Abstract
The effects of V addition on the structural, magnetic, and magnetocaloric properties in Ni49-xVxMn37Sn12B2 (x = 0, 1, 2, and 3) alloys were investigated. XRD analyses performed at room temperature showed that the main sample was in martensite phase, while x = 3 sample was in L21 structure which is attributed to austenite phase. The samples exhibited a first-order structural transformation from austenite phase to martensite phase. The martensitic transformation (MT) temperature was reduced by increasing the amount of V. Besides, V doping caused an increase in magnetization. Although antiferromagnetic interactions arising from Mn–Mn couplings were effective at low temperatures, they vanished above the blocking temperature. Magnetic entropy change (ΔSM) of the samples was estimated using the Maxwell equation from isothermal magnetization curves. An inverse magnetocaloric effect was observed around the MT interval and ΔSM was significantly improved with increasing V content and applied magnetic field. Maximum refrigerant capacity (RC), which is one of the quality parameters for characterizing a magnetic refrigerant, was determined as 96.7 J/kg for x = 3 samples (ΔH = 5 T).
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References
Kirat, G., Aksan, M.A.: Influence of the Cu substitution on magnetic properties of Ni–Mn–Sn–B shape memory ribbons. Appl. Phys. A Mater. Sci. Process. 127, 1–9 (2021). https://doi.org/10.1007/s00339-020-04251-5
KIRAT, G.: Exchange Bias Effect in NiMnSbB ferromagnetic shape memory alloys depending on Mn content. Adıyaman Univ. J. Sci. 11, 444–455 (2021). https://doi.org/10.37094/adyujsci.987045
Zhang, X., Zhang, H., Qian, M., Geng, L.: Enhanced magnetocaloric effect in Ni-Mn-Sn-Co alloys with two successive magnetostructural transformations. Sci. Rep. 8, 1–11 (2018). https://doi.org/10.1038/s41598-018-26564-5
Kirat, G., Ali Aksan, M.: Investigation of martensitic transformation and magnetoresistance properties of cu-substituted Ni-Mn-Sn-B melt spun ribbons. J. Magn. Magn. Mater. 529, 167858 (2021). https://doi.org/10.1016/j.jmmm.2021.167858
Khan, M., Dubenko, I., Stadler, S., Ali, N.: Magnetostructural phase transitions in Ni50Mn 25+xSb25-x Heusler alloys. J. Phys. Condens. Matter. 20, (2008). https://doi.org/10.1088/0953-8984/20/23/235204
Gamzatov, A.G., Aliev, A.M., Ghotbi Varzaneh, A., Kameli, P., Sarsari, I.A., Yu, S.C.: Inverse-direct magnetocaloric effect crossover in Ni47Mn40Sn12.5Cu0.5 Heusler alloy in cyclic magnetic fields. Appl. Phys. Lett. 113, 1–6 (2018). https://doi.org/10.1063/1.5049398
Dos Reis, R.D., Caron, L., Singh, S., Felser, C., Nicklas, M.: Direct and indirect determination of the magnetocaloric effect in the heusler compound ni1.7pt0.3mnga. Entropy. 23, 1–10 (2021). https://doi.org/10.3390/e23101273
Aksoy, S., Acet, M., Deen, P.P., Mañosa, L., Planes, A.: Magnetic correlations in martensitic Ni-Mn-based Heusler shape-memory alloys: neutron polarization analysis. Phys. Rev. B - Condens. Matter Mater. Phys. 79, 1–4 (2009). https://doi.org/10.1103/PhysRevB.79.212401
Wang, X., Shang, J.X., Wang, F.H., Jiang, C.B., Xu, H.: Bin: Origin of unusual properties in the ferromagnetic Heusler alloy Ni-Mn-Sn: a first-principles investigation. Scr. Mater. 89, 33–36 (2014). https://doi.org/10.1016/j.scriptamat.2014.06.027
Aydogdu, Y., Turabi, A.S., Aydogdu, A., Vance, E.D., Kok, M., Kirat, G., Karaca, H.E.: The effects of substituting B for Cu on the magnetic and shape memory properties of CuAlMnB alloys. Appl. Phys. A Mater. Sci. Process. 122, 1–8 (2016). https://doi.org/10.1007/s00339-016-0222-5
Zheng, H., Wang, W., Xue, S., Zhai, Q., Frenzel, J., Luo, Z.: Composition-dependent crystal structure and martensitic transformation in Heusler Ni-Mn-Sn alloys. Acta Mater. 61, 4648–4656 (2013). https://doi.org/10.1016/j.actamat.2013.04.035
Luo, H., Meng, F., Jiang, Q., Liu, H., Liu, E.: Effect of boron on the martensitic transformation and magnetic. Scr. Mater. 63, 569–572 (2010). https://doi.org/10.1016/j.scriptamat.2010.06.009
Planes, A., Mãosa, L., Acet, M.: Magnetocaloric effect and its relation to shape-memory properties in ferromagnetic Heusler alloys. J. Phys. Condens. Matter. 21, (2009). https://doi.org/10.1088/0953-8984/21/23/233201
