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Surface Tension of the 4-Methyl-2-Pentanone/Ethyl Benzoate Binary System in the Temperature Range from 278.15 to 308.15K

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Abstract

Surface tensions (σ) and densities (ρ) of 4-methyl-2-pentanone/ethyl benzoate binary mixtures have been measured over the entire composition range at 278.15, 288.15, 298.15, and 308.15 K. Values of the excess surface tensions (σE) and excess molar volumes (VE) have been calculated. The σE and VE values were fitted by to the Redlich–Kister polynomial equation and the A k coefficients have been derived. The standard deviations between the calculated and the experimental excess properties have also been derived. The surface tension values have been further used to calculate the surface entropies (SS) and surface enthalpies (HS) per unit surface area. The lyophobicity (β) and the surface mole fractions (x1S) of the surfactant 4-methyl-2-pentanone have been derived using the extended Langmuir model. The obtained results are discussed from the viewpoint of the existence of specific interactions between unlike molecules in the bulk region and the surface.

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References

  1. J. Lyklema, The Surface Tension of Pure Liquids: Thermodynamic Components and Corresponding States, Colloids Surf. A: Physicochem. Eng. Aspects 156, 413–421 (1999).

    Article  CAS  Google Scholar 

  2. M. H. Ghatee and L. Pakdel, Surface Tension Regularity of Non-Polar, Polar, and Weak Electrolyte Liquid Hydrocarbons, Fluid Phase Equilib. 234, 101–107 (2005).

    Article  CAS  Google Scholar 

  3. G. Vázquez, G. Antorrena, J. M. Navaza, and V. Santos, Absorption of CO2 by Water and Surfactant Solutions in the Presence of Induced Marangoni Effect, Chem. Eng. Sci. 51, 3317–3324 (1996).

    Google Scholar 

  4. G. Vázquez, E. Alvarez, and J. M. Navaza, Surface Tension of Alcohol + Water from 20 to 50 °C, J. Chem. Eng. Data 40, 611–614 (1995).

    Google Scholar 

  5. E. Calvo, A. Penas, M. Pintos, R. Bravo, and A. Amigo, Refractive Indices and Surface Tensions of Binary Mixtures of 1,4-Dioxane + 1-Alkanols at 298.15 K, J. Chem. Eng. Data 46, 692–695 (2001).

    Article  CAS  Google Scholar 

  6. J. Wu, Z. Liu, F. Wang, and C. Ren, Surface Tension of Dimethyl Ether from (213 to 368) K, J. Chem. Eng. Data 48, 1571–1573 (2003).

    CAS  Google Scholar 

  7. G. Ouyang, Z. Huang, J. Ou, W. Wu, and B. Kang, Excess Molar Volumes and Surface Tensions of Xylene with 2-Propanol or 2-Methyl-2-Propanol at 298.15 K, J. Chem. Eng. Data 48, 195–197 (2003).

    Article  CAS  Google Scholar 

  8. X.-X. Li, Y.-X. Liu, and X.-H. Wei, Density, Viscosity, and Surface Tension at 293.15 K and Liquid–Liquid Equilibria from 301.15 K to 363.15 K under Atmospheric Pressure for the Binary Mixture of Diethylene Glycol Diethyl Ether + Water, J. Chem. Eng. Data 49, 1043–1045 (2004).

    CAS  Google Scholar 

  9. C. Pan, Q. Ke, G. Ouyang, X. Zhen, Y. Yang, and Z. Huang, Excess Molar Volumes and Surface Tensions of Trimethylbenzene with Tetrahydrofuran Tetrachloromethane and Dimethyl Sulfoxide at 298.15 K, J. Chem. Eng. Data 49, 1839–1842 (2004).

    CAS  Google Scholar 

  10. S. Azizian and N. Bashavard, Surface Tension of Dilute Solutions of Linear Alcohols in Benzyl Alcohol, J. Chem. Eng. Data 50, 1303–1307 (2005).

    CAS  Google Scholar 

  11. M. Hafez and S. Hartland, Densities and Viscosities of Binary Systems Toluene–Acetone and 4-Methyl-2-Pentanone–Acetic Acid at 20, 25, 35, and 45°C, J. Chem. Eng. Data 21, 179–182 (1976).

