Skip to main content
SpringerLink
Log in

MnCrxFe2−xO4 Nanoparticles: Magnetic and Microwave Absorption Properties

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Chromium substituted Mn nanospinel ferrites having the formula MnCrxFe2−xO4 (0.0 ≤ x ≤ 1.0) have been synthesized using the microwave-assisted combustion synthesis. The composition, structural, spectroscopic features of the products were studied by X-ray powder diffractometry (XRD), Fourier transform infrared spectroscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy. XRD investigations indicated the formation of single-phased cubic spinel structure for all products. Lattice parameters of the products represented the continuous decrease with increasing the substitution of Cr3+. The saturation magnetization of undoped sample appeared to be highest and as Cr3+ concentration increases magnetization of the samples decreases. There is one reflection loss minimum in all doped samples at around 13 GHz with magnitude of −12 dB mechanism of which is explained by quarter wave cancellation model.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. S.H. Hosseini, S.H. Mohseni, A. Asadniac, H. Kerdari, J. Alloys Compd. 509, 4682–4687 (2011)

    Article  CAS  Google Scholar 

  2. F. Rena, G. Zhu, P. Ren, K. Wang, X. Cui, X. Yan, Appl. Surf. Sci. 351, 40–47 (2015)

    Article  Google Scholar 

  3. X. Ren, G. Xu, J. Magn. Magn. Mater. 354, 44–48 (2014)

    Article  CAS  Google Scholar 

  4. Robert C. Pullar, Prog. Mater. Sci. 57, 1191–1197 (2012)

    Article  CAS  Google Scholar 

  5. Vincent G. Harris, Microwav. Handb. Magn. Mater. 20, 1–63 (2012)

    Article  CAS  Google Scholar 

  6. M.B. Mohamed, K. El Sayed, Compos. Part B 56, 270–278 (2014)

    Article  CAS  Google Scholar 

  7. H. MeiXiao, X.M. Liu, S.Y. Fu, Compos. Sci. Technol. 66, 2003–2010 (2006)

    Article  Google Scholar 

  8. A.A. Thant, S. Srimala, P. Kaung, M. Itoh, O. Radzali, M.N. Ahmad Fauzi, J. Aust. Ceram. Soc. 46, 11–14 (2010)

    CAS  Google Scholar 

  9. A. Baykal, N. Kasapoğlu, Y. Köseoğlu, A.C. Başaran, H. Kavas, M.S. Toprak, Cent. Eur. J. Chem. 6, 125–130 (2008)

    Article  CAS  Google Scholar 

  10. A. Manikandan, M. Durka, K. Seevakan, J. Supercond. Novel Magn. 28, 1405–1416 (2015)

    Article  CAS  Google Scholar 

  11. A. Manikandan, M. Durka, S.A. Antony, J. Supercond. Novel Magn. 28, 209–218 (2015)

    Article  CAS  Google Scholar 

  12. A. Manikandan, M. Durka, S.A. Antony, J. Supercond. Novel Magn. 28, 2047–2058 (2015)

    Article  CAS  Google Scholar 

  13. N. Kasapoğlu, A. Baykal, Y. Köseoğlu, M.S. Toprak, Scr. Mater. 57, 441–444 (2007)

    Article  Google Scholar 

  14. M. Sertkol, Y. Köseoğlu, A. Baykal, H. Kavas, M.S. Toprak, J. Magn. Magn. Mater. 322, 866–871 (2010)

    Article  CAS  Google Scholar 

  15. J. Kong, Y. Wei, J. Li, J. Huang, T. Wang, Adv. Powder Technol. 26, 778–782 (2015)

    Article  CAS  Google Scholar 

  16. A.K. Rathi, M.J.B. Gawande, R. Zboril, R.S. Varm, Coord. Chem. Rev. 291, 68–94 (2015)

    Article  CAS  Google Scholar 

  17. B.L. Hayes, Aldrichim. Acta 37, 66–74 (2004)

    CAS  Google Scholar 

  18. C.S. Lim, Mater. Chem. Phys. 131, 714–718 (2012)

    Article  CAS  Google Scholar 

  19. Y. Liu, J.J. Li, F.F. Min, J.B. Zhu, M.X. Zhang, J. Magn. Magn. Mater. 354, 295–298 (2014)

    Article  CAS  Google Scholar 

  20. D.R. Mane, U.N. Devatwal, K.M. Jadhav, Mater. Lett. 44, 91–98 (2000)

    Article  CAS  Google Scholar 

  21. C.G. Whinfrey, D.W. Eskart, A. Tauber, J. Am. Chem. Soc. 82, 2695–6701 (1960)

    Article  CAS  Google Scholar 

  22. M.A. Gabal, Y.M. Al-Angari, Mater. Chem. Phys. 115, 578–585 (2009)

    Article  CAS  Google Scholar 

  23. M.J. Iqbal, M.R. Siddiquah, J. Alloys Compd. 453, 513–518 (2008)

    Article  CAS  Google Scholar 

  24. M.A. Gabal, Y.M. Al Angari, J. Magn. Magn. Mater. 322, 3159–3165 (2010)

    Article  CAS  Google Scholar 

  25. M. Mohan, I.A. Shaikh, R.C. Kulkarni, Phys. B 217, 292–298 (1996)

    Article  CAS  Google Scholar 

  26. R.D. Shannon, Acta Crystallogr. A 32, 560–751 (1976)

    Article  Google Scholar 

