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MoO3/γ-In2Se3 heterostructure photoanodes for enhanced photoelectrochemical water splitting

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Abstract

Developing efficient semiconductor photoanodes demonstrating strong light absorption, efficient separation of photogenerated charge carriers, and reduced charge carrier recombination rate can benefit PEC water splitting. Integrating a wide band gap semiconductor with narrow bandgap material with suitable band alignment can enhance PEC performance. Herein, we have fabricated novel MoO3/γ-In2Se3 heterostructure photoanodes using RF magnetron sputtering. The films structural, optical, morphological, and elemental composition were investigated in detail using low-angle XRD, Raman spectroscopy, XPS analysis, EDAX, and FESEM. The XRD, Raman, XPS, and EDAX results strongly confirmed the presence of desired phases of MoO3 and γ-In2Se3 layers in heterostructure without forming any impurity or alloy. FESEM micrographs revealed a uniform, dense grain structure. Optical analysis of MoO3/γ-In2Se3 done by UV–Visible spectroscopy shows increased absorption  compared  to pristine-MoO3. Conduction and valence band-edge potential values indicate that MoO3/γ-In2Se3 films are suitable for PEC hydrogen production. The PEC performance of these heterostructure photoanodes was evaluated by performing LSV, Chronoamperometry, EIS, and Mott–Schottky analysis. LSV results of MoO3/γ-In2Se3 showed a 10-fold increase in photocurrent density and attained higher photoconversion efficiency (0.5%) compared to pristine-MoO3 photoanode. EIS analysis revealed that MoO3/γ-In2Se3 photoanodes had small charge transfer resistance. Investigation of Mott Schottky results shows carrier density increases from 2.8 × 1019 cm−3 to 2.1 × 1020 cm−3 after incorporating γ-In2Se3 over MoO3. An increase in time-dependent photocurrent density reveals that MoO3/γ-In2Se3 films have effective electron-hole separation. Our finding suggests that MoO3/γ-In2Se3-based heterostructure photoanode can enhance light harvesting capacity and suppresses carrier recombination rate, eventually boosting PEC performance. Moreover, these results encourage the development of highly efficient photoelectrodes based on heterostructures for solar water-splitting applications.

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Data availability

The datasets used and analyzed during the current study are available from the corresponding author upon reasonable request.

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Acknowledgements

Ashish Waghmare, Yogesh Hase, Vidya Doiphode, Shruti Shah, Pratibha Shinde, Yogesh Hase, and Bharat Bade are thankful to the Ministry of New and Renewable Energy (MNRE), Government of India, for the financial support under the National Renewable Energy Fellowship (NREF) program Furthermore, Ashvini Punde is thankful to the Mahatma Jyotiba Phule Research and Training Institute (MAHAJYOTI), Government of Maharashtra, for the Mahatma Jyotiba Phule Research Fellowship (MJPRF). Swati Rahane is thankful for the research fellowship to the Chhatrapati Shahu Maharaj Research, Training and Human Development Institute (SARTHI), Government of Maharashtra. In addition, Vidhika Sharma, Mohit Prasad, and Sandesh Jadkar are grateful to Indo-French Centre for the Promotion of Advanced Research-CEFIPRA, Department of Science and Technology, New Delhi, for special financial support.

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Authors and Affiliations

  1. Department of Physics, Savitribai Phule Pune University, Pune, 411 007, India

    Ashish Waghmare, Vidhika Sharma, Pratibha Shinde, Shruti Shah, Ashvini Punde, Yogesh Hase, Bharat Bade, Vidya Doiphode, Swati Rahane, Somnath Ladhane & Sandesh Jadkar

  2. Department of Applied Science and Humanities, PCCOE, Pune, Nigdi, 411 004, India

    Mohit Prasad

  3. Department of Materials Engineering, Indian Institute of Science, Bangalore, 560 012, India

    Sachin Rondiya

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Contributions

AW: Methodology, Formal analysis, Investigation, Data curation, Writing—original draft. VS: Formal analysis, Data curation, Writing—original draft. PS: Conceptualization, Validation, Formal analysis, Investigation. SS: Methodology, Validation, Formal analysis, Investigation. AP: Methodology, Validation, Formal analysis, Investigation. YH: Methodology, Conceptualization, Validation, Formal analysis, Investigation. BB: Conceptualization, Validation, Formal analysis, Investigation.  VD: Methodology, Validation, Formal analysis, Investigation. SR: Data curation, Formal analysis, Investigation. SL: Data curation, Formal analysis, Investigation. MP: Data curation, Writing—Review, and Editing. SR: Methodology, Conceptualization, Validation, Investigation. SJ: Visualization, Writing—Review, Editing, Supervision, Funding acquisition.

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Correspondence to Mohit Prasad or Sandesh Jadkar.

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Waghmare, A., Sharma, V., Shinde, P. et al. MoO3/γ-In2Se3 heterostructure photoanodes for enhanced photoelectrochemical water splitting. J Mater Sci: Mater Electron 34, 1139 (2023). https://doi.org/10.1007/s10854-023-10526-3

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