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A 3D Mesomeric Supramolecular Structure of a Cu(II) Coordination Polymer with 1,1′-Biphenyl-2,2′,3,3′-tetracarboxylic Acid and 5,5′-Dimethyl-2,2′-bipyridine Ligands

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Abstract

A novel metal–organic framework {[Cu(H2bptc)(cbpy)(H2O)]·(H2O)} n (1) has been hydrothermally synthesized through reaction of 1,1′-biphenyl-2,2′,3,3′-tetracarboxylic acid (H4bptc) with Cu(II) salt in the presence of ancillary nitrogen ligand 5,5′-dimethyl-2,2′-bipyridine (cbpy), and its structure was determined by X-ray diffraction and characterized by elemental analysis, and IR spectrum. The title compound crystallizes in monoclinic space group P21/c. Both right- and left-handed helices are detected in the structure. In the ab-plane, adjacent chains are homochiral and parallel to each other, which are connected together by hydrogen bonds to form a 2D supramolecular structure. The supramolecular layers with opposite chirality are arranged alternatively along the c-axis to form a 3D mesomeric supramolecular structure through π···π interactions. The thermal stability of the complex 1 was studied by thermal gravimetric and differential thermal analysis.

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Acknowledgments

The authors are grateful for financial support from the International Technology Cooperation Project of Science and Technology Department of Henan Province of China (No. 124300510050).

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  1. Institute of Environmental and Municipal Engineering, North China University of Water Conservancy and Electric Power, Zhengzhou, 450011, China

    Hai-Hua Li, Ning Ma & Kai-Hui Li

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  1. Hai-Hua Li
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  2. Ning Ma
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Correspondence to Kai-Hui Li.

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Li, HH., Ma, N. & Li, KH. A 3D Mesomeric Supramolecular Structure of a Cu(II) Coordination Polymer with 1,1′-Biphenyl-2,2′,3,3′-tetracarboxylic Acid and 5,5′-Dimethyl-2,2′-bipyridine Ligands. J Inorg Organomet Polym 22, 1320–1324 (2012). https://doi.org/10.1007/s10904-012-9767-8

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