Abstract
Bi2MoO6/reduced graphene oxide (RGO) composite nanofibers were successfully fabricated by calcining the electrospun polyvinyl pyrrolidone (PVP)/RGO/[(NH4)6Mo7O24 + Bi(NO3)3] composite nanofibers. The products were investigated in detail by X-ray diffractometer, scanning electron microscope, transmission electron microscope, UV–Vis diffuse reflectance spectroscope and X-ray photoelectron spectroscope. The as-prepared Bi2MoO6/RGO composite nanofibers are pure orthorhombic phase with space group of Pbca, and the diameter is 132 ± 18 nm. These nanocomposite samples display high photocatalytic hydrogen production activity in aqueous solutions containing methanol as sacrificial reagent under visible light irradiation. Bi2MoO6/5 % RGO composite nanofibers used as photocatalyst for water splitting exhibit the highest H2 evolution rate of 794.72 μmol h−1, which is improved by 2.86 times compared to Bi2MoO6 nanofibers. The enhancement of photocatalytic hydrogen production performance is due to addition of RGO, the intimate interfacial contact and large contact area between Bi2MoO6 nanoparticles and RGO sheets, which help to make full use of the electron conductivity of RGO for transferring the photogenerated electrons and separating the photoproduced carriers. Therefore the electrospinning is a facile and effective technique to fabricate Bi2MoO6/RGO composite nanofibers which could take advantage of solar energy to achieve efficient H2-evolution from water splitting.
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Y. Sung, J. Lim, J.H. Koh, L.J. Hill, B.K. Min, J. Pyun, K. Char, Uniform decoration of Pt nanoparticles on well-defined CdSe tetrapods and the effect of their Pt cluster size on photocatalytic H2 generation. CrystEngComm 17, 8423–8427 (2015)
T. Grewe, H. Tüysüz, Alkali metals incorporated ordered mesoporous tantalum oxide with enhanced photocatalytic activity for water splitting. J. Mater. Chem. A 4, 3007–3017 (2016)
A. Fujishima, K. Honda, Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37–38 (1972)
X.F. Zhou, Q.Z. Gao, X. Li, Y.J. Liu, S.S. Zhang, Y.P. Fang, J. Li, Ultra-thin SiC layers covered graphene nanosheets as dvanced photocatalysts for hydrogen evolution. J. Mater. Chem. A 3, 10999–11005 (2015)
M.Y. Wang, J. Ioccozia, L. Sun, C.J. Lin, Z.Q. Lin, Inorganic-modified semiconductor TiO2 nanotube arrays for photocatalysis. Energy Environ. Sci. 7, 2182–2202 (2014)
Y.H. Zhang, Y.J. Xu, Bi2WO6: a highly chemoselective visible light photocatalyst toward aerobic oxidation of benzylic alcohols in water. RSC Adv. 4, 2904–2910 (2014)
D.J. Martin, K. Qiu, S.A. Shevlin, A.D. Handoko, X.W. Chen, Z.X. Guo, J.W. Tang, Highly efficient photocatalytic H2 evolution from water using visible light and structure-controlled graphitic carbon nitride. Angew. Chem. Int. Ed. 53, 9240–9245 (2014)
S.J. Hu, B. Chi, J. Pu, L. Jian, Surface charge modification in improvement of photocatalytic H2 production over La2Ti2O7/graphene nanocomposite. RSC Adv. 4, 60437–60444 (2014)
F.K. Ma, G. Zhao, C. Li, T.L. Wang, Y.Z. Wu, J.X. Lv, Y.Y. Zhong, X.P. Hao, Fabrication of CdS/BNNSs nanocomposites with broadband solar absorption for efficient photocatalytic hydrogen evolution. CrystEngComm 18, 631–637 (2016)
M.Y. Zhang, C.L. Shao, J.B. Mu, X.M. Huang, Z.Y. Zhang, Z.C. Guo, P. Zhang, Y.C. Liu, Hierarchical heterostructures of Bi2MoO6 on carbon nanofibers: controllable solvothermal fabrication and enhanced visible photocatalytic properties. J. Mater. Chem. 22, 577–584 (2012)
X. Wang, Fei Gu, L. Li, G. L. Fang, X. Wang. A facile mixed-solvothermal route to γ-Bi2MoO6 nanoflakes and their visible-light-responsive photocatalytic activity. Mater. Res. Bull. 48, 3761–3765 (2013)
C. Belver, C. Adan, M.F. Garcia, Photocatalytic behaviour of Bi2MoO6 polymetalates for rhodamine B degradation. Catal. Today 143, 274–281 (2009)
