Abstract
In this paper, the composition and structure of homogeneous silicon carbide layers produced by multiple implantation of 40-, 20-, 10-, 5- and 3-keV carbon ions into silicon were studied by transmission electron microscopy, X-ray diffraction, Auger spectroscopy, IR spectroscopy and Atomic force microscopy. After high temperature annealing the homogeneous, fine-grained, polycrystalline SiC0.95 and SiC1.4 films consists of globular or plate-like grains are obtained. The intensive translations of atoms during annealing at 800–1400 °C are taken place causing the deformation of the layer surface and the formation of grains with sizes ∼30–100 nm. The grains consist of chaotically oriented SiC crystallites with average sizes ∼5 nm. The temperature dependences of IR spectra parameters are evidence of similarity of carbon and silicon-carbon clusters types in SiC0.95 and SiC1.4 layers. An influence of carbon- and silicon-carbon clusters prevailed in as-implanted layer on the crystallization processes in silicon layers with high carbon concentration, are considered.
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The authors would like to thank the Ministry of Education and Science of Republic of Kazakhstan for the financial support by grant.
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Nussupov, K.K., Beisenkhanov, N.B., Valitova, I.V. et al. Structure properties of carbon implanted silicon layers. J Mater Sci: Mater Electron 19 (Suppl 1), 254–262 (2008). https://doi.org/10.1007/s10854-007-9533-9
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DOI: https://doi.org/10.1007/s10854-007-9533-9