Skip to main content
Log in

Ban the beauty in trace element laboratories: contamination risks of eye shadow

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Brazilian and Chinese eye shadow powders were evaluated for assessing the cosmetics as a source of contamination during sample preparation of biological materials. Nineteen chemical elements were measured by INAA. Highest mass fractions measured were for Ba (~ 2.5%), Cr (~ 1%), Fe (~ 45%), Na (~ 10%) and Sn (~ 1). It was experimentally verified that more than 0.01 mg of eye shadow may drop off and as such may be a potential source of contamination, causing high relative errors depending on the type of biological matrices and chemical element considered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1

Similar content being viewed by others

References

  1. Versieck A, Cornelis R (1989) Trace elements in human plasma and serum. CRC Press, Boca Raton

    Google Scholar 

  2. Draelos ZD (2001) Special considerations in eye cosmetics. Clin Dermatol 19:424–430

    Article  CAS  PubMed  Google Scholar 

  3. U.S. FDA. Part 73 (2018) https://www.ecfr.gov/cgi-bin/text-idx?c=ecfr&SID=fc2869830da702969a2dcfdeb71d7594&rgn=div5&view=text&node=21:1.0.1.1.27&idno=21#21:1.0.1.1.27.3. Accessed 11 May 2018

  4. Council Directive 76/768/EEC (1976) https://eur-ex.europa.eu/LexUriServ/LexUriServ.do?uri=CONSLEG:1976L0768:20100301:en:PDF. Accessed 15 May 2018

  5. ANVISA—Brazilian Health Regulatory Agency (2012) http://portal.anvisa.gov.br/documents/10181/3285555/RDC_44_2012_.pdf/a2489836-8233-40bc-b880-c7719ae356fc. Accessed 15 May 2018

  6. Hepp NM, Mindak WR, Gasper JW, Thompson CB, Barrows JN (2014) Survey of cosmetics for arsenic, cadmium, cobalt, lead, mercury and nickel content. J Cosmet Sci 63:125–145

    Google Scholar 

  7. Sneyers L, Verheyen L, Vermaercke P, Bruggeman M (2009) Trace element determination in beauty products by k0-instrumental neutron activation analysis. J Radioanal Nucl Chem 281:259–263

    Article  CAS  Google Scholar 

  8. Bruzzoniti MC, Abollino O, Pazzi M, Rivoira L, Giacomino A, Vincenti M (2017) Chromium, nickel, and cobalt in cosmetic matrices: an integrated bioanalytical characterization through total content, bioaccessibility, and Cr(III)/Cr(VI) speciation. Anal Bioanal Chem 409:6831–6841

    Article  CAS  PubMed  Google Scholar 

  9. Kanias GD (1984) Determination of trace elements in eyeshadow face powder and rouge make-up cosmetics by neutron activation analysis. J Radioanal Nucl Chem 89:487–496

    Article  Google Scholar 

  10. Furuta E, Nakahara H, Hatsukawa Y, Matsue H, Sakane H (2008) Neutron activation analysis of trace elements in Japanese hormesis cosmetics. J Radioanal Nucl Chem 278:553–557

    Article  CAS  Google Scholar 

  11. Sainio EL, Jolanki R, Hakala E, Kanerva L (2000) Metals and arsenic in eye shadow. Contact Dermat 45:5–10

    Article  Google Scholar 

  12. Atz VL (2008) Desenvolvimento de métodos para determinação de elementos traço em sombra para olhos e batom. Master Dissertation. Universidade Federal do Rio Grande do Sul. Porto Alegre, Brazil

  13. Atz VL, Pozebon D (2009) Graphite furnace atomic absorption spectrometry (GFAAS) methodology for trace element determination in eye shadow and lipstick. At Spectrosc 30:82–91

    CAS  Google Scholar 

  14. Melquiades FL, Parreira PS, Endo LY, Santos G, Wouk L, Filho OP (2015) Portable EDXRF for quality assurance of cosmetics. Cosmetics 2:277–285

    Article  CAS  Google Scholar 

  15. Santos BV, Júnior JMO, Júnior WB, Hanai-Yoshida VM (2018) Assessment of chemical elements in cosmetics’ eye shadows by X-ray fluorescence and international nomenclature of cosmetic ingredients characterization. X-ray Spectrom 47:242–251

    Article  CAS  Google Scholar 

  16. Barros AI, Silva TV, Ferreira EC, Neto JAG (2015) Determination of lead in eye shadow and blush by high-resolution continuum source graphite furnace atomic absorption spectrometry employing direct solid sampling. J Braz Chem Soc 26:140–146

    CAS  Google Scholar 

  17. Volpe MG, Nazzaro M, Coppola R, Rapuano F, Aquino RP (2012) Determination and assessment of selected heavy metals in eye shadow cosmetics from China, Italy, and USA. Microchem J 101:65–69

    Article  CAS  Google Scholar 

  18. Dalmázio I, Menezes MABC (2011) Multi-elemental profile of some Brazilian make-up products by instrumental neutron activation analysis. In: Proceedings of the international nuclear Atlantic conference—INAC 2011, Belo Horizonte, MG, Brazil

  19. França EJ, Fernandes EAN, Bacchi MA (2003) Ni–Cr alloy as neutron flux monitor: composition and homogeneity assessment by NAA. J Radioanal Nucl Chem 257:113–115

    Article  Google Scholar 

  20. Bacchi MA, Fernandes EAN, Oliveira H (2000) A Brazilian experience on k0 standardized neutron activation analysis. J Radioanal Nucl Chem 245:109–114

    Article  Google Scholar 

  21. Bacchi MA, Fernandes EAN (2003) Quantu—design and development of a software package dedicates to k0-standardized INAA. J Radioanal Nucl Chem 257:577–582

    Article  CAS  Google Scholar 

  22. Elias C, Fernandes EAN, Bacchi MA (2012) Neutron activation analysis for assessing chemical composition of dry dog food. J Radioanal Nucl Chem 291:245–250

    Article  CAS  Google Scholar 

  23. Kato LS, Fernandes EAN, Bacchi MA, Elias C, Sarriés SRV, Sarriés GA, Modolo PS (2013) Instrumental neutron activation analysis for assessing homogeneity of a whole rice candidate reference material. J Radioanal Nucl Chem 297:271–275

    Article  CAS  Google Scholar 

  24. Turra C, Fernandes EAN, Bacchi MA, Tagliaferro FS, França EJ (2006) Differences between elemental composition of orange juices and leaves from organics and conventional production systems. J Radioanal Nucl Chem 270:203–208

    Article  CAS  Google Scholar 

  25. Bacchi MA, Fernandes EAN, Tsai SM, Santos LGC (2003) Conventional and organic potatoes: assessment of elemental composition using k0-INAA. J Radioanal Nucl Chem 259:421–424

    Article  Google Scholar 

Download references

Acknowledgements

The authors are thankful to the Radioisotopes Laboratory, Nuclear Energy Centre for Agriculture, University of São Paulo, for providing financial support for this research.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Gabriela da Silva.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

da Silva, G., De Nadai Fernandes, E.A., Bacchi, M.A. et al. Ban the beauty in trace element laboratories: contamination risks of eye shadow. J Radioanal Nucl Chem 318, 761–765 (2018). https://doi.org/10.1007/s10967-018-6158-9

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-018-6158-9

Keywords

Navigation