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Two 3D Coordination Polymers with New Topology Based on Mixed Ligands: Synthesis, Structure, and Photoluminescence Properties

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Abstract

Employing tetracarboxylate and imidazole mixed ligands to react with different transition meat salts afford two new 3D coordination polymers, {[Zn2(BPTC)(BBI)2]·(H2O)3·DMSO}n (1) and {[Cd2(BPTC)(BBI)2]·H2O}n (2) (H4BPTC = biphenyl-3,3′,4,4′-tetracarboxylic acid, BBI = 1,1′-(1,4-butanediyl)bis(imidazole)). Both these two coordination polymers are 4-connected network topologies. Compound 1 features a unprecedented 3-nodal (4,4,4)-connected network topology with the point symbol {64·82}, and 2 displays a (4,4)-connected binodal network bearing new topology with the point symbol of {72·84}2{73·83}. Additionally, thermal stability and photoluminescence properties of 1 and 2 were investigated.

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Acknowledgements

This work was supported by the National Natural Science Foundations of China (No. 21263014), the Natural Science Foundations of Jiangxi Province (Nos. 2011ZBAB203013 and 20122BAB203010), and the Foundation of Educational Department of Jiangxi Province (No. GJJ12103).

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Correspondence to Shengjun Deng or Ning Zhang.

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Wang, T., Ji, J., Deng, S. et al. Two 3D Coordination Polymers with New Topology Based on Mixed Ligands: Synthesis, Structure, and Photoluminescence Properties. J Inorg Organomet Polym 28, 1439–1445 (2018). https://doi.org/10.1007/s10904-018-0810-2

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