Abstract
Two new 3D transition metal coordination polymers [Zn(1,3-BDC)(L)0.5] (1) and [Cu(5-AIP)(L)0.5] (2) [L = N,N′-di(3-pyridyl)succinamide, 1,3-H2BDC = 1,3-benzenedicarboxylic acid, 5-H2AIP = 5-aminoisophthalic acid] have been hydrothermally synthesized and structurally characterized by elemental analyses, IR, TG and single crystal X-ray diffraction analysis. In complex 1, two carboxyl groups with monodentate modes from two 1,3-BDC ligands connect two Zn(II) ions to form a dinuclear {Zn2} SBUs, then the adjacent {Zn2} SBUs are connected by two pairs of 1,3-BDC ligands and two L ligands to construct a 3D coordination network with the large square-shape grids. Finally, the complex 1 exhibits a 4-connected CdSO4 topology with the threefold interpenetrating feature. Complex 2 is a 3D coordination framework constructed by the ligands L and 5-AIP anions, which represents a binodal (3,8)-connected {42·6}2{44·610·79·85} topology. The different coordination modes of metal ions and two dicarboxylates play important roles in the formation of coordination frameworks for title complexes. In addition, the thermal stabilities, the fluorescent properties of complexes 1–2 and the electrochemical behavior of complex 2 modified carbon paste electrode have also been investigated.
Graphical Abstract
Two new 3D coordination polymers, [Zn(1,3-BDC)(L)0.5] (1) and [Cu(5-AIP)(L)0.5] (2), have been hydrothermally synthesized. Complex 1 represents a threefold interpenetrating CdSO4 topology, complex 2 exhibits a binodal (3,8)-connected {42·6}2{44·610·79·85} topology. The different coordination modes of metal ions and dicarboxylates play important roles in the formation of final structures for title complexes.
Similar content being viewed by others
References
Alexandrov EV, Blatov VA, Kochetkov AV, Proserpio DM (2011) CrystEngComm 13:3947–3958
Jiang HL, Tatsu Y, Lu ZH, Xu Q (2010) J Am Chem Soc 132:5586–5587
An J, Shade CM, Chengelis-Czegan DA, Petoud S, Rosi NL (2011) J Am Chem Soc 133:1220–1223
He YB, Xiang SC, Chen B (2011) J Am Chem Soc 133:14570–14572
Suh MP, Park HJ, Prasad TK, Lim DW (2012) Chem Rev 112:782–835
Zhang XM, Wang YQ, Song Y, Gao EQ (2011) Inorg Chem 50:7284–7294
Yoshizawa M, Klosterman JK, Fujita M (2009) Angew Chem Int Ed 48:3418–3438
Zhao L, Chu YL, He C, Duan CY (2014) Chem Commun 50:3467–3469
Liu GL, Qin YJ, Jing L, Wei GY, Li H (2013) Chem Commun 49:1699–1701
Li YW, Li JR, Wang LF, Zhou BY, Chen Q, Bu XH (2013) J Mater Chem A 1:495–499
Kreno LE, Leong K, Farha OK, Allendorf M, Van Duyne RP, Hupp JT (2012) Chem Rev 112:1105–1125
Wang GY, Yang LL, Li Y, Song H, Ruan WJ, Chang Z, Bu XH (2013) Dalton Trans 42:12865–12868
Wang XL, Luan J, Lin HY, Le M, Liu GC (2014) Dalton Trans 43:8072–8082
Wang XL, Mu B, Lin HY, Liu GC (2011) J Organomet Chem 696:2313–2321
Wang XL, Zhao HY, Lin HY, Liu GC, Fang JN, Chen BK (2008) Electroanalysis 20:1055–1060
Hsu YF, Hu HL, Wu CJ, Yeh CW, Proserpio DM, Chen JD (2009) CrystEngComm 11:168–176
Sheldrick GM (2008) Acta Crystallogr Sect A 64:112–122
Spek AL (2003) J Appl Crystallogr 36:7–13
Zhao FH, Jing S, Che YX, Zheng JM (2012) CrystEngComm 14:4478–4485
Wang HN, Meng X, Qin C, Wang XL, Yang GS, Su ZM (2012) Dalton Trans 41:1047–1053
Sie MJ, Chang YJ, Cheng PW, Kuo PT, Yeh CW, Cheng CF, Chen JD, Wang JC (2012) CrystEngComm 14:5505–5516
Sun GM, Luo F, Song YM, Tian XZ, Huang HX, Zhu Y, Yuan ZJ, Feng XF, Luo MB, Liu SJ, Xu WY (2012) Dalton Trans 41:11559–11561
Gong Y, Li J, Qin JB, Wu T, Cao R, Li JH (2011) Cryst Growth Des 11:1662–1674
Wang XL, Luan J, Lin HY, Lu QL, Xu C, Liu GC (2013) Dalton Trans 42:8375–8386
Gong Y, Wu T, Lin JH, Wang BS (2012) CrystEngComm 14:5649–5656
Zou JP, Peng Q, Wen ZH, Zeng GS, Xing QJ, Guo GC (2010) Cryst Growth Des 10:2613–2619
Wang XL, Luan J, Lin HY, Xu C, Liu GC, Zhang JW, Tian AX (2013) CrystEngComm 15:9995–10006
Gong Y, Wu T, Lin JH (2012) CrystEngComm 14:3727–3736
Cui YJ, Yue YF, Qian GD, Chen BL (2012) Chem Rev 112:1126–1162
Gao GG, Xu L, Wang WJ, An WJ, Qiu YF, Wang ZQ, Wang EB (2005) J Phys Chem B 109:8948–8953
Wang XL, Mu B, Lin HY, Liu GC, Tian AX, Yang S (2012) CrystEngComm 14:1001–1009
Acknowledgments
The supports of the National Natural Science Foundation of China (21171025), New Century Excellent Talents in University (NCET-09-0853), and Program of Innovative Research Team in University of Liaoning Province (LT2012020) are gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
10870_2015_570_MOESM1_ESM.doc
X-ray crystallographic files (CIF); selected bond distances and angles, figures, IR spectra, TG curves for complexes 1 and 2. (DOC 6413 kb)
Rights and permissions
About this article
Cite this article
Lin, HY., Le, M., Sui, FF. et al. Two New 3D Zn(II)/Cu(II) Coordination Polymers Based on N,N′-Di(3-pyridyl)succinamide and Two Different Aromatic Dicarboxylates: Syntheses, Crystal Structures and Properties. J Chem Crystallogr 45, 94–102 (2015). https://doi.org/10.1007/s10870-015-0570-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10870-015-0570-6