Abstract
All commercially available mineral waters of Austrian origin were investigated with regard to the natural radionuclides 228Ra, 226Ra, 210Pb, 210Po, 238U and 234U. From 1 to 1.5 L of sample the nuclides were extracted and measured sequentially: the radium isotopes as well as 210Pb were measured by liquid scintillation counting after separation on a membrane loaded with element-selective particles (Empore Radium Disks), 210Po was determined by α-particle spectroscopy after spontaneous deposition onto a copper planchette and uranium was determined also by α-particle spectroscopy after anion separation and microprecipitation with NdF3. The calculated committed effective doses for adults, teens and babies were compared to the total indicative dose of 0.1 mSv/year given in the EC Drinking Water Directive. The dominant portion of the committed effective dose was due to 228Ra. Highly mineralised waters showed also higher 226Ra and 228Ra levels.


Similar content being viewed by others
References
Council Directive 98/83/EC of 3 November 1998 on the quality of water intended for human consumption. Official Journal L 330, 05/12/1998, pp. 0032–0054
Commission Recommendation of 20 December 2001 on the protection of the public against exposure to radon in drinking water supplies (2001/928/Euratom)
World Health Organisation (WHO) (2005) Uranium in drinking-water. Background document for development of WHO guidelines for drinking-water quality. WHO, Geneva. www.who.int/water_sanitation_health/dwq/chemicals/uranium290605.pdf.
US EPA (2000) Proposed drinking water standards, US EPA 65 FR 76707. US Environmental Protection Agency, 7 Dec 2000
Fisenne IM (1996) USDOE remediation site case study. Environ Int 22:243–249
Bundesgesetzblatt Nr. 56, Seite 2762: Deutsche Mineral – und Tafelwasserverordnung, 12.12.2006
Bayes JC, Gomez E, Garcias F, Casas M, Cerda V (1996) Radium determination in mineral water. Appl Radiat Isot 47(9/10):849–853
Godoy JM, da S Amaral EC, Godoy ML (2001) Natural radionuclides in Brazilian mineral water and consequent doses to the population. J Environ Radioact 53/2:175–182
Kralik C, Friedrich M, Vojir F (2003) Natural radionuclides in bottled water in Austria. J Environ Radioact 65(2):233–241
Kovacs T, Bodrogi E, Dombovari P, Somlai J, Nemeth C, Capote A, Tarjan S (2004) 238U, 226Ra, 210Po concentrations of bottled mineral waters in Hungary and their committed effective dose. Rad Prot Dosim 108(2):175–181
Schönhofer F, Wallner G (2001) Very rapid determination of 226Ra, 228Ra and 210Pb by selective adsorption and liquid scintillation counting. Radioact Radiochem 12(2):33–38
Wallner G (2002) Determination of 226Ra, 228Ra and 210Pb in drinking water using liquid scintillation counting. In: Möbius S, Noakes JE, Schönhofer F (eds) International conference on advances in liquid scintillation spectrometry 2001 (Karlsruhe, Germany). Radiocarbon, Tucson, pp 269–274
Landstetter C, Katzlberger C (2006) Rapid methods for the determination of natural radionuclides in drinking water. In: Chalupnik S, Schönhofer F, Noakes J (eds) LSC 2005. Advances in liquid scintillation spectrometry. Radiocarbon, Tucson, pp 181–190
Kozlowska B, Walencik A, Dorda J (2008) Natural radioactivity and dose estimation in underground water from the Sudety mountains in Poland. Rad Prot Dosim 128(3):331–335
Wallner G, Steininger G (2007) Radium isotopes and 222Rn in Austrian drinking waters. J Radioanal Nucl Chem 274(3):511–516
Wallner G, Wagner R, Katzlberger C (2008) Natural radionuclides in Austrian mineral water and their sequential measurement by fast methods. J Environ Radioact 99(7):1090–1094
Schönhofer F, Chalupnik S, Wallner G, Chmielewska I (2009) Natural radionuclides in mineral waters sold in Upper Silesia, Poland. Their measurement by liquid scintillation spectrometry. Doses and compliance with regulations. In: Eikenberg J, Jäggi M, Beer H, Baehrle H (eds) International conference on advances in liquid scintillation spectrometry, 2008, Davos, Switzerland. Radiocarbon, Tucson, pp 125–131
Wallner G, Herincs E, Ayromlou S (2009) Determination of natural radionuclides in drinking water from the Waldviertel, Austria. In: Eikenberg J, Jäggi M, Beer H, Baehrle H (eds) International conference on advances in liquid scintillation spectrometry, 2008, Davos, Switzerland. Radiocarbon, Tucson, pp 345–352
ICRP Publ. No. 67, Part 2, Annals of the ICRP 23(3/4), 1993
ICRP Publ. No. 68, Annals of the ICRP 24(4), 1994
Katzlberger C, Wallner G, Irlweck K (2001) Determination of 210Pb, 210Bi and 210Po in natural drinking water. J Radioanal Nucl Chem 249(1):191–196
Delacroix D, Guerre JP, Leblanc P, Hickman C (2002) Radionuclide and radiation protection data handbook 2002. Radiat Prot Dosim 98(1):168
Acknowledgments
This work was performed under contract GZ: BMGFJ-32234/0002-III/B/5/2008 with the Bundesministerium für Gesundheit; we thank Min.Rat Dr. M. Ditto for his interest.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wallner, G., Jabbar, T. Natural radionuclides in Austrian bottled mineral waters. J Radioanal Nucl Chem 286, 329–334 (2010). https://doi.org/10.1007/s10967-010-0751-x
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-010-0751-x