Hernando, B., Sánchez Llamazares, J.L., Santos, J.D., Prida, V.M., Baldomir, D., Serantes, D., Varga, R., González, J.: Magnetocaloric effect in melt spun Ni50.3 Mn35.5 Sn14.4 ribbons. Appl. Phys. Lett. 92, 12–15 (2008). https://doi.org/10.1063/1.2904625
Krenke, T., Duman, E., Acet, M., Wassermann, E.F., Moya, X., Mañosa, L., Planes, A., Suard, E., Ouladdiaf, B.: Magnetic superelasticity and inverse magnetocaloric effect in Ni-Mn-In. Phys. Rev. B - Condens. Matter Mater. Phys. 75, 1–6 (2007). https://doi.org/10.1103/PhysRevB.75.104414
Brown, P.J., Gandy, A.P., Ishida, K., Kainuma, R., Kanomata, T., Neumann, K.U., Oikawa, K., Ouladdiaf, B., Ziebeck, K.R.A.: The magnetic and structural properties of the magnetic shape memory compound Ni2Mn1.44Sn0.56. J. Phys. Condens. Matter. 18, 2249–2259 (2006). https://doi.org/10.1088/0953-8984/18/7/012
Xuan, H.C., Wang, D.H., Zhang, C.L., Han, Z.D., Gu, B.X., Du, Y.W.: Boron’s effect on martensitic transformation and magnetocaloric effect in Ni43 Mn46Sn11 Bx alloys. Appl. Phys. Lett. 92, 1–4 (2008). https://doi.org/10.1063/1.2895645
Luo, H., Meng, F., Jiang, Q., Liu, H., Liu, E., Wu, G., Wang, Y.: Effect of boron on the martensitic transformation and magnetic properties of Ni50Mn36.5Sb13.5-xBx alloys. Scr. Mater. 63, 569–572 (2010). https://doi.org/10.1016/j.scriptamat.2010.06.009
Nong, N.V., Tai, L.T., Huy, N.T., Trung, N.T., Bahl, C.R.H., Venkatesh, R., Poulsen, F.W., Pryds, N.: Structural, magnetic and magnetocaloric properties of Heusler alloys Ni50Mn38Sb12 with boron addition. Mater. Sci. Eng. B Solid-State Mater. Adv. Technol. 176, 1322–1325 (2011). https://doi.org/10.1016/j.mseb.2011.07.013
Wang, W.H., Chen, J.L., Liu, Z., Wu, G.H., Zhan, W.S.: Thermal hysteresis and friction of phase boundary motion in ferromagnetic Ni52Mn23Ga25 single crystals. Phys. Rev. B. 65, 012416 (2001). https://doi.org/10.1103/PhysRevB.65.012416
Xuan, H.C., Wang, D.H., Zhang, C.L., Han, Z.D., Gu, B.X., Du, Y.W.: Boron’s effect on martensitic transformation and magnetocaloric effect in Ni43 Mn46Sn11 Bx alloys. Appl. Phys. Lett. 92, 90–93 (2008). https://doi.org/10.1063/1.2895645
Llamazares, J.L.S., Quintana-Nedelcos, A., Ríos-Jara, D., Sánchez-Valdes, C.F., García-Fernández, T., García, C.: The effect of low temperature thermal annealing on the magnetic properties of Heusler Ni-Mn-Sn melt-spun ribbons. J. Magn. Magn. Mater. 401, 38–43 (2016). https://doi.org/10.1016/j.jmmm.2015.10.005
Khan, M., Dubenko, I., Stadler, S., Ali, N.: Exchange bias in bulk Mn rich Ni-Mn-Sn Heusler alloys. J. Appl. Phys. 102, 3–7 (2007). https://doi.org/10.1063/1.2818016
Wang, B.M., Liu, Y., Wang, L., Huang, S.L., Zhao, Y., Yang, Y., Zhang, H.: Exchange bias and its training effect in the martensitic state of bulk polycrystalline Ni49.5Mn34.5In16. J. Appl. Phys. 104, 14–18 (2008). https://doi.org/10.1063/1.2973187
Chernenko, V.A., Barandiarán, J.M., Rodriguez Fernández, J., Rojas, D.P., Gutiérrez, J., Lázpita, P., Orue, I.: Magnetic and magnetocaloric properties of martensitic Ni 2Mn 1.4Sn 0.6 Heusler alloy. J. Magn. Magn. Mater. 324, 3519–3523 (2012). https://doi.org/10.1016/j.jmmm.2012.02.080
Nayak, A.K., Nicklas, M., Chadov, S., Khuntia, P., Shekhar, C., Kalache, A., Baenitz, M., Skourski, Y., Guduru, V.K., Puri, A., Zeitler, U., Coey, J.M.D., Felser, C.: Design of compensated ferrimagnetic Heusler alloys for giant tunable exchange bias. Nat. Mater. 14, 679–684 (2015). https://doi.org/10.1038/nmat4248
Chatterjee, S., Giri, S., De, S.K., Majumdar, S.: Reentrant-spin-glass state in Ni2Mn1.36Sn0.64 shape-memory alloy . Phys. Rev. B. 79, 1–4 (2009). https://doi.org/10.1103/physrevb.79.092410
Li, Z., Jing, C., Chen, J., Yuan, S., Cao, S., Zhang, J.: Observation of exchange bias in the martensitic state of Ni50 Mn36 Sn14 Heusler alloy. Appl. Phys. Lett. 91, (2007). https://doi.org/10.1063/1.2784958
Varzaneh, A.G., Kameli, P., Amiri, T., Ramachandran, K.K., Mar, A., Sarsari, I.A., Luo, J.L., Etsell, T.H., Salamati, H.: Effect of Cu substitution on magnetocaloric and critical behavior in Ni47Mn40Sn13−xCux alloys. J. Alloys Compd. 708, 34–42 (2017). https://doi.org/10.1016/j.jallcom.2017.02.278
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Kirat, G. Improving the Magnetocaloric Performance of NiMnSnB Heusler Alloys with V Substitutions. J Supercond Nov Magn 35, 3323–3331 (2022). https://doi.org/10.1007/s10948-022-06396-1
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DOI: https://doi.org/10.1007/s10948-022-06396-1