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Lanthanide Cluster Organic Frameworks Derived from Pyridine-2,6-dicarboxylate and Oxalate: Syntheses, Structures and Luminescence

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Abstract

Two novel cluster organic frameworks derived from pyridine-2,6-dicarboxylate (PDA) and oxalate (ox2−) have been hydrothermally made: [Eu3(SO4)(PDA)3(ox)0.5(H2O)5]·4H2O (1) and Er(PDA)(ox)0.5(H2O) (2). Compound 1 possesses one-dimensional chain structure constructed from the alternate linkage of tetranuclear [Eu4(SO4)2]8+ (Eu4) and dinuclear [Eu2(ox)]4+ (Eu2) clusters. Compound 2 is a two-dimensional layer based on dimeric [Er2(COO)2]2+ (Er2) cluster units. Interestingly, such layer can be intuitively viewed as the linkages of helical chains and oxalate. In these two compounds, all anions are bivalent, and the ratio of trivalent lanthanide ions to these dianions is 2:3. Furthermore, compound 1 exhibits strong red luminescence upon 276 nm excitation.

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Acknowledgments

This work was supported by the NSFC (Nos. 91122028, 21221001, and 50872133), the 973 Program (Nos. 2014CB932101 and 2011CB932504), the NSFC for Distinguished Young Scholars (No. 20725101).

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Authors and Affiliations

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China

    Wei-Hui Fang, Xiang-Li Jia & Guo-Yu Yang

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  1. Wei-Hui Fang
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  2. Xiang-Li Jia
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  3. Guo-Yu Yang
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Correspondence to Guo-Yu Yang.

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Fang, WH., Jia, XL. & Yang, GY. Lanthanide Cluster Organic Frameworks Derived from Pyridine-2,6-dicarboxylate and Oxalate: Syntheses, Structures and Luminescence. J Clust Sci 25, 1553–1565 (2014). https://doi.org/10.1007/s10876-014-0751-z

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