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Synthesis, Characterization and X-Ray Crystal Structure of the Tri Aqua (3-Hydroxy-5-Hydroxymethyl-2-Methylpyridine-4-Carboxaldehyde-3-Methylisotiosemicarbazone: k3, O3, N7, N10) Ni(II) Nitrate

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Abstract

The title complex triaqua (3-hydroxy-5-hydroxymethyl-2-methylpyridine-4-carboxaldehyde-3-methylisothiosemicarbazone-k3,O3,N7,N10)Ni(II) nitrate ([Ni(PLITSC)(H2O)3](NO3)2, 1) represents the second transition metal complex incorporating an isothiosemicarbazide-pyridoxal based Schiff base that has been crystallographically characterized. Complex 1 crystallizes in a P21/n space group, with lattice constants: a = 11.2254(1) Å, b = 12.9941(2) Å, c = 12.8663(2), β = 96,7713(5)°, V = 1863.64(4) Å3, Z = 4, F(000) = 1016, R 1 = 0.0681, wR 2 = 0.1201. The central Ni(II) cation is found in a six-coordinate octahedral geometry formed by the tridentate Schiff base ligand PLITSC and three water molecules. The identity of 1 was further confirmed by elemental analysis, IR spectra, and conductometric and magnetochemical measurements.

Index Abstract

The coordination sphere of the Ni(II) cation in the green, paramagnetic complex [Ni(C10H14N4O2S1)(H2O)3](NO3)2 (1, Fig. 1), which crystallizes in P21/n space group, consists of three water molecules and a single tridentate ligand (Schiff base) obtained from isothiosemicarbazide and pyridoxal (pyridoxal is 3-hydroxy-5-hydroxymethyl-2-methylpyridine-4-carboxaldehyde) moieties.

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Scheme 1
Scheme 2
Fig. 1
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Acknowledgments

The author acknowledges the Oxford Chemical Crystallography Service for the use of the instrumentation and many thanks to the D.J. Watkin research group for helpful discussions.

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Authors and Affiliations

  1. Departman za hemiju, Prirodno-matematicki fakultet, Trg Dositeja Obradovica 3, 21000, Novi Sad, Serbia

    Violeta Jevtovic

  2. Department of Chemistry, University of Oxford, Mansfield Road, Oxford, OX1 3TA, UK

    Dragoslav Vidovic

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  1. Violeta Jevtovic
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  2. Dragoslav Vidovic
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Correspondence to Violeta Jevtovic.

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Jevtovic, V., Vidovic, D. Synthesis, Characterization and X-Ray Crystal Structure of the Tri Aqua (3-Hydroxy-5-Hydroxymethyl-2-Methylpyridine-4-Carboxaldehyde-3-Methylisotiosemicarbazone: k3, O3, N7, N10) Ni(II) Nitrate. J Chem Crystallogr 40, 794–798 (2010). https://doi.org/10.1007/s10870-010-9746-2

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