Skip to main content
SpringerLink
Log in

A 2D In(III) Coordination Polymer with Extended In–OH–In Chains

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

A new indium(III) coordination polymer [In(OH)(Hpdc)(H2O)] n (1) H3pdc = 3,5-pyrazole-dicarboxylic acid) has been synthesized under hydrothermal condition and characterized by the elemental analysis and single crystal X-ray diffraction. X-ray diffraction analysis reveals that 1 (C5H5InN2O6) crystallizes in the monoclinic space group P21/n, and features an interesting 2D layer constructed by 1D In–Hpdc chains and μ 2-OH ligands. Unit cell parameters for 1: a = 10.406(2), b = 6.326(2), c = 11.631(2) Å, β = 104.0(1)°, and Z = 4.

Index Abstract

The title compound, [In(OH)(Hpdc)(H2O)] n (H3pdc = 3,5-pyrazole-dicarboxylic acid), was synthesized under hydrothermal condition by the treatment of InCl3·4H2O with 3,5-pyrazole-dicarboxylic acid and its crystal structure determined. Single crystal X-ray diffraction analysis reveals that the molecular structure of the title compound is an interesting 2D layer constructed by 1D In–Hpdc chains and μ2-OH ligands.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. (a) Tong ML, Chen XM, Ye BH, Ji LN (1999) Angew Chem Int Ed 38:2237. (b) Bu XH, Weng W, Du M, Chen W, Li JR, Zhang RH, Zhao LJ (2002) Inorg Chem 41:1007

  2. (a) Moulton B, Zaworotko MJ (2000) Chem Rev 101:1629. (b) Eddaoudi M, Moler DB, Li H, Chen B, Reineke TM, O’Keeffe M, Yaghi OM (2001) Acc Chem Res 34:319. (c) Lu WG, Su CY, Lu TB, Jiang L, Chen JM (2006) J. Am. Chem. Soc. 128:34

  3. Fujita M, Ibukuro F, Yamaguchi K, Ogura KJ (1995) Am Chem Soc 117:4175

    Article  CAS  Google Scholar 

  4. (a) Kahn O (2000) Acc Chem Res 33:647. (b) Ma Y, Han ZB, He YK, Yang LG (2007) Chem Commun 4107. (c) Han ZB, He YK, Ge CH, Ribas J, Xu L (2007) Daltron Trans 3020. (d) He YK, Han ZB, Ma Y, Zhang XD (2007) Inorg Chem Commun 10:829. (e) He YK, Han ZB (2007) Inorg Chem Commun 10:1523

  5. (a) Tong ML, Chen XM, Batten SR (2003) J Am Chem Soc 125:16170. (b) Zhang JP, Zheng SL, Huang XC, Chen XM (2003) Angew Chem Int Ed 43:206

  6. (a) Ludise RA (1962) Progress in inorganic chemistry, vol 3. Interscience, New York. (b) Rabenau A (1985) Angew Chem Int Ed 97:1017

  7. Lin ZZ, Jiang FL, Chen L, Yuan DQ, Hong MC (2005) Inorg Chem 44:73

    Article  CAS  Google Scholar 

  8. Liu YL, Eubank JF, Cairns AJ, Eckert J, Kravtsov VC, Luebke R, Eddaoudi M (2007) Angew Chem Int Ed 46:3278

    Article  CAS  Google Scholar 

  9. Lii KH, Huang YF (1999) Inorg Chem 38:1348

    Article  CAS  Google Scholar 

  10. Tian JL, Yan SP, Liao DZ, Jiang ZH, Cheng P (2003) Inorg Chem Commun 6:1025

    Article  CAS  Google Scholar 

  11. Pan L, Ching N, Huang XY, Li J (2001) Chem Eur J 7:4431

    Article  CAS  Google Scholar 

  12. Pan L, Huang XY, Li J (2000) J Solid State Chem 152:236

    Article  CAS  Google Scholar 

  13. Bentiss F, Roussel P, Drache M, Conflant P, Lagrenée M, Wignacourt JPJ (2004) Mol Struct 707:63

    Article  CAS  Google Scholar 

  14. (a) Sheldrick GM, SHELXTL97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997. (b) Sheldrick GM, SHELXS97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997; (c) Sheldrick GM (1990) Acta Crystallogr Sect A 46:467

  15. (a) Lin ZZ, Jiang FL, Chen L, Yuan DQ, Zhou YF, Hong MC (2005) Eur J Inorg Chem 77. (b) Lin ZZ, Jiang FL, Yuan DQ, Chen L, Zhou YF, Hong MC (2005) Eur J Inorg Chem 1927. (c) Volkringer C, Loiseau T (2006) Mater Res Bull 41:948. (d) Vougo-Zanda M, Wang XQ, Jacobson AJ (2007) Inorg Chem 46:8819. (e) Lin ZZ, Jiang FL, Chen L, Yue CY, Yuan DQ, Lan AJ, Hong MC (2007) Cryst Growth Des 7:1712. (f) Gómez-Lor B, Gutiérrez-Puebla E, Iglesias M, Monge MA, Ruiz-Valero C, Snejko N (2005) Chem Mater 17:2568

  16. (a) Liu YL, Kravtsov VC, Beauchamp DA, Eubank JF, Eddaoudi M (2005) J Am Chem Soc 127:7266. (b) Ramezanipour F, Aghabozorg H, Shokrollahi A, Shamsipur M, Stoeckli-Evans H, Soleimannejad J, Sheshmani S (2005) J Mol Struct 779:77. (c) Pal MK, Kushwah NP, Wadawale AP, Sagoria VS, Jain VK, Tiekink ERT (2007) J Solid State Chem 692:4237

    Google Scholar 

Download references

Acknowledgments

This work was granted financial support from the Program for Liaoning Excellent Talents in University(RC-05-11).

Author information

Authors and Affiliations

  1. College of Chemistry, Liaoning University, Shenyang, 110036, Peoples’ Republic of China

    Yong-Juan Song, Zheng-Bo Han, Yong-Ke He & Peng Zhang

Authors
  1. Yong-Juan Song
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zheng-Bo Han
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yong-Ke He
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Peng Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Zheng-Bo Han.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Song, YJ., Han, ZB., He, YK. et al. A 2D In(III) Coordination Polymer with Extended In–OH–In Chains. J Chem Crystallogr 38, 891–894 (2008). https://doi.org/10.1007/s10870-008-9401-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-008-9401-3

Keywords

Search

Navigation