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Fabrication of photoactive CaTiO3–TiO2 composite thin film electrodes via facile single step aerosol assisted chemical vapor deposition route

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Abstract

CaTiO3–TiO2 composite oxide films have been employed, for the first time, as photoelectrodes in photoelectrochemical (PEC) splitting of water. The transparent methanol solutions of Ti(iPro)4 and newly synthesized calcium complex [Ca2(TFA)3(OAc)(iPrOH)(H2O)(THF)3] (1) (where TFA stands for trifluoroacetato; OAc stands for acetate; and iPrOH stands for isopropanol) were utilized for aerosol assisted chemical vapor deposition (AACVD) of the target films. The composite electrodes were deposited on fluorine doped tin oxide (FTO) coated conducting glass substrates at varying deposition temperatures of 500–600 °C. The resulting films were extensively characterized by powder X-ray diffraction, X-ray photoelectron spectroscopy, energy dispersive X-ray analysis and scanning electron microscopy. PEC responses of all the composite electrodes were studied under simulated solar irradiation of AM 1.5 G (100 mW cm−2). The CaTiO3–TiO2 photoanode formed at 600 °C showed higher photocurrent density of 610 µA cm−2 at 0.7 V versus Ag/AgCl/3 M KCl reference electrode as compared to the other two electrodes fabricated similarly with only difference of fabrication temperature (i.e., 500 and 550 °C).

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References

  1. S. Chen, S.S. Thind, A. Chen, Electrochem. Commun. 63, 10–17 (2016)

    Article  Google Scholar 

  2. T. Hisatomi, J. Kubota, K. Domen, Chem. Soc. Rev. 43, 7520–7535 (2014)

    Article  Google Scholar 

  3. X. Zou, Y. Zhang, Chem. Soc. Rev. 44, 5148–5180 (2015)

    Article  Google Scholar 

  4. X. Chen, L. Liu, F. Huang, Chem. Soc. Rev. 44, 1861–1885 (2015)

    Article  Google Scholar 

  5. Y. Ma, X. Wang, Y. Jia, X. Chen, H. Han, C. Li, Chem. Rev. 114, 9987–10043 (2014)

    Article  Google Scholar 

  6. E. Kalamaras, V. Dracopoulos, L. Sygellou, P. Lianos, Chem. Eng. J. 295, 288–294 (2016)

    Article  Google Scholar 

  7. W. Wang, M.O. Tadé, Z. Shao, Chem. Soc. Rev. 44, 5371–5408 (2015)

    Article  Google Scholar 

  8. S.S. Arbuj, R.R. Hawaldar, S. Varma, S.B. Waghmode, B.N. Wani, Sci. Adv. Mater. 4, 568–572 (2012)

    Article  Google Scholar 

  9. N.P. Dasgupta, J. Sun, C. Liu, S. Brittman, S.C. Andrews, J. Lim, H. Gao, R. Yan, P. Yang, Adv. Mater. 26, 2137–2184 (2014)

    Article  Google Scholar 

  10. O.A. Jaramillo-Quintero, M.S. de la Fuente, R.S. Sanchez, I.B. Recalde, E.J. Juarez-Perez, M.E. Rincón, I. Mora-Seró, Nanoscale 8, 6271–6277 (2016)

    Article  Google Scholar 

  11. E. Grabowska, Appl. Catal. B 186, 97–126 (2016)

    Article  Google Scholar 

  12. T.W. Kim, K.-S. Choi, Science 343, 990–994 (2014)

    Article  Google Scholar 

  13. H. Zhang, G. Chen, Y. Li, Y. Teng, Int. J. Hydrogen Energy 35, 2713–2716 (2010)

    Article  Google Scholar 

  14. A. Mumtaz, N.M. Mohamed, M. Mazhar, M.A. Ehsan, M.S. Mohamed, Saheed, ACS Appl. Mater. Interfaces 8, 9037–9049 (2016)

    Article  Google Scholar 

  15. D. Sharma, S. Upadhyay, V.R. Satsangi, R. Shrivastav, U.V. Waghmare, S. Dass, ‎J. Phys. Chem. C 118, 25320–25329 (2014)

    Article  Google Scholar 

  16. W. Yang, Y. Yu, M.B. Starr, X. Yin, Z. Li, A. Kvit, S. Wang, P. Zhao, X. Wang, Nano Lett. 15, 7574–7580 (2015)

    Article  Google Scholar 

  17. K. Shimura, H. Yoshida, Energy Environ. Sci. 3, 615–617 (2010)

    Article  Google Scholar 

  18. A.A. Tahir, H.A. Burch, K.U. Wijayantha, B.G. Pollet, Int. J. Hydrogen Energy 38, 4315–4323 (2013)

    Article  Google Scholar 

  19. A.A. Tahir, M. Mat-Teridi, K. Wijayantha, Phys. Status Solidi Rapid Res. Lett. 8, 976–981 (2014)

    Article  Google Scholar 

  20. M. Mat-Teridi, A.A. Tahir, S. Senthilarasu, K. Wijayantha, M.Y. Sulaiman, N. Ahmad-Ludin, M.A. Ibrahim, K. Sopian, Phys. Status Solidi Rapid Res. Lett. 8, 982–986 (2014)