    Article  CAS  Google Scholar 

  12. M. Fermeglia, R. Lapasin, and G. Torriano, Excess Volumes and Viscosities of Binary Systems Containing 4-Methyl-2-Pentanone, J. Chem. Eng. Data 35, 260–265 (1990).

    Article  CAS  Google Scholar 

  13. L.-S. Lee and M.-I. Chuang, Excess Volumes of Cyclohexane with 2-Propanone, 2-Butanone, 3-Pentanone, 4-Methyl-2-pentanone, 1-Propanol, and 2-Propanol and Ethanoic Acid + 1-Propanol Systems, J. Chem. Eng. Data 42, 850–853 (1997).

    CAS  Google Scholar 

  14. T. M. Aminabhavi, S. K. Raikar, and R. H. Balundgi, Densities, Viscosities, Refractive Indices, and Speeds of Sound in Methyl Acetoacetate + Methyl Acetate, + Ethyl Acetate, + n-Butyl Acetate, + Methyl Benzoate, and + Ethyl Benzoate at 298.15, 303.15, and 308.15 K, J. Chem. Eng. Data 38, 441–445 (1993).

    CAS  Google Scholar 

  15. T. M. Aminabhavi, H. T. S. Phayde, R. S. Khinnavar, B. Gopalakrishna, and K. C. Hansen, Densities, Refractive Indices, Speeds of Sound, and Shear Viscosities of Diethylene Glycol Dimethyl Ether with Ethyl Acetate, Methyl Benzoate, Ethyl Benzoate, and Diethyl Succinate in the Temperature Range from 298.15 to 318.15 K, J. Chem. Eng. Data 39, 251–260 (1994).

    CAS  Google Scholar 

  16. P.-J. Lien, P. Venkatesu, H.-M. Lin, and M.-J. Lee, Excess Molar Enthalpies of 1-Octanol with Ethylbenzene, Ethyl Benzoate, Acetophenone, Anisole, or Methanol at 298.15 K, J. Chem. Eng. Data 47, 768–771 (2002).

    Google Scholar 

  17. P.-J. Lien, H.-M. Lin, M.-J. Lee, and P. Venkatesu, Excess Molar Enthalpies of Dimethyl Carbonate with o-Xylene, m-Xylene, p-Xylene, Ethylbenzene, or Ethyl Benzoate at 298.15 K, J. Chem. Eng. Data 48, 110–113 (2003).

    CAS  Google Scholar 

  18. N. G. Tsierkezos, A. E. Kelarakis, and I. E. Molinou, Densities, Viscosities, Refractive Indices, and Surface Tensions of 4-Methyl-2-Pentanone + Ethyl Benzoate Mixtures at (283.15, 293.15, and 303.15) K, J. Chem. Eng. Data 45, 776–779 (2000).

    CAS  Google Scholar 

  19. N. G. Tsierkezos and I. E. Molinou, Thermodynamic Properties of Water + Ethylene Glycol at 283.15, 293.15, 303.15, and 313.15 K, J. Chem. Eng. Data 43, 989–993 (1998).

    Article  CAS  Google Scholar 

  20. N. G. Tsierkezos and I. E. Molinou, Densities and Viscosities of Ethylene Glycol Binary Mixtures at 293.15 K, J. Chem. Eng. Data 44, 955–958 (1999).

    Article  CAS  Google Scholar 

  21. N. G. Tsierkezos, M. M. Palaiologou, and I. E. Molinou, Densities and Viscosities of 1-Pentanol Binary Mixtures at 293.15 K, J. Chem. Eng. Data 45, 272–275 (2000).

    CAS  Google Scholar 

  22. N. G. Tsierkezos, I. E. Molinou, and G. A. Polizos, Relative Permittivities, Speeds of Sound, Viscosities, and Densities of Cyclohexanone + cis-Decalin and Cyclohexanone + trans-Decalin Mixtures at 283.15, 293.15, and 303.15 K, J. Chem. Eng. Data 47, 1492–1495 (2002).

