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The holographic properties of photopolymers on the base of oxygen- and sulfur-containing spirocyclic monomers

  • Polymers & biopolymers
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Abstract

The influence of the oxygen and sulfur atoms in the spirocycles (–O–CH2–CH2–O–, –O–CH2–CH2–S–, –S–CH2–CH2–S–) of the spirocyclic acryloylpiperidonyl monomers on the thermomechanical and holographic properties of the photopolymer material was studied. The conversion of double bonds of monomers during UV polymerization was determined by IR spectroscopy method. The refractive indices of spirocyclic monomers and photopolymers were measured. The phase transmission diffraction gratings were recorded in photopolymer materials containing the spirocyclic monomers. The highest modulation of the refractive index was observed in the photopolymer based on the acryloylpiperidonyl dithiaazaspiroheterocyclic (–S–CH2–CH2–S–) monomer. It was shown that light scattering in the photopolymer at hologram recording has noticeable negative contribution and for the decrease in the diffraction efficiency of holograms. The phase incompatibility of the polymer matrix and formed photopolymer is considered as the reason of the light-scattering growth.

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The raw/processed data required to reproduce these findings cannot be shared at this time as the data also forms part of an ongoing study.

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Acknowledgements

Authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements. This research conducted under a scientific theme FWUE-2022-0016 and 122040400028-5 and did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors.

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Authors and Affiliations

  1. Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Science, 9, Academician Lavrentjev Ave, Novosibirsk, 630090, Russia

    Vladimir Shelkovnikov, Evgenii Vasiliev, Dmitry Derevyanko, Alexandra Bukhtoyarova, Viktoria Berezhnaya & Inna Shundrina

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  1. Vladimir Shelkovnikov
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Correspondence to Evgenii Vasiliev.

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Shelkovnikov, V., Vasiliev, E., Derevyanko, D. et al. The holographic properties of photopolymers on the base of oxygen- and sulfur-containing spirocyclic monomers. J Mater Sci 58, 983–995 (2023). https://doi.org/10.1007/s10853-022-08105-8

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