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A Novel Two-Dimensional CdII Coordination Polymer Based on Flexible Bis(triazole) and Benzene-1,3-diacetic Acid: Synthesis, Structure and Physical Properties

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Abstract

A novel coordination polymer [Cd2(PDA)2(OMTMB)(H2O)2]n (H2PDA = benzene-1,3-diacetic acid, OMTMB = 1,3-bis(1,2,4-triazol-1-ylmethyl)benzene) has been synthesized and characterized by IR spectra, elemental analysis and single crystal X-ray diffraction. The crystal structure of the title complex shows a novel two dimensional framework based on one-dimensional double-chains [Cd2(PDA)2]n containing 40-membered rings. Moreover, the layers are connected by two types of hydrogen bonds (O–H···O and C–H···O) and by C–H···π and O–H···π interactions to form a three-dimensional supramolecular structure. The thermal stability and photoluminescent property of the title complex have been investigated.

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References

  1. R. Chakrabary, P.S. Mukherjee, P.J. Stang, Chem. Rev. 111, 6810 (2011)

    Article  Google Scholar 

  2. D.T. Genna, A.G. Wong-Foy, A.J. Matzger, M.S. Sanford, J. Am. Chem. Soc. 135, 10586 (2013)

    Article  CAS  Google Scholar 

  3. J. Huang, W. Wang, H. Li, Catalysis. 3, 1526 (2013)

    CAS  Google Scholar 

  4. T.K. Kim, K.J. Lee, J.Y. Cheon, J.H. Lee, S.H. Joo, H.R. Moon, J. Am. Chem. Soc. 135, 8940 (2013)

    Article  CAS  Google Scholar 

  5. Z.Z. Lu, R. Zhang, Y.Z. Li, Z.J. Guo, H.G. Zheng, J. Am. Chem. Soc. 133, 4172 (2011)

    Article  CAS  Google Scholar 

  6. K. Sumida, D.L. Rogow, J.A. Mason, T.M. McDonald, E.D. Bloch, Z.R. Herm, T.-H. Bae, J.R. Long, Chem. Rev. 112, 724 (2012)

    Article  CAS  Google Scholar 

  7. C. Train, T. Nuida, R. Gheorghe, M. Gruselle, S. Ohkoshi, J. Am. Chem. Soc. 131, 16838 (2009)

    Article  CAS  Google Scholar 

  8. N. Xu, J. Yang, Y.-C. He, Y.-Y. Liu, J.-F. Ma, CrystEngComm 15, 7360 (2013)

    Article  CAS  Google Scholar 

  9. G.Z. Liu, X.D. Li, X.L. Li, L.Y. Wang, CrystEngComm 15, 2428 (2013)

    Article  CAS  Google Scholar 

  10. R.-M. Han, J.-F. Ma, Y.-Y. Liu, J. Yang, CrystEngComm 15, 5641 (2013)

    Article  CAS  Google Scholar 

  11. Y.-X. Zhang, J. Yang, W.-Q. Kan, J.-F. Ma, CrystEngComm 14, 6004 (2012)

    Article  CAS  Google Scholar 

  12. M.A. Braverman, R.L. LaDuca, Cryst. Growth Des. 7, 2343 (2007)

    Article  CAS  Google Scholar 

  13. X.-F. Xie, S.-P. Chen, Z.-Q. Xia, S.-L. Gao, Polyhedron 28, 679 (2007)

    Article  Google Scholar 

  14. H. Ge, L. Wang, Y. Yang, B. Li, Y. Zhang, J. Mol. Struct. 876, 288 (2008)

    Article  CAS  Google Scholar 

  15. H.-Y. Ge, Y. Yang, Y.-F. Peng, B.-L. Li, Y. Zhang, J. Coord. Chem. 65, 3372 (2012)

    Article  CAS  Google Scholar 

  16. G.M. Sheldrick, SHELXL-97: program for refining crystal structure refinement (University of Göttingen, Germany, 1997)

  17. M.D. Allendorf, C.A. Bauer, R.K. Bhakta, R.J.T. Houk, Chem. Soc. Rev. 38, 1330 (2009)

    Article  CAS  Google Scholar 

  18. C.S.B. Gomes, P.T. Gomes, M.T. Duarte, R.E. DiPaolo, A.L. Macanita, M.J. Calhorda, Inorg. Chem. 48, 11176 (2009)

    Article  CAS  Google Scholar 

  19. J. Guo, J.-F. Ma, B. Liu, W.-Q. Kan, J. Yang, Cryst. Growth Des. 11, 3609 (2011)

    Article  CAS  Google Scholar 

  20. Z. Zhang, J.-F. Ma, Y.-Y. Liu, W.-Q. Kan, J. Yang, CrystEngComm 15, 2009 (2013)

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. School of Chemistry & Chemical Engineering, Yancheng Teachers University, Yancheng, 224002, Jiangsu, People’s Republic of China

    Xiao-Juan Xu

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  1. Xiao-Juan Xu
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Correspondence to Xiao-Juan Xu.

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Xu, XJ. A Novel Two-Dimensional CdII Coordination Polymer Based on Flexible Bis(triazole) and Benzene-1,3-diacetic Acid: Synthesis, Structure and Physical Properties. J Inorg Organomet Polym 25, 606–610 (2015). https://doi.org/10.1007/s10904-014-0137-6

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  • DOI: https://doi.org/10.1007/s10904-014-0137-6

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