Abstract
A computational electrochemo-fluid dynamics model has been developed to describe the electrowinning behavior in an electrolyte stream through a planar electrode cell system. Electrode reaction of the uranium electrowinning process from a molten-salt electrolyte stream was modeled to illustrate the details of the flow-assisted mass transport of ions to the cathode. This modeling approach makes it possible to represent variations of the convective diffusion limited current density by taking into account the concentration profile at the electrode surface as a function of the flow characteristics and applied current density in a commercially available computational fluid dynamics platform. It was possible to predict the conventional current–voltage relation in addition to details of electrolyte fluid dynamics and electrochemical variables, such as the flow field, species concentrations, potential, and current distributions throughout the galvanostatic electrolysis cell.
Similar content being viewed by others
References
IAEA (2008) Spent fuel reprocessing options, IAEA-TECDOC-1587. IAEA, Vienna, p 139
Lee HS, Park GI, Kang KH, Hur JM, Kim JG, Ahn DH, Cho YZ, Kim EH (2011) Nucl Eng Tech 43:317
Kim KR, Choi SY, Ahn DH, Lee HS, Hwang IS (2010) J Radioanal Nucl Chem 286:801
Kim KR, Choi SY, Ahn DH, Paek S, Park BG, Lee HS, Yi KW, Hwang IS (2009) J Radioanal Nucl Chem 282:449
Choi SY, Park J, Kim KR, Jung HS, Hwang IS, Park BG, Yi GW, Lee HS, Ahn DH, Paek S (2010) J Alloy Compd 503:177
Palmiotti G et al (2005) Requirements for advanced simulation of nuclear reactor and chemical separation plants, ANL-AFCI-168. Argonne National Laboratory, Argonne, IL, USA, p 12
Newman JS (1991) Electrochemical system, 2nd edn. Prentice Hall, New Jersey
ANSYS CFX-12.0 Solver (2009) Cannonsburg, USA/ANSYS, http://www.ansys.com. Accessed 17 Dec 2009
Pickett DJ (1979) Electrochemical reactor design, 2nd edn. American Elsevier, New York
Bard AJ, Faulkner LR (2001) Electrochemical methods, fundamentals and applications, 2nd edn. Wiley, New York
Kang YH et al (1999) Pyrometallurgical data book, Korea Atomic Energy Research Institute report, KAERI/TS-110/99
Acknowledgments
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kim, K.R., Choi, S.Y., Kim, S.H. et al. Computational electrochemo-fluid dynamics modeling in a uranium electrowinning cell. J Radioanal Nucl Chem 299, 165–170 (2014). https://doi.org/10.1007/s10967-013-2720-7
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-013-2720-7