Skip to main content
Log in

Separation of 109Cd impurity from a decayed 110m/108mAg source

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

In this present work, 109Cd impurity from a decayed 110m/108mAg source has been separated by cloud point extraction using Triton X-114 + APDC. ~ 80% of 108mAg was extracted in the surfactant rich phase using 5% v/v TX-114 + 0.1 M APDC, without any interference of 109Cd impurity at pH 1.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Samaddar P, Sen K (2014) Cloud point extraction: A sustainable method of elemental preconcentration and speciation. J Indust Engg Chem 20:1209–1219

    Article  CAS  Google Scholar 

  2. Mandal S, Lahiri S (2013) Cloud point extraction of 99Mo with Triton x–114. J Radioanal Nucl Chem 295:1361–1364

    Article  CAS  Google Scholar 

  3. Hansen HJ, Grosell M, Jacobsen UL, Jørgensen JC, Hogstrand C, Wood CM (2002) Precautions in the use of 110mAg as a tracer of silver metabolism in ecotoxicology: preferential bioconcentration of 109Cd by trout gills after 110mAg exposure. Environ Toxicol Chem: An International J 21:1004–1008

    Article  CAS  Google Scholar 

  4. Goetz L, Sabbioni E, Marafante E, Birattari C, Bonardi M (1980) Cyclotron production of 107,109Cd for use in metallobiochemistry of heavy metal pollution. Radiochem Radioanal Lett 45:51

    CAS  Google Scholar 

  5. Aardaneh K, Naidoo C, Steyn GF (2008) Radiochemical separation of 109Cd from a silver target. J Radioanal Nucl Chem 276:831

    Article  CAS  Google Scholar 

  6. Sadeghi M, Karami H, Sarabadani P, Bolourinovin F (2009) Separation of the no-carrier-added 109Cd from Ag, Cu and 65Zn by use of a precipitation and AG1-X8 resin. J Radioanal Nucl Chem 281:619–623

    Article  CAS  Google Scholar 

  7. Sadeghi M, Karami H, Sarabandi P, Mirzaee M (2009) Separation of 109Cd from silver targets by nanohematite. Radiochim Acta 97:733–738

    Article  CAS  Google Scholar 

  8. Sadeghi M, Mirazaee M, Gholamzadeh Z, Karimian A, Novin FB (2009) Targetry and radiochemistry for no-carrier-added production of 109Cd. Radiochim Acta 97:113–116

    CAS  Google Scholar 

  9. Sadeghi M, Sarabadani P, Karami H (2010) Synthesis of maghemite nano-particles and its application as radionuclidic adsorbant to purify 109Cd radionuclide. J Radioanal Nucl Chem 283:297–303

    Article  CAS  Google Scholar 

  10. Sadeghi M, Mirzaii M, Gholamzadeh Z, Sarabadani P, Sattari A (2010) High cadmium-109 recovery from a dissolved silver target solution using Dowex 1×8 anion-exchange resin. Radiochem 52:565–569

    Article  CAS  Google Scholar 

  11. Ineza C, Naidoo C, Vermeulen C, Mphahlele J (2014) The production of 103Pd and 109Cd from a proton irradiated tandem natAg/natAg targets. J Radioanal Nucl Chem 301:227–236

    Article  CAS  Google Scholar 

  12. Das MK, Das SS, Alam M, Chattopadhyay S, Barua L (2014) 109Cd production in cyclotron by proton irradiation of natural silver target and separation of 109Cd from the irradiated target. In Proc. of the 3rd Int. Conf. Appl. Radiotracers and Energetic Beams in Sci. (ARCEBS-14), V. 4, Kolkata, India; Jan 12–18, 2014.

  13. Mengatti J, Sgambatti EM, Sumiya JB, Sciani V, Osso Junior JA (1992) Chemical separation of Cd-109 and silver when irradiated by cyclotron protons. https://inis.iaea.org/search/search.aspx?orig_q=RN:23077908

  14. Egamediev S, Mukhtarov A, Nurbaeva D, Rakhmanov A. (2006) Radiochemical separation of cadmium-109. 6th Int. Conf. Modern Problems of Nucl. Phys. Sept 19–22, https://inis.iaea.org/collection/NCLCollectionStore/_Public/37/122/37122127.pdf

  15. Akama Y, Ito M, Tanaka S (2000) Selective separation of cadmium from cobalt, copper, iron (III) and zinc by water-based two-phase system of tetrabutylammonium bromide. Talanta 53:645–650

    Article  CAS  Google Scholar 

  16. Gholamzadeh Z, Sadeghi M, Mirzaei M, Aref M (2011) Novel method to produce 109Cd via proton irradiation of electroplated silver on a gold-coated copper backing. Kerntechnik 76:273–276

    Article  CAS  Google Scholar 

  17. Kornilov AS, Chernookaya EV, Romanov EG, Abdullov RG (2019) Isolation of 109Cd from irradiated 107Ag. Radiochem 61:207–210

    Article  CAS  Google Scholar 

  18. Maiti M, Ghosh K, Lahiri S (2013) Simultaneous production and separation of no-carrier-added 111In, 109Cd from alpha particle induced silver target. J Radioanal Nucl Chem 295:1945–1950

    Article  CAS  Google Scholar 

  19. Ghosh K, Maiti M, Lahiri S (2013) Separation of no-carrier-added 109Cd from natural silver target using RTIL 1-butyl-3-methylimidazolium hexafluorophosphate. J Radioanal Nucl Chem 298:1049–1054

    Article  CAS  Google Scholar 

  20. Ghosh K, Maiti M, Lahiri S, Hussain VA (2014) Ionic liquid-salt based aqueous biphasic system for separation of 109Cd from silver target. J Radional Nucl Chem 302:925–930

    Article  CAS  Google Scholar 

  21. Lahiri S, Maiti M, Ghosh K (2015) Separation of no-carrier-added 111In and 109Cd from a-particle induced Ag target using glass wool surface. J Radioanal Nucl Chem 306:469–475

    Article  CAS  Google Scholar 

  22. Kazi TG, Afridi HI, Shah F, Arain SS, Brahman KD, Ali J, Arain MS (2016) Simultaneous determination of silver and other heavy metals in aquatic environment receiving wastewater from industrial area, applying an enrichment method. Arabian J Chem 9:105–113

    Article  Google Scholar 

  23. Peng W, Yunchang Z, Xiandeng H (2006) Cloud point extraction thermo spray flame quartz furnace atomic absorption spectrometry for determination of ultratrace cadmium in water and urine. Spectrochim Acta Part B: At Spectros 61:1310–1314

    Article  Google Scholar 

  24. Subramanian KS, Mérenger JC (1980) Stability of tetramethylenedithiocarbamate chelates in the 4-methyl penta n -2-one phase after extraction from an aqueous phase. Analyst 105:620–624

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Susanta Lahiri.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mandal, S., Naskar, N., Mandal, A. et al. Separation of 109Cd impurity from a decayed 110m/108mAg source. J Radioanal Nucl Chem 330, 1281–1284 (2021). https://doi.org/10.1007/s10967-021-08037-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-021-08037-8

Keywords

Navigation