    Article  CAS  Google Scholar 

  23. R. Riggio, H. E. Martinez, and H. N. Solimo, Excess Volumes, Viscosities, Enthalpies, and Gibbs Free Energies for Mixtures of Methyl Isobutyl Ketone + n-Pentanol and Methyl Isobutyl Ketone + Isoamyl Alcohol at 298.15 K, Can. J. Chem. 64, 1595–1598 (1986).

    CAS  Google Scholar 

  24. R. Riggio, M. H. Ubeda, J. F. Ramos, and H. E. Martinez, Densities and Refractive Indexes of Binary Mixtures in the System Methyl Isobutyl Ketone-2-Butanol. Mathematical Relations Obtained, J. Chem. Eng. Data 25, 318–320 (1980).

    Article  CAS  Google Scholar 

  25. R. Riggio, H. E. Martinez, J. A. Espindola, and J. F. Ramos, Viscosities, Densities and Refractive Indexes of Mixtures of Methyl Isobutyl Ketone-Isobutyl Alcohol, J. Chem. Eng. Data 29, 11–13 (1984).

    Article  CAS  Google Scholar 

  26. P.-J. Lien, S.-T. Wu, M.-J. Lee, and H.-M. Lin, Excess Molar Enthalpies for Dimethyl Carbonate with o-Xylene, m-Xylene, p-Xylene, Ethylbenzene, or Ethyl Benzoate at 298.15 K and 10.2 MPa, J. Chem. Eng. Data 48, 632–636 (2003).

    CAS  Google Scholar 

  27. O. Redlich and A. T. Kister, Algebraic Representation of Thermodynamic Properties and the Classification of Solutions, Ind. Eng. Chem. 40, 345–348 (1948).

    Google Scholar 

  28. J. J. Jasper, E. R. Kerr, and F. Gregorich, The Orthobaric Surface Tensions and Thermodynamic Properties of the Liquid Surfaces of the n-Alkanes, C5 to C28, J. Am. Chem. Soc. 75, 5252–5254 (1953).

    CAS  Google Scholar 

  29. R. S. Hansen, Thermodynamics of Interfaces Between Condensed Phases, J. Phys. Chem. 66, 410–415 (1962).

    CAS  Google Scholar 

  30. M. Aratono, T. Toyomasu, M. Villeneuve, Y. Uchizono, T. Takiue, K. Motomura, and N. Ikeda, Thermodynamic Study on the Surface Formation of the Mixture of Water and Ethanol, J. Colloid Interface Sci. 191, 146–153 (1997).

    Article  CAS  Google Scholar 

  31. J. B. Griffin and H. L. Clever, Surface Tension of Perfluoromethylcyclohexane, J. Chem. Eng. Data 5, 390–390 (1960).

    Article  CAS  Google Scholar 

  32. J. Gliński, G. Chavepeyer, J.-K. Platten, and Ph. Smet, Surface Properties of Diluted Aqueous Solutions of Normal Aliphatic Alcohols, J. Chem. Phys. 109, 5050–5053 (1998).

    Google Scholar 

  33. J. Gliński, G. Chavepeyer, and J.-K. Platten, Untypical Surface Properties of Aqueous Solutions of 1,5-Pentanediol, Colloids Surf. A: Physicochem. Eng. Aspects 162, 233–238 (2000).

    Google Scholar 

  34. J. Gliński, G. Chavepeyer, and J.-K. Platten, Surface Properties of Diluted Aqueous Solutions of 3-Picoline, Colloids Surf. A: Physicochem. Eng. Aspects 178, 207–212 (2001).

    Google Scholar 

  35. A. Piñeiro, P. Brocos, A. Amigo, J. Gracia-Fadrique, and M. G. Lemus, Extended Langmuir Isotherm for Binary Liquid Mixtures, Langmuir 17, 4261–4266 (2001).

    Google Scholar 

  36. S. Azizian and N. Bashavard, Surface Properties of Pure Liquids and Binary Liquid Mixtures of Ethylene Glycol + Methylcyclohexanols, J. Chem. Eng. Data 49, 1059–1063 (2004).

