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Synthesis and characterization of Bis(μ-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V)]. Crystal structure of Mo2O2(Φ-S2)[S2P(OMe)2]2.C6H6

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Bis(μ-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V) was prepared by dropwise addition of an ethanolic solution of the ammonium salt of O,O-dimethyldithio-phosphoric acid to a hot aqueous solution of MoCl5. The X-ray structure of Mo2O2(Φ-S2)[S2P(OMe)2]2.C6H6 was determined. Crystal data: Monoclinic, P21/n, a = 6.9788(6), b = 22.616(3), c = 14.633(1) Å, β = 101.193(9)°, V = 2265.5(4) Å−3, Z = 4. The immediate environment around the two molybdenum atoms is essentially square pyramidal if the Mo—Mo interaction is ignored. The terminal oxygen atoms are in the syn conformation.

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Acknowledgement

M.B.H. thanks the UK Engineering and Physical Sciences Council for support of the X-ray facilities at Southampton. J.E.D. thanks the University of Windsor for financial support. L. Awwal and R. Kumar thank the University Grants Commission, New Delhi for financial support.

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Authors and Affiliations

  1. Department of Pure and Applied Chemistry, M.D.S. University, Ajmer,, India

    L. Awwal, R. Kumar & R. Ratnani

  2. Department of Chemistry, University of Southampton, Highfield, Southampton,, UK

    A.L. Bingham, M.B. Hursthouse & M.E. Light

  3. Department of Chemistry and Biochemistry, University of Windsor, Windsor,, Ontario,, Canada

    J.E. Drake & R. Ratnani

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  1. L. Awwal
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  2. A.L. Bingham
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  7. R. Ratnani
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Correspondence to R. Ratnani.

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Awwal, L., Bingham, A., Drake, J. et al. Synthesis and characterization of Bis(μ-sulfido)bis[{O,O-dimethyldithiophosphato}oxomolybdenum(V)]. Crystal structure of Mo2O2(Φ-S2)[S2P(OMe)2]2.C6H6 . J Chem Crystallogr 36, 135–140 (2006). https://doi.org/10.1007/s10870-005-9030-z

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  • DOI: https://doi.org/10.1007/s10870-005-9030-z

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