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Volumetric Properties of the Ternary System 1,4-Dioxane + Butyl Acrylate + Ethyl Acrylate and Its Binary Butyl Acrylate + Ethyl Acrylate at 298.15 K

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Abstract

Densities of the ternary system 1,4-dioxane + butyl acrylate + ethyl acrylate and its binary butyl acrylate + ethyl acrylate have been measured in the whole composition range, at 298.15 K and atmospheric pressure, using an Anton Paar DMA 5000 oscillating U-tube densimeter. The calculated excess molar volumes of the binary system are positive and were correlated with the Redlich–Kister equation and with a series of Legendre polynomials. Several models were used to correlate the ternary behavior from the excess molar volume data of their constituent binaries and were found equally good to fit the data. The best fit was based on a direct approach, without information on the component binary systems.

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Authors and Affiliations

  1. Department of Chemical Engineering, Ben-Gurion University of the Negev, Beer-Sheva, 84105, Israel

    Jaime Wisniak

  2. Centro de Investigación en Química Aplicada, Saltillo, 25000, Coahuila, México

    René D. Peralta, Ramiro Infante & Gladis Cortez

Authors
  1. Jaime Wisniak
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  2. René D. Peralta
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  3. Ramiro Infante
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  4. Gladis Cortez
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Correspondence to Jaime Wisniak.

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Wisniak, J., Peralta, R.D., Infante, R. et al. Volumetric Properties of the Ternary System 1,4-Dioxane + Butyl Acrylate + Ethyl Acrylate and Its Binary Butyl Acrylate + Ethyl Acrylate at 298.15 K. J Solution Chem 34, 171–183 (2005). https://doi.org/10.1007/s10953-005-2754-8

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  • DOI: https://doi.org/10.1007/s10953-005-2754-8

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