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Direct Synthesis of CdO Nanoparticles from a Novel Nano-Rods Cadmium(II) 4,4-Difluoro-1-phenyl-1,3-butanedionate Nano Coordination Compound

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Abstract

A novel nano-rods cadmium(II) fluorine-substituted β-diketonate, [Cd(2,2′-bpy)(dfpb)2] (1), (2,2′-bpy = 2,2′-bipyridine; dfpb = 4,4-difluoro-1-phenyl-1,3-butandion) has been synthesized by a sonochemical method that produces the coordination compound with nano dimensions. The new nanostructure was characterized by scanning electron microscopy, X-ray powder diffraction (XRD) elemental analysis and IR spectroscopy. Compound 1 was structurally characterized by single crystal X-ray diffraction. The single-crystal structure of this complex shows that the coordination number of the CdII ions is six with two N-donor atoms from the 2,2′-bpy ligand and four O-donors from two dfpb. Self-assembly of the complex occurs through CH···F–C and π–π stacking interactions. The supramolecular features of 1 are controlled by weak directional intermolecular interactions. CdO nanoparticles were obtained by thermolysis of 1 at 180 °C with oleic acid as a surfactant. The average diameter of the nanoparticles was estimated by the Scherrer equation to be 20 nm. The morphology and size of the CdO samples were further observed using SEM.

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Acknowledgments

This work is funded by the World Class University Grant KRF R32-2008-000-20082-0 of the National Research Foundation of Korea.

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Authors and Affiliations

  1. WCU Nano Research Center, School of Mechanical Engineering, Yeungnam University, Gyongsan, 712-749, South Korea

    Younes Hanifehpour, Babak Mirtamizdoust & Sang Woo Joo

  2. Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    Younes Hanifehpour, Sanaz Mokhtari Asl & Babak Mirtamizdoust

Authors
  1. Younes Hanifehpour
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  2. Sanaz Mokhtari Asl
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  3. Babak Mirtamizdoust
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  4. Sang Woo Joo
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Correspondence to Sang Woo Joo.

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Hanifehpour, Y., Asl, S.M., Mirtamizdoust, B. et al. Direct Synthesis of CdO Nanoparticles from a Novel Nano-Rods Cadmium(II) 4,4-Difluoro-1-phenyl-1,3-butanedionate Nano Coordination Compound. J Inorg Organomet Polym 22, 923–928 (2012). https://doi.org/10.1007/s10904-012-9682-z

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  • DOI: https://doi.org/10.1007/s10904-012-9682-z

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