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Kinetic determination of traces of Th(IV) on the basis of its catalytic effect in environmental water samples

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Abstract

A new analytic kinetic-catalytic method based on catalytic effect of traces of Th(IV) on the reaction oxidation of 4-hydroxycoumarin by KMnO4 were developed and validated in this study. The linearity of the method was obtained in the range of concentrations of Th(IV) from 0.2 to 2 μg mL−1. The probable relative error is in the interval from 7.88 to 3.50% for the range of concentration of Th(IV) from 0.5 to 2 μg mL−1. Kinetic equations of investigated reactions were established. The proposed kinetic method was directly applied on determination of Th(IV) in environmental water samples. It was found that the results of Th(IV) determination in water samples obtained by proposed kinetic method and comparative atomic absorption spectrometry method were statistically agreeable.

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Authors and Affiliations

  1. Faculty of Science and Mathematics, University of Pristina, Kosovska Mitrovica, Serbia

    Ruzica Micic

  2. Faculty of Science and Mathematics, University of Nis, Nis, Serbia

    Snezana Mitic, Aleksandra Pavlovic, Snezana Tosic & Milan Mitic

Authors
  1. Ruzica Micic
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  2. Snezana Mitic
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  3. Aleksandra Pavlovic
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  4. Snezana Tosic
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  5. Milan Mitic
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Correspondence to Ruzica Micic.

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Micic, R., Mitic, S., Pavlovic, A. et al. Kinetic determination of traces of Th(IV) on the basis of its catalytic effect in environmental water samples. J Radioanal Nucl Chem 288, 845–850 (2011). https://doi.org/10.1007/s10967-011-1009-y

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  • DOI: https://doi.org/10.1007/s10967-011-1009-y

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