    Article  Google Scholar 

  21. M.A. Ehsan, H. Khaledi, A. Pandikumar, N.M. Huang, Z. Arifin, M. Mazhar, J. Solid State Chem. 230, 155–162 (2015)

    Article  Google Scholar 

  22. M.A. Mansoor, M.A. Ehsan, V. McKee, N.-M. Huang, M. Ebadi, Z. Arifin, W.J. Basirun, M. Mazhar, J. Mater. Chem. A 1, 5284–5292 (2013)

    Article  Google Scholar 

  23. A.A. Tahir, K.U. Wijayantha, S. Saremi-Yarahmadi, M. Mazhar, V. McKee, Chem. Mater. 21, 3763–3772 (2009)

    Article  Google Scholar 

  24. A.A. Tahir, T. Peiris, K. Wijayantha, Chem. Vap. Depos 18, 107–111 (2012)

    Article  Google Scholar 

  25. M.A. Ehsan, R. Naeem, V. McKee, A.S. Hakeem, M. Mazhar, Sol. Energy Mater Sol. Cells 161, 328–337 (2017)

    Article  Google Scholar 

  26. C. Han, J. Liu, W. Yang, Q. Wu, H. Yang, X. Xue, J. Sol-Gel Sci. Technol. 81, 806–813 (2017)

    Article  Google Scholar 

  27. J. Jang, P. Borse, J.S. Lee, K. Lim, O. Jung, E. Jeong, J. Bae, H. Kim, Bull. Korean Chem. Soc. 32, 95–99 (2011)

    Article  Google Scholar 

  28. X. Huang, Y. Xin, H. Wu, F. Ying, Y. Min, W. Li, S. Wang, Z.-j. Wu, Trans. Nonferr. Metals Soc. China 26, 464–471 (2016)

    Article  Google Scholar 

  29. J. Shi, L. Guo, Prog. Nat. Sci. Mater. 22, 592–615 (2012)

    Article  Google Scholar 

  30. H. Zhang, G. Chen, X. He, J. Xu, J. Alloys Compd. 516, 91–95 (2012)

    Article  Google Scholar 

  31. T. Xian, H. Yang, Y. Huo, Phys. Scr. 89, 115801 (2014)

    Article  Google Scholar 

  32. M. Eghbali-Arani, A. Sobhani-Nasab, M. Rahimi-Nasrabadi, F. Ahmadi, S. Pourmasoud, Ultrason. Sonochem. 43, 120–135 (2018)

    Article  Google Scholar 

  33. S. Pourmasoud, A. Sobhani-Nasab, M. Behpour, M. Rahimi-Nasrabadi, F. Ahmadi, J. Mol. Struct. 1157, 607–615 (2018)

    Article  Google Scholar 

  34. A. Sobhani-Nasab, Z. Zahraei, M. Akbari, M. Maddahfar, S.M. Hosseinpour-Mashkani, J. Mol. Struct. 1139, 430–435 (2017)

    Article  Google Scholar 

  35. C.B. Hübschle, G.M. Sheldrick, B. Dittrich, J. Appl. Crystallogr. 44, 1281–1284 (2011)

    Article  Google Scholar 

  36. G.M. Sheldrick, Acta Crystallogr. A 71, 3–8 (2015)

    Article  Google Scholar 

  37. G.M. Sheldrick, Acta Crystallogr. C 71, 3–8 (2015)

    Article  Google Scholar 

  38. X. Cai, Y. Wu, L. Wang, N. Yan, J. Liu, X. Fang, Y. Fang, Soft Matter. 9, 5807–5814 (2013)

    Article  Google Scholar 

  39. M. Veith, M. Haas, V. Huch, Chem. Mater. 17, 95–101 (2005)

    Article  Google Scholar 

  40. F.H. Allen, Acta Crystallogr. B 58, 380–388 (2002)

    Article  Google Scholar 

  41. M.A. Ehsan, H. Khaledi, A. Pandikumar, P. Rameshkumar, N.M. Huang, Z. Arifin, M. Mazhar, New J. Chem. 39, 7442–7452 (2015)

