Skip to main content
Log in

New Route for Devulcanization of Natural Rubber and the Properties of Devulcanized Rubber

  • Original Paper
  • Published:
Journal of Polymers and the Environment Aims and scope Submit manuscript

Abstract

Devulcanization of natural rubber (NR) compound was carried out by means of benzoyl peroxide as a devulcanizing agent by two different techniques namely (a) chemical process and (b) mechano-chemical process. Furthermore, the effects of time and concentration of devulcanizing agent on the devulcanization process were investigated. The extent of devulcanization of natural rubber was studied by estimation of percent devulcanization, volume fraction of rubber after swelling, Mooney viscosity and crosslinked density. The devulcanized natural rubber obtained from mechano-chemical process was blended with virgin natural rubber in different proportions. The mechanical properties and morphology of the revulcanized blends were examined and found to be interesting. Thus, waste rubber could be reused successfully by this technique.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Das S, Curlee TR, Rizy CG, Schexnayder SM (1995) Resour Conserv Recycl 14:265

    Article  Google Scholar 

  2. Jang JW, Yoo TS, Oh JH, Iwasaki T (1998) Resour Conserv Recycl 22:1

    Article  Google Scholar 

  3. Wena L, Lin CH, Lee SC (2009) Waste Manag 29:2248

    Article  Google Scholar 

  4. Warner WC (1994) Rubber Chem Technol 67:559

    Article  CAS  Google Scholar 

  5. Klingensmith B (1991) Rubber World 16:203

    Google Scholar 

  6. Tolonen EO (1992) US patent 5 115:988

  7. Garmater RA (1994) US patent 5 299:744

  8. Drozdovskii VF (1998) Prog Rubber Plast Teclmol 14:116

    CAS  Google Scholar 

  9. Mastral AM, Callen MS, Murillo R, Garcia T (1999) Environment Sci Teclmol 33:4155

    Article  CAS  Google Scholar 

  10. Pelofsky AH (1973) US patent 3 725:314

  11. Okuda M, Hatano Y, (1987) Japanese patent 62 121: 741

  12. Isayev AI, Chen J, Tukachinsky A (1995) Rubber Chem Technol 68:267

    Article  CAS  Google Scholar 

  13. Yun J, Isayev AI, Kim SH, Tapale M (2003) J Appl Polym Sci 88:434

    Article  CAS  Google Scholar 

  14. Dubey V, Pandey SK, Rao NBSN (1995) J Anal Appl Pyroyl 34:111

    Article  CAS  Google Scholar 

  15. Novotny BS, Marsh RL, Masters FC, Tally DN (1978) US patent 4 104: 205

  16. Fix SR (1980) Elastomerics 112:38

    CAS  Google Scholar 

  17. Tantayanon S, Juikham S (2003) J Appl Polym Sci 91:510

    Article  Google Scholar 

  18. Murtland WO (1978) Elastomerics 26:110

    Google Scholar 

  19. Phadke AA, De SK (1986) Conserv Recycl 9:271

    Article  CAS  Google Scholar 

  20. Linos A, Steinbüchel A (1998) Kautschuk Gummi Kunststoffe 51:496

    CAS  Google Scholar 

  21. Tsuchii A, Suzuki T, Takeda K (1985) Appl Env Microb 50:965

    CAS  Google Scholar 

  22. Tsuchii A (1990) Appl Env Microb 56:269

    CAS  Google Scholar 

  23. Rouse MW (1992) Rubber World 25:206

    Google Scholar 

  24. Srinivasan A, Sanmugharaj AM, Bhowmick AK (2007) In:Bhowmick AK (ed) Current Topics in Elastomer Research, Taylor and Francis Group, LLC, USA

  25. Rebmann A (1948) Swiss Patent 215:952

    Google Scholar 

  26. Tukachinsky A, Schworm D, Isayev AI (1996) Rubber Chem Technol 69:92

    Article  CAS  Google Scholar 

  27. Levin VY, Kim SH, Isayev AI, Massey J, Meerwall E (1996) Rubb Chem Technol 69:104

    Article  CAS  Google Scholar 

  28. Hong CK, Isayev AI (2002) J Mat Sci 37:385

    Article  CAS  Google Scholar 

  29. Masaki K (2004) J Appl Polym Sci 91:3342

    Article  CAS  Google Scholar 

  30. Elgin JC (1949) Can Patent 456789

  31. Webb FJ, Cook WS, Albert HE, Smith GEP (1954) Ind Engg Chem 46:1711

    Article  CAS  Google Scholar 

  32. Meyer KH, Hohenemser W (1936) Rubber Chem Technol 9:201

    Article  CAS  Google Scholar 

  33. Yamashita S, Kawabata N, Sagan S, Hayashi K (1977) J Appl Polym Sci 21:2201

    Article  CAS  Google Scholar 

  34. Jacob C, De PP, Bhowmick AK, De SK (2001) J Appl Polym Sci 82:3293

    Article  CAS  Google Scholar 

  35. Jacob C, De PP, Bhowmick AK, De SK (2003) J Appl Polym Sci 87:2204

    Article  CAS  Google Scholar 

  36. Rajan VV, Dierkes WK, Noordermeer JWM, Joseph R (2005) Rubber Chem Technol 78:572

    Article  CAS  Google Scholar 

  37. De D, Adhikari B, Maiti S (1997) J Polym Mater 14:333

    CAS  Google Scholar 

  38. Maridass B, Gupta BR (2003) Kautschuk Gummi Kunststoff 56:232

    CAS  Google Scholar 

  39. Goldshtein V, Kopylov M (2003) US patent 6541526

  40. Jalilvand AR, Ghasemi I, Karrabi M, Azizi H (2007) Iranian Polym J 16:327

    CAS  Google Scholar 

  41. Holst O, Stenberg B, Christiansson M (1998) Biodegradation 9:301

    Article  CAS  Google Scholar 

  42. Mouri M, Okamoto H, Matsushita M, Honda H, Nakashima K, Takeushi K, Suzuki Y, Owaki M (2000) Int Polym Sci Technol 27 T/17

  43. Sutanto P, Picchioni F, Janssen LPBM (2006) J Appl Polym Sci 102:5028

    Article  CAS  Google Scholar 

  44. Je KL, Chang DH (2000) Polymer 41:1799

    Article  Google Scholar 

  45. Kader MA, Bhowmick AK, Inoue T, Chiba T (2002) J Mat Sci 37:1503

    Article  CAS  Google Scholar 

  46. Goldshtein V (2002) US Patent 6 387: 966

  47. Goldshtein V (2003) US Patent 6, 541: 526

  48. www.ecserrubber.com/COUNTERCURE.pdf. Accessed 10 Jan 2010

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Anil K. Bhowmick.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rooj, S., Basak, G.C., Maji, P.K. et al. New Route for Devulcanization of Natural Rubber and the Properties of Devulcanized Rubber. J Polym Environ 19, 382–390 (2011). https://doi.org/10.1007/s10924-011-0293-5

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10924-011-0293-5

Keywords

Navigation