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Preparation and separation properties of porous norbornane-bridged silica membrane

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Abstract

Bis(trimethoxysilyl)norbornane (BTMSN) bearing a highly rigid norbornane bridge was employed as a new silica membrane precursor. The membrane prepared by subjecting BTMSN to the sol–gel process was examined for gas and water separation, and the results were compared with those of ethylene- and ethenylene-bridged silica membranes reported previously. Interestingly, the gas permeability of the BTMSN silica membrane was higher than that of the ethylene- and ethenylene-bridged silica membranes, whereas the water permeability was rather suppressed. The moderately high H2/SF6 permeance ratio of 1,160 and the NaCl rejection of 95 % (2,000 ppm aqueous NaCl) obtained for the BTMSN silica membrane clearly indicate its potential application to gas and water separation.

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Acknowledgments

This research was supported by Core Research for Evolutionary Science and Technology (CREST), Japan Science and Technology Agency (JST).

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Authors and Affiliations

  1. Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima, 739-8527, Japan

    Joji Ohshita, Haruna Muragishi, Kazuki Yamamoto & Tomonobu Mizumo

  2. Department of Chemical Engineering, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima, 739-8527, Japan

    Masakoto Kanezashi & Toshinori Tsuru

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  1. Joji Ohshita
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  2. Haruna Muragishi
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  3. Kazuki Yamamoto
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  4. Tomonobu Mizumo
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  5. Masakoto Kanezashi
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  6. Toshinori Tsuru
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Correspondence to Joji Ohshita or Toshinori Tsuru.

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Ohshita, J., Muragishi, H., Yamamoto, K. et al. Preparation and separation properties of porous norbornane-bridged silica membrane. J Sol-Gel Sci Technol 73, 365–370 (2015). https://doi.org/10.1007/s10971-014-3542-y

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  • DOI: https://doi.org/10.1007/s10971-014-3542-y

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