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X-ray structure and conformation of some enol acetates derived from simple ketones

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The conformational arrangements of a series of enol acetates derived from simple ketones have been examined by X-ray crystallography. For this series, the carbonyl enol motif was found to adopt a similar conformation.

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Acknowledgments

We are grateful to the Royal Society, the University of London Central Research Fund and Syngenta (Grangemouth, Scotland) for their financial support, the EPSRC National Mass Spectrometry Service (at Swansea, UK) for accurate mass determinations, and the EPSRC National Crystallographic Service (at Southampton, UK) for data collection on compound 5.

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Authors and Affiliations

  1. Syngenta, Grangemouth Manufacturing Centre, Earls Road, Grangemouth, FX3 8XG, Scotland

    Ewan Boyd & Ray V. H. Jones

  2. Department of Chemistry, Queen Mary, University of London, Mile End Road, London, E1 4NS, UK

    Svitlana Buksha, Gregory S. Coumbarides, Majid Motevalli & Michael J. Suggate

  3. Department of Chemistry, University of Hull, Cottingham Road, Kingston upon Hull, HU6 7RX, UK

    Marco Dingjan & Jason Eames

  4. Syngenta, Global Specialist Technology, P.O. Box A38, Leeds Road, Huddersfield, HD2 1FF, UK

    Rachel A. Stenson

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  1. Ewan Boyd
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Correspondence to Jason Eames.

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Boyd, E., Buksha, S., Coumbarides, G.S. et al. X-ray structure and conformation of some enol acetates derived from simple ketones. J Chem Crystallogr 37, 233–241 (2007). https://doi.org/10.1007/s10870-006-9081-9

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