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Synthesis, Crystal Structure, Luminescence, and Magnetic Properties of a New 4d–4f Heterometallic Architecture Based on Pyridine-3,4-Dicarboxylic Acid

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Abstract

A 4d–4f heterometallic coordination polymer, [AgEu(pydc)2]·2H2O (1) (H2pydc = pyridine-3,4-dicarboxylic acid), has been synthesized under hydrothermal conditions, and further characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complex 1 features a three-dimensional framework containing one-dimensional (1D) channels occupied by free water molecules, which is constructed from 1D inorganic heterometallic chains and linear pydc linkers. After removal of the water molecules from complex 1, the remaining material has high thermal stability. Moreover, the photoluminescence, and magnetic properties of 1 were also investigated.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 21271106), the Key Project of Chinese Ministry of Education (No. 210102) and the Qing Lan Project of Jiangsu Provincial Department of Education.

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Correspondence to Guang-Xiang Liu.

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Liu, GX. Synthesis, Crystal Structure, Luminescence, and Magnetic Properties of a New 4d–4f Heterometallic Architecture Based on Pyridine-3,4-Dicarboxylic Acid. J Clust Sci 24, 787–798 (2013). https://doi.org/10.1007/s10876-013-0573-4

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  • DOI: https://doi.org/10.1007/s10876-013-0573-4

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