    Article  Google Scholar 

  42. A.A. Tahir, M.A. Ehsan, M. Mazhar, K.U. Wijayantha, M. Zeller, A. Hunter, Chem. Mater. 22, 5084–5092 (2010)

    Article  Google Scholar 

  43. D. Wei, Y. Zhou, D. Jia, Y. Wang, J. Biomed. Mater. Res. B 84, 444–451 (2008)

    Article  Google Scholar 

  44. S.-W. Lee, L. Lozano-Sánchez, V. Rodríguez-González, J. Hazard. Mater. 263, 20–27 (2013)

    Article  Google Scholar 

  45. D. Boukhvalov, D. Korotin, A. Efremov, E. Kurmaev, C. Borchers, I. Zhidkov, D. Gunderov, R. Valiev, N. Gavrilov, S. Cholakh, Phys. Status Solidi B 252, 748–754 (2015)

    Article  Google Scholar 

  46. H. Mizoguchi, K. Ueda, M. Orita, S.-C. Moon, K. Kajihara, M. Hirano, H. Hosono, Mater. Res. Bull. 37, 2401–2406 (2002)

    Article  Google Scholar 

  47. D.O. Scanlon, C.W. Dunnill, J. Buckeridge, S.A. Shevlin, A.J. Logsdail, S.M. Woodley, C.R.A. Catlow, M.J. Powell, R.G. Palgrave, I.P. Parkin, Nat. Mater. 12, 798–801 (2013)

    Article  Google Scholar 

  48. F. Hu, W. Chen, Electrochem. Commun. 13, 955–958 (2011)

    Article  Google Scholar 

  49. M.A. Mansoor, M. Mazhar, M. Ebadi, H.N. Ming, M.A.M. Teridi, L.K. Mun, New J. Chem. 40, 5177–5184 (2016)

    Article  Google Scholar 

  50. S.E. Stanca, R. Müller, M. Urban, A. Csaki, F. Froehlich, C. Krafft, J. Popp, W. Fritzsche, Catal. Sci. Technol. 2, 1472–1479 (2012)

    Article  Google Scholar 

  51. J. Ng, S. Xu, X. Zhang, H.Y. Yang, D.D. Sun, Adv. Funct. Mater. 20, 4287–4294 (2010)

    Article  Google Scholar 

  52. X. Yan, X. Huang, Y. Fang, Y. Min, Z. Wu, W. Li, J. Yuan, L. Tan, Int. J. Electrochem. Sci. 9, 5155–5163 (2014)

    Google Scholar 

  53. M. Ueda, S. Otsuka-Yao-Matsuo, Sci. Technol. Adv. Mater. 5, 187–193 (2004)

    Article  Google Scholar 

  54. T. Omata, S. Otsuka-Yao-Matsuo, J. Photochem. Photobiol. 156, 243–248 (2003)

    Article  Google Scholar 

  55. Z. Jin, X. Zhang, Y. Li, S. Li, G. Lu, Catal. Commun. 8, 1267–1273 (2007)

    Article  Google Scholar 

  56. A. Kudo, Y. Miseki, Chem. Soc. Rev. 38, 253–278 (2009)

    Article  Google Scholar 

  57. J. Zhang, J.H. Bang, C. Tang, P.V. Kamat, ACS Nano 4, 387–395 (2009)

    Article  Google Scholar 

  58. A. Kudo, H. Kato, I. Tsuji, Chem. Lett. 33, 1534–1539 (2004)

    Article  Google Scholar 

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Acknowledgements

The authors acknowledge the High-Impact Research scheme Grant Number: UM.C/625/1/HIR/242, FRGS Grant Number: FP039-2016, IPPP Grant Number: PG053-2016A and HIR-MOHE Grant Number: UM.S/P/628/3SC21 for funding. AR acknowledges the start up Grant Number: SR151005 from KFUPM.

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Authors and Affiliations

  1. Center of Research Excellence in Nanotechnology (CENT), King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia

    Muhammad Ali Ehsan & Abbas Saeed Hakeem

  2. Department of Chemistry, Government College University, Lahore, Pakistan

    Rabia Naeem

  3. School of Chemical Sciences, Dublin City University, Dublin 9, Glasnevin, Ireland

    Vickie McKee

  4. Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia

    Abdul Rehman

  5. Department of Environmental Sciences, Fatima Jinnah Women University, The Mall, Rawalpindi, 46000, Pakistan

    Muhammad Mazhar

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  1. Muhammad Ali Ehsan
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Correspondence to Muhammad Ali Ehsan.

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Ehsan, M.A., Naeem, R., McKee, V. et al. Fabrication of photoactive CaTiO3–TiO2 composite thin film electrodes via facile single step aerosol assisted chemical vapor deposition route. J Mater Sci: Mater Electron 30, 1411–1424 (2019). https://doi.org/10.1007/s10854-018-0411-4

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