Skip to main content
SpringerLink
Log in

Crystal structure of KPb2Cl5 and KPb2Br5

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The KPb2Cl5 and KPb2Br5 crystals are monoclinic (P21/c) with a microtwinned structure. X-ray analysis of chloride resulted in the parameters a = 8.854(2) Å, b = 7.927(2) Å, c = 12.485(3) Å; β = 90.05(3)°, d calc = 4.78(1) g/cm3 (STOE STADI4, MoK α, 2θmax = 80°), R 1 = 0.0702 for 4094 F ≥ 4 σ(F) reflections. For bromide, a = 9.256(2) Å, b = 8.365(2) Å, c = 13.025(3) Å; β = 90.00(3)°, d calc = 5.62(1) g/cm3 (Bruker P4, MoK α, 2θmax = 70°), R 1 = 0.0692 for 3076 F ≥ 4 (F) reflections.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. M. Tkachuk, S. E. Ivanova, L. I. Isaenko, et al., Opt. Spektrosk., 91, No. 6, 942–954 (2001).

    Google Scholar 

  2. G. M. Sheldrick, SHELX-97. Release 97-2, Univ. Göttingen, Germany (1998).

    Google Scholar 

  3. H. Keller, Z. Naturforsch., B31, 885 (1976).

    Google Scholar 

  4. F. Ras, D. Ijdo, and G. C. Verschoor, Acta Crystallogr., B33, 259/260 (1977).

    Google Scholar 

  5. M. Nikl, K. Nitsch, I. Velicka, et al., Phys. Status Solidi (b), K37, 168 (1991).

    Google Scholar 

  6. K. Nitsch, M. Dusek, M. Nikl, et al., Prog. Crystal Growth Charact., 30, 1–22 (1995).

    Article  CAS  Google Scholar 

  7. A. A. Merkulov and L. I. Isaenko, Proceedings of the 5 th International Conf. “Crystals: Growth, Properties, Real Structure, and Applications,” VNIISIMS, Alexandrov (2001), pp. 70–77.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Mineralogy and Petrography, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    A. A. Merkulov, L. I. Isaenko, V. M. Pashkov & V. G. Mazur

  2. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    A. V. Virovets & D. Yu. Naumov

Authors
  1. A. A. Merkulov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. I. Isaenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Pashkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. G. Mazur
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. V. Virovets
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. D. Yu. Naumov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text Copyright © 2005 by A. A. Merkulov, L. I. Isaenko, V. M. Pashkov, V. G. Mazur, A. V. Virovets, and D. Yu. Naumov

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 1, pp. 106–110, January–February, 2005.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Merkulov, A.A., Isaenko, L.I., Pashkov, V.M. et al. Crystal structure of KPb2Cl5 and KPb2Br5 . J Struct Chem 46, 103–108 (2005). https://doi.org/10.1007/s10947-006-0015-3

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10947-006-0015-3

Keywords

Search

Navigation