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Controlled growth of MAPbBr3 single crystal: understanding the growth morphologies of vicinal hillocks on (100) facet to form perfect cubes

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Abstract

Organic and inorganic hybrid perovskites have attracted significant attentions due to their impressive optoelectronic properties. MAPbBr3, one of the most popular members in MAPbX3 (MA = methyl ammonium and X = Cl, Br, I) family, is considered as new generation optoelectronic materials, especially in the field of solar cells. Compared to polycrystalline films, MAPbBr3 single crystal is deemed more ideal for optoelectronic device because of fewer grain boundaries. To realize a controlled crystal growth, a thorough understanding of its growth mechanism, especially the role of surface structures played in growth kinetics, is of paramount importance. In this paper, hillocks on (100) facet of MAPbBr3 crystal were observed using atomic force microscopy when grown from N-dimethylformamide (DMF) solution. The results revealed that the growth of (100) facet was controlled by 2D nucleation at low concentration, which derived plenty of elementary steps whose height was about 0.59 nm, equivalent to one unit cell. Then the growth transferred to step flow model along [011] direction. Step flow ceased when encountering holes on the terraces. The optical morphologies validated that cubic plates were prone to growing along [011] directions, which were in a layer-by-layer model. Moreover, the temperature reverse solubility of MAPbBr3 in DMF solution was measured. In terms of the solubility and growth mechanism of MAPbBr3, a series of MAPbBr3 single crystals were successfully grown from thin cubic plates to thick and perfect cubes via temperature controlling rising method ultimately.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (No. 51202131), Science Foundation of Shandong Province (ZR2016EMQ10), Scientific Research Foundation of Shandong University of Science and Technology for Recruited Talent (No. 2014RCJJ001), SDUST Research Fund and Joint Innovative Center for Safe and Effective Mining Technology and Equipment of Coal Resources, Shandong Province