  27. L. Vegard, Z. Phys. 5, 17–25 (1921)

    Article  CAS  Google Scholar 

  28. K.H. Jani, M.C. Chhantbar, H.H. Joshi, J. Magn. Magn. Mater. 320, 2208–2214 (2008)

    Article  CAS  Google Scholar 

  29. F.C. Romeijn, Philips Res. Rep. 8, 304–309 (1953)

    CAS  Google Scholar 

  30. A. Goldman, Modern Ferrite Technology (Springer, New York, 2005)

    Google Scholar 

  31. A. Yang, C.N. Chinnasamy, J.M. Greneche, Y. Chen, S.D. Yoon, K. Hsu, C. Vittoria, V.G. Harris, Appl. Phys. Lett. 94, 113109–113114 (2009)

    Article  Google Scholar 

  32. P.J. van der Zaag, V.A.M. Brabers, M.T. Johnson, A. Noordermeer, P.F. Bongers, Phys. Rev. B 51, 12009–12011 (2011)

    Google Scholar 

  33. S. Jauhar, S. Singhal, Ceram. Int. 40, 11845–11855 (2014)

    Article  CAS  Google Scholar 

  34. M. Vadivel, R.R. Babu, K. Sethuraman, M. Arivanandhan, J. Magn. Magn. Mater. 62, 122–129 (2014)

    Article  Google Scholar 

  35. R.D. Waldron, Phys. Rev. 99, 1727–1732 (1955)

    Article  CAS  Google Scholar 

  36. F.A. Lopez, A. Lopez-Delgado, J.L. Martın de Vidales, E. Vila, J. Alloys Compd. 265, 291–296 (1998)

    Article  CAS  Google Scholar 

  37. F. Gözüak, Y. Köseoğlu, A. Baykal, H. Kavas, J. Magn. Magn. Mater. 321, 2170–2177 (2009)

    Article  Google Scholar 

  38. Y. Köseoğlu, A. Baykal, F. Gözüak, H. Kavas, Polyhedron 28, 2887–2892 (2009)

    Article  Google Scholar 

  39. Md Amir, B. Unal, E.S. Shirsath, M. Geleri, M. Sertkol, A. Baykal, Superlattices Microstruct. 85, 747–760 (2015)

    Article  CAS  Google Scholar 

  40. A.M. Wahba, M.B. Mohamed, Ceram. Int. 40, 6127–6135 (2014)

    Article  Google Scholar 

  41. M. Han, C.R. Vestal, Z.J. Zhang, J Phys Chem B 108, 583–587 (2004)

    Article  CAS  Google Scholar 

  42. A.A. Birajdar, S.E. Shirsath, R.H. Kadam, S.M. Patange, D.R. Mane, A.R. Shitre, Ceram. Int. 38, 2963–2970 (2012)

    Article  Google Scholar 

  43. A.M. Sankpal, S.S. Suryavanshi, S.V. Kakatkar, G.G. Tengshe, R.S. Patil, N.D. Chaudhari, S.R. Sawant, J. Magn. Magn. Mater. 186, 349–355 (1998)

    Article  CAS  Google Scholar 

  44. H. Sozeri, Z. Durmus, A. Baykal, Mater. Res. Bull. 47, 2442–2448 (2012)

    Article  CAS  Google Scholar 

  45. Y. Yafet, C. Kittel, Phys. Rev. 87, 290–296 (1952)

    Article  CAS  Google Scholar 

  46. J. Xie, M. Han, L. Chen, R. Kuang, L. Deng, J. Magn. Magn. Mater. 314, 37–43 (2007)

    Article  CAS  Google Scholar 

  47. B. Viswanathan, V.R.K. Murthty, Ferrite Materials Science and Technology (Springer-Verlag Narosa Publishing House, New York, 2000), pp. 28–60

    Google Scholar 

  48. A.N. Yusoff, M.H. Abdulla, S.H. Ahmad, S.F. Jusoh, A.A. Mansor, S.A.A. Hamid, J. Appl. Phys. 92, 876–882 (2002)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by TUBITAK (The Scientific and Technological Research Council of Turkey) with Project Number 213M174 and by Fatih University under BAP Grant No: P50021301-Y (3146).

Author information

Authors and Affiliations

  1. Chemistry Department, Fatih University, Büyükçekmece, 34500, Istanbul, Turkey

    A. Baykal & A. Z. Elmal

  2. TUBITAK-UME, National Metrology Institute, 41470, Gebze, Kocaeli, Turkey

    F. Genç & H. Sözeri

  3. Physics Department, Gebze Technical University, 41400, Gebze, Kocaeli, Turkey

    S. Gökçe

  4. Department of Physics Engineering, Istanbul Technical University, Maslak, 34469, Istanbul, Turkey

    M. Sertkol

Authors
  1. A. Baykal
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. Genç
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Z. Elmal
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. Gökçe
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. Sertkol
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. H. Sözeri
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Baykal.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Baykal, A., Genç, F., Elmal, A.Z. et al. MnCrxFe2−xO4 Nanoparticles: Magnetic and Microwave Absorption Properties. J Inorg Organomet Polym 26, 134–141 (2016). https://doi.org/10.1007/s10904-015-0288-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-015-0288-0

Keywords

Search

Navigation