. The reaction of ammonium nitrate with carbon powder. J Jpn Explos Soc. 2002;63:87–93.
Pandey M, Jha S, Kumar R, Mishra S, Jha RR. The pressure effect study on the burning rate of ammonium nitrate–HTPB-based propellant with the influence catalysts. J Therm Anal Calorim. 2012;107:135–40.
Canterberry JB, Schlueter SS, Adams JH, Walsh RK. Gas generating compositions containing phase stabilized ammonium nitrate. USPatent 6,019,861 A. 2000.
Deimling A, Engel W, Eisenreich N. Phase transitions of ammonium nitrate doped with alkali nitrates studied with fast X-ray diffraction. J Therm Anal Cal. 1992;38:843–53.
Sudhakar AOR, Mathew S. Thermal behaviour of CuO doped phase-stabilised ammonium nitrate. Thermochim Acta. 2006;451:5–9.
Izato Y, Miyake A, Echigoya H. Influence of the physical properties of carbon on the thermal decomposition behavior of ammonium nitrate and carbon mixtures. Sci Technol Energ Mater. 2009;70:101–4.
Miyake A, Izato Y. Thermal decomposition behaviors of ammonium nitrate and carbon mixtures. Int J Energ Mater Chem Prop. 2010;9:467–75.
Donnet JB. Structure and reactivity of carbons: from carbon black to carbon composites. Carbon. 1982;20:267–82.
Morozov IV, Fedorova AA, Knotko AV, Valedinskaja OR, Kemnitz E. Mixed 3d-metal oxides prepared using molten ammonium nitrate. Mendeleev Commun. 2004;14:138–9.
Dyukarey SS, Morozov IV, Reshetova LN, Guz’ OV, Arkhangel’skii IV, Korenev YM, Spiridonov FM. Copper(II) nitrate ammoniates Cu(NH3)4(NO3)2 and Cu(NH3)2(NO3)2 and their thermolysis under reduced pressure. Russ J Inorg Chem. 1999;44:883–8.
Southern TM, Wendlandt WW. The thermal decomposition of metal complexes—XX: some amine copper(II) nitrate complexes. J Inorg Nucl Chem. 1970;32:3783–92.
Friedel RA, Shultz JL, Sharkey AG. Mass spectrum of nitric acid. Anal Chem. 1959;31:1128.
NIST Chemistry Webbook Standard Reference Database. 2005:69.
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Kajiyama, K., Izato, Yi. & Miyake, A. Thermal characteristics of ammonium nitrate, carbon, and copper(II) oxide mixtures. J Therm Anal Calorim 113, 1475–1480 (2013). https://doi.org/10.1007/s10973-013-3201-5
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DOI: https://doi.org/10.1007/s10973-013-3201-5