M.Y. Zhang, C.L. Shao, J.B. Mu, Z.Y. Zhang, Z.C. Guo, P. Zhang, Y.C. Liu, One-dimensional Bi2MoO6/TiO2 hierarchical heterostructures with enhanced photocatalytic activity. CrystEngComm 14, 605–612 (2012)
Y. Shimodaira, H. Kato, H. Kobayashi, A. Kudo, Photophysical properties and photocatalytic activities of bismuth molybdates under visible light irradiation. J. Phys. Chem. B 110, 17790–17797 (2006)
Y.C. Miao, G.F. Pan, Y.N. Huo, H.X. Li, Aerosol-spraying preparation of Bi2MoO6: a visible photocatalyst in hollow microspheres with a porous outer shell and enhanced activity. Dyes Pigm. 99, 382–389 (2013)
M.Y. Zhang, C.L. Shao, P. Zhang, C.Y. Su, X. Zhang, P.P. Liang, Y.Y. Sun, Y.H. Liu, Bi2MoO6 microtubes: controlled fabrication by using electrospun polyacrylonitrile microfibers as template and their enhanced visible light photocatalytic activity. J. Hazard. Mater. 225–226, 155–163 (2012)
Y.S. Xu, W.D. Zhang, Monodispersed Ag3PO4 nanocrystals loaded on the surface of spherical Bi2MoO6 with enhanced photocatalytic performance. Dalton Trans. 42, 1094–1101 (2013)
M. Shang, W.Z. Wang, J. Ren, S.M. Sun, L. Zhang, Nanoscale Kirkendall effect for the synthesis of Bi2MoO6 boxes via a facile solution-phase method. Nanoscale 3, 1474–1476 (2011)
A. Martínez-de la Cruz, S. Obregón, Alfaro. Synthesis and characterization of γ-Bi2MoO6 prepared by co-precipitation: photoassisted degradation of organic dyes under vis-irradiation. J. Mol. Catal. A Chem. 320, 85–91 (2010)
F. Zhou, R. Shi, Y.F. Zhu, Significant enhancement of the visible photocatalytic degradation performances of γ-Bi2MoO6 nanoplate by graphene hybridization. J. Mol. Catal. A Chem. 340, 77–82 (2011)
H.P. Li, Q.H. Deng, J.Y. Liu, W.G. Hou, N. Du, R.J. Zhang, X.T. Tao, Synthesis, characterization and enhanced visible light photocatalytic activity of Bi2MoO6/Zn–Al layered double hydroxide hierarchical heterostructures. Catal. Sci. Technol. 4, 1028–1037 (2014)
J. Di, J.X. Xia, M.X. Ji, H.P. Li, H. Xu, H.M. Li, R. Chen, The synergistic role of carbon quantum dots for the improved photocatalytic performances of Bi2MoO6. Nanoscale 7, 11433–11443 (2015)
D. Chen, L. Tang, J. Li, Graphene-based materials in electrochemistry. Chem. Soc. Rev. 39, 3157–3180 (2010)
Q. Xiang, J.G. Yu, M. Jaroniec, Graphene-based semiconductor photocatalysts. Chem. Soc. Rev. 41, 782–796 (2012)
Y. Zhang, Y.K. Zhu, J.Q. Yu, D.J. Yang, T.W. Ng, P.K. Wong, J.C. Yu, Enhanced photocatalytic water disinfection properties of Bi2MoO6–RGO nanocomposites under visible light irradiation. Nanoscale 5, 6307–6310 (2013)
P.F. Wang, Y.H. Ao, C. Wang, J. Hou, J. Qian, A one-pot method for the preparation of graphene-Bi2MoO6 hybrid photocatalysts that are responsive to visible-light and have excellent photocatalytic activity in the degradation of organic pollutants. Carbon 50, 5256–5264 (2012)
X.J. Zhou, Q.L. Ma, W.S. Yu, T.T. Wang, X.T. Dong, J.X. Wang, G.X. Liu, Magnetism and white-light-emission bifunctionality simultaneously assembled into flexible janus nanofiber via electrospinning. J. Mater. Sci. 50, 7884–7895 (2015)
K. Lun, Q.L. Ma, M. Yang, X.T. Dong, Y. Yang, J.X. Wang, W.S. Yu, G.X. Liu, Color-tunable luminescence nanofibers endowed with simultaneously tuned electricity–magnetism performance. J. Mater. Sci.: Mater. Electron. 26, 5994–6003 (2015)
L. Han, M.M. Pan, Y. Lv, Y.T. Gu, X.F. Wang, D. Li, Q.L. Kong, X.T. Dong, Fabrication of Y2O2S:Eu3+ hollow nanofibers by sulfurization of Y2O3:Eu3+ hollow nanofibers. J. Mater. Sci.: Mater. Electron. 26, 677–684 (2015)
J. Tian, Q.L. Ma, X.T. Dong, M. Yang, Y. Yang, J.X. Wang, W.S. Yu, G.X. Liu, Flexible composite nanobelts: facile electrospinning construction, structure and color-tunable photoluminescence. J. Mater. Sci.: Mater. Electron. 26, 8413–8420 (2015)
K.S. Divya, T.U. Umadevi, S. Mathew, Graphene-based semiconductor nanocomposites for photocatalytic applications. J. Nanosci. Lett. 4, 21 (2014)
