Skip to main content
SpringerLink
Log in

Synthesis and Crystal Structure of the Heteronuclear Decavanadates Complex: [Fe(phen)3]2·[V10O28]·15H2O

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

A new decavanadate metal complex [Fe(phen)3]2·[V10O28]·15H2O (phen = 1,10-phenanthroline) has been synthesized from a hydrothermal reaction and the crystal structure has been determined by means of single-crystal X-ray diffraction. The crystal structure analysis reveals that the polyoxoanions are decorated with the [Fe(phen)3]3+ cations, and that the water molecules play the bridge role on the packing modes. They are further contacted to form supramolecular networks through extensive hydrogen bonding.

Graphical Abstract

A new decavanadate metal complex [Fe(phen)3]2·[V10O28]·15H2O (phen = 1,10-phenanthroline) has been synthesized from a hydrothermal reaction and the crystal structure has been determined by means of single-crystal X-ray diffraction. The crystal structure analysis reveals that the polyoxoanions are decorated with the [Fe(phen)3]3+ cations, and that the water molecules play the bridge role on the packing modes. They are further contacted to form supramolecular networks through extensive hydrogen bonding.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Zhang XM, Chen XM (2003) Inorg Chem Commun 6:206–209

    Article  CAS  Google Scholar 

  2. Li GB, Yang SH, Xiong M, Lin JH (2004) Acta Cryst C 60:m612–m614

    Google Scholar 

  3. Wang L, Sun XP, Liu ML, Gao YQ, Gu W, Liu X (2008) J Cluster Sci 19:531–542

    Article  CAS  Google Scholar 

  4. Kumagai H, Arishima M, Kitagawa S, Ymada K, Kawata S, Kaizaki S (2002) Inorg Chem 41:1989–1992

    Article  CAS  Google Scholar 

  5. Rakovský E, Joniaková D, Gyepes R, Schwendt P, Mička Z (2005) Cryst Res Technol 40:719–722

    Article  Google Scholar 

  6. Liu YB, Duan LM, Yang XM, Xu JQ, Zhang QB, Lu YK, Liu J (2006) J Solid State Chem 179:122–129

    Article  CAS  Google Scholar 

  7. Sheldrick GM (2008) SADABS v2008/1. Bruker AXS Inc., Madison

    Google Scholar 

  8. Sheldrick GM (2008) Acta Cryst A64:112–122

    CAS  Google Scholar 

  9. Wilson AJ (1992) International table for X-ray crystallography, V. C, Kluwer Academic Publishers, Dordrecht (1992) Tables 6.1.1.4 (pp. 500-502) and 4.2.6.8 (pp. 219–222) respectively

  10. Li PZ, Lu XM, Liu B, Wang S, Wang XJ (2007) Inorg Chem 46:5823–5825

    Article  CAS  Google Scholar 

  11. Fujiwara T, Iwamoto E, Yamamoto Y (1984) Inorg Chem 23:115–117

    Article  CAS  Google Scholar 

  12. Zheng NF, Lu HW, Bu XH, Feng PY (2006) J Am Chem Soc 128:4528–4529

    Article  CAS  Google Scholar 

  13. Bukietyńska K, Krot K, Starynowicz P (2001) Transit Met Chem 26:311–314

    Article  Google Scholar 

  14. Chen L, Yue CY, Yuan DQ, Jiang FL, Hong MC (2007) Acta Crystallogr Sect E Struct Rep Online 63:m675–m677

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by Natural Science Foundation of Shandong Province (No. ZR2009BL019 and ZR2010BL025), State Key Laboratory of Inorganic Synthesis and Preparative Chemistry (JilinUniversity) (No. 2011-13), and MOE Key Laboratory of Analytical Chemistry for Life Science (Nanjing University) (No. KLACLS1002).

Author information

Authors and Affiliations

  1. Microscale Science Institute, Weifang University, Weifang, 261061, People’s Republic of China

    Haixing Liu, Yufeng Li & Fangfang Jian

  2. New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology, Qingdao, 266042, Shandong, People’s Republic of China

    Jing Wang & Fangfang Jian

Authors
  1. Haixing Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jing Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yufeng Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Fangfang Jian
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Fangfang Jian.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Liu, H., Wang, J., Li, Y. et al. Synthesis and Crystal Structure of the Heteronuclear Decavanadates Complex: [Fe(phen)3]2·[V10O28]·15H2O. J Chem Crystallogr 41, 1254–1257 (2011). https://doi.org/10.1007/s10870-011-0083-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-011-0083-x

Keywords

Search

Navigation