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1,1-Cyclohexanediacetate as New Bridging Ligand for Assembling of Homo- and Heterometallic Molecular Complexes with Cu II3 , Cu II2 Ln III2 (Ln = Sm or Gd) and Ni II2 Gd III2 Cores: Synthesis, Structure and Magnetic Properties

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Abstract

Interaction of [Cu2(Piv)4(HPiv)2] (Piv− = pivalate) with tetrabutylammonium salt of 1,1-cyclohexanediacetate (Chda2−) and 2,2-bipyridine (2,2′-bpy) in acetonitrile led to formation of the trinuclear homometallic complex [Cu3(2,2′-bpy)2(Chda)2(Piv)2]·2MeCN·0.4H2O (1·2MeCN·0.4H2O). In similar conditions but in presence of [Ln2(Piv)6(HPiv)7] tetranuclear heterometallic complexes [Ln III2 Cu II2 (2,2′-bpy)2(Chda)2(Piv)6] (Ln = SmIII, 2·2MeCN, or GdIII, 3·2MeCN·5H2O) and [Gd III2 Ni II2 (2,2′-bpy)2(Chda)2(Piv)6] (4) were synthesized. Carboxylic groups in Piv− and Chda2− act as bridges between the metal ions in all complexes. Temperature dependencies of magnetic susceptibilities and room-temperature solid-state ESR spectra of compounds 2·2MeCN, 3·2MeCN·5H2O, 4 were studied and analyzed.

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Acknowledgments

This work was supported by Russian Foundation for Basic Research (Nos. 13-03-00703, 14-03-01116, 14-03-31292, 13-03-12430, 13-03-00682, 14-03-90423, 14-03-31580), the Council on Grants of the President of the Russian Federation (Grant NSh-4773.2014.3, MK-2917.2014.3), the Target Programs for Basic Research of the Presidium of the Russian Academy of Sciences and joint grant of the National Academy of Sciences of Ukraine and Russian Foundation for Basic Research (Nos. 10-03-12U and 10-03-13U).

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Leninsky Prosp. 31, 119991, Moscow, GSP-1, Russian Federation

    Natalya Gogoleva, Ekaterina Zorina-Tikhonova, Grigory Aleksandrov, Anatoly Lermontov, Nikolay Efimov, Elena Ugolkova, Aleksey Sidorov, Vadim Minin, Vladimir Novotortsev & Igor Eremenko

  2. International Tomography Centre, Institutskaya Str. 3a, 630090, Novosibirsk, Russian Federation

    Artem Bogomyakov

  3. L. V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of the Ukraine, Prospekt Nauki 31, Kiev, 03028, Ukraine

    Sergey Kolotilov

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  1. Natalya Gogoleva
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Gogoleva, N., Zorina-Tikhonova, E., Aleksandrov, G. et al. 1,1-Cyclohexanediacetate as New Bridging Ligand for Assembling of Homo- and Heterometallic Molecular Complexes with Cu II3 , Cu II2 Ln III2 (Ln = Sm or Gd) and Ni II2 Gd III2 Cores: Synthesis, Structure and Magnetic Properties. J Clust Sci 26, 137–155 (2015). https://doi.org/10.1007/s10876-014-0740-2

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