C. Hou, Q. Zhang, M. Zhu, Y. Li, H. Wang, One-step synthesis of magnetically-functionalized reduced graphite sheets and their use in hydrogels. Carbon 49, 47–53 (2011)
Y. Ma, Y.L. Jia, Z.B. Jiao, M. Yang, Y.X. Qi, Y.P. Bi, Hierarchical Bi2MoO6 nanosheet-built frameworks with excellent photocatalytic properties. Chem. Commun. 51, 6655–6658 (2015)
C.Y. He, R.H. Wang, H.G. Fu, P.K. Shen, Nitrogen-self-doped graphene as a high capacity anode material for lithium-ion batteries. J. Mater. Chem. A 1, 14586–14591 (2013)
W. Geng, X.F. Zhao, W.Y. Zan, H.X. Liu, X.J. Yao, Effects of the electric field on the properties of ZnO–graphene composites: a density functional theory study. Phys. Chem. Chem. Phys. 16, 3542–3548 (2014)
Z. Zhang, C. Shao, X. Li, Y. Sun, M. Zhang, J. Mu, P. Zhang, Z. Guo, Y. Liu, Hierarchical assembly of ultrathin hexagonal SnS2 nanosheets onto electrospun TiO2 nanofibers: enhanced photocatalytic activity based on photoinduced interfacial charge transfer. Nanoscale 5, 606–618 (2013)
C.H. Wang, C.L. Shao, Y.C. Liu, X.H. Li, Water-dichloromethane interface controlled synthesis of hierarchical rutile TiO2 superstructures and their photocatalytic properties. Inorg. Chem. 48, 1105–1113 (2009)
R.P. Panmand, Y.A. Sethi, S.R. Kadam, M.S. Tamboli, L.K. Nikam, J.D. Ambekar, C.-J. Park, B.B. Kale, Self-assembled hierarchical nanostructures of Bi2WO6 for hydrogen production and dye degradation under solar light. CrystEngComm 17, 107–115 (2015)
S.J. Hu, B. Chi, J. Pu, L. Jian, Surface charge modification for improvement of photocatalytic H2 production over a La2Ti2O7/graphene nanocomposite. RSC Adv. 4, 60437–60444 (2014)
M. Orlita, C. Faugeras, P. Plochocka, P. Neugebauer, G. Martinez, D.K. Maude, A.L. Barra, M. Sprinkle, C. Berger, W.A. de Heer, M. Potemski, Approaching the dirac point in high-mobility multilayer epitaxial graphene. Phys. Rev. Lett. 101, 267601 (2008)
J. Yang, X.H. Wang, X.L. Zhao, J. Dai, S.R. Mo, Synthesis of uniform Bi2WO6-reduced graphene oxide nanocomposites with significantly enhanced photocatalytic reduction activity. J. Phys. Chem. C 119, 3068–3078 (2015)
X. Lin, X.Y. Guo, Q.W. Wang, L.M. Chang, H.J. Zhai, Hydrothermal synthesis and efficient visible light photocatalytic activity of Bi2MoO6/BiVO4 heterojunction. Acta Phys. Chim. Sin. 30, 2113–2120 (2014)
J.G. Yu, W.G. Wang, B. Cheng, B.L. Su, Enhancement of photocatalytic activity of mesporous TiO2 powders by hydrothermal surface fluorination treatment. J. Phys. Chem. C 113, 6743–6750 (2009)
H. Zhang, X.J. Lv, Y.M. Li, Y. Wang, J.H. Li, P25-graphene composite as a high performance photocatalyst. ACS Nano 4, 380–386 (2010)
K.F. Zhou, Y.H. Zhu, X.L. Yang, X. Jiang, C.Z. Li, Preparation of graphene–TiO2 composites with enhanced photocatalytic activity. New J. Chem. 35, 353–359 (2011)
J.G. Yu, J.R. Ran, Facile preparation and enhanced photocatalytic H2-production activity of Cu(OH)2 cluster modified TiO2. Energy Environ. Sci. 4, 1364–1371 (2011)
E.P. Gao, W.Z. Wang, M. Shang, J.H. Xu, Synthesis and enhanced photocatalytic performance of graphene–Bi2WO6 composite. Phys. Chem. Chem. Phys. 13, 2887–2893 (2011)
Acknowledgments
This work was financially supported by the National Natural Science Foundation of China (51573023, 50972020, 51072026), Ph.D. Programs Foundation of the Ministry of Education of China (20102216110002, 20112216120003), the Science and Technology Development Planning Project of Jilin Province (Grant Nos. 20130101001JC, 20070402).
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Zhao, J., Yang, Y., Yu, W. et al. Bi2MoO6/RGO composite nanofibers: facile electrospinning fabrication, structure, and significantly improved photocatalytic water splitting activity. J Mater Sci: Mater Electron 28, 543–552 (2017). https://doi.org/10.1007/s10854-016-5557-3
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DOI: https://doi.org/10.1007/s10854-016-5557-3