    Article  CAS  Google Scholar 

  37. S. Azizian and N. Bashavard, Equilibrium Surface Tensions of Benzyl Alcohol + Ethylene Glycol Mixtures, J. Chem. Eng. Data 50, 709–712 (2005).

    CAS  Google Scholar 

  38. S. Azizian and N. Bashavard, Surface Tensions of Dilute Solutions of Cycloheptanol in Ethylene Glycol, J. Chem. Eng. Data 50, 1091–1094 (2005).

    CAS  Google Scholar 

  39. T. M. Aminabhavi, M. I. Aralaguppi, S. B. Harogoppad, and R. H. Balundgi, Densities, Viscosities, Refractive Indices, and Speeds of Sound for Methyl Acetoacetate + Aliphatic Alcohols (C1–C8), J. Chem. Eng. Data 38, 31–39 (1993).

    CAS  Google Scholar 

  40. J.-P. E. Grolier, D. Ballet, and A. Viallard, Thermodynamics of Ester-Containing Mixtures. Excess Enthalpies and Excess Volumes for Alkyl Acetates and Alkyl Benzoates + Alkanes, + Benzene, + Toluene, and + Ethylbenzene, J. Chem. Thermodyn. 6, 895–908 (1974).

    CAS  Google Scholar 

  41. P. Venkatesu and M. V. Prabhakara Rao, Excess Volumes of Ternary Mmixtures of N,N-Dimethylformamide + Methyl Isobutyl Ketone + 1-Alkanols at 303.15 K, Fluid Phase Equilib. 98, 173–178 (1994).

    Article  CAS  Google Scholar 

  42. P. Venkatesu and M. V. Prabhakara Rao, Excess Volumes of N,N-Dimethylformamide with Ketones at 303.15 K, J. Chem. Eng. Data 41, 1059–1060 (1996).

    Article  CAS  Google Scholar 

  43. J. J. Jasper, Surface Tension of Pure Liquid Compounds, J. Phys. Chem. Ref. Data 1, 841–1009 (1972).

    CAS  Google Scholar 

  44. B. C. Hoke and J. C. Chen, Binary Aqueous-Organic Surface Tension Temperature Dependence, J. Chem. Eng. Data 36, 322–326 (1991).

    Article  CAS  Google Scholar 

  45. G. Law and P. R. Watson, Surface Tension Measurements of N-Alkylimidazolium Ionic Liquids, Langmuir 17, 6138–6141 (2001).

    Article  CAS  Google Scholar 

  46. C. Pan, C. Ouyang, J. Lin, Y. Rao, X. Zhen, G. Lu, and Z. Huang, Excess Molar Volumes and Surface Tensions of 1,2,4-Trimethylbenzene and 1,3,5-Trimethylbenzene with 1-Butanol, 2-Methyl-1-Propanol, 2-Butanol, and 2-Methyl-2-Propanol at 298.15 K, J. Chem. Eng. Data 49, 1744–1747 (2004).

    CAS  Google Scholar 

  47. G. Ouyang, Y. Yang, S. Lu, Z. Huang, and B. Kang, Excess Molar Volumes and Surface Tensions of Xylene with Acetone or 2-Butanone at 298.15 K, J. Chem. Eng. Data 49, 330–332 (2004).

    CAS  Google Scholar 

  48. J. Gliński, J. Przybylski, G. Chavepeyer, and J.-K. Platten, Untypical Surface Properties of the System Caprylic Acid + n-Propyl Acetate, J. Solution Chem. 30, 925–936 (2001).

    Google Scholar 

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Authors and Affiliations

  1. Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Strasse 2, D-12489, Berlin, Germany

    Nikos G. Tsierkezos

  2. Physical Chemistry Laboratory, Department of Chemistry, University of Athens, Panepistimiopolis, Athens, 15771, Greece

    Ioanna E. Molinou

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  1. Nikos G. Tsierkezos
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Correspondence to Nikos G. Tsierkezos.

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Tsierkezos, N.G., Molinou, I.E. Surface Tension of the 4-Methyl-2-Pentanone/Ethyl Benzoate Binary System in the Temperature Range from 278.15 to 308.15K. J Solution Chem 35, 279–296 (2006). https://doi.org/10.1007/s10953-006-9365-x

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