Abstract
For the first time, gliadin films with excellent strength and water stability have been developed without using any crosslinking agents. So far, it has not been possible to obtain water stable gliadin films even after crosslinking. In this research, a novel method of using aqueous urea and ethanol has been developed to obtain highly water stable gliadin films without using crosslinking chemicals. The effects of concentrations of gliadin, urea and ethanol on the strength of the films and the stability of the films in water at high temperatures and various pH conditions has been studied. Gliadin films developed in this research have strength of about 30 MPa similar to the strength of previously reported gliadin films crosslinked with aldehydes and cysteine. Gliadin films obtained in this research were stable in pH 7.2 water at 50 °C for 20 days. The gliadin films did not dissolve in 70% ethanol which readily dissolves gliadin powder.
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References
Gennadios A, Rhim JW, Handa A, Weller CL, Hanna MA (1998) J Food Sci 63(2):1
Roy S, Weller CL, Gennadios A, Zeece MG, Testin RF (199) J Food Sci 64(1):57
Munoz PH, Kanavouras A, Villalobos R, Chiralt AJ (2004) J Agric Food Chem 52:7897
Munoz PH, Rubio A, Lagaron JM, Gavara R (2004) Biomacromolecules 5:415
Munoz PH, Villalobos R, Chiralt A (2004) Food Hydrocoll 18:403
Yang Y, Wang L, Li S (1996) J Appl Polym Sci 59(3):433
Zhang X, Min BG, Kumar S (2003) J Appl Polym Sci 90(3):716
Reddy N, Yang Y (2007) Biomacromolecules 8:638
Reddy N, Yang Y (2008) J Mater Sci Mater Med 19:2055
Huang HC, Hammond EG, Reitmeier CA, Myers DJ (1995) J Am Oil Chem Soc 72(12):1453
Lens JP, Mulder WJ, Kolster P (1999) Cereal Food World 44(1):5
Park SK, Bae DH, Rhee KC (2000) J Am Oil Chem Soc 77(8):879
Munoz P, Kanavouras A, Lagaron JM, Gavara R (2005) J Agric Food Chem 53:8216
Beckwith AC, Wall JS, Jordan RW (1965) Arch Biochem Biophys 112:16
Larrubial MA, Ramis G, Busca G (2000) Appl Catal B 27:145
Grosskreutz JC (1960) Biochim Biophys Acta 38:400
Traub W, Hutchinson JB, Daniels DGH (1957) Nature 179:769
Acknowledgements
This research was partially supported with funds from Nebraska Wheat Board, The Consortium for Plant Biotechnology Research, Inc by DOE prime agreement No. DE-FG36-02G012026, Archer Daniel Midland Company, USDA Hatch Act, the Agricultural Research Division at the University of Nebraska-Lincoln and by Multi State Research Project S-1026. The financial sponsors do not endorse the views expressed in this publication.
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Reddy, N., Yang, Y. Developing Water Stable Gliadin Films Without Using Crosslinking Agents. J Polym Environ 18, 277–283 (2010). https://doi.org/10.1007/s10924-010-0193-0
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DOI: https://doi.org/10.1007/s10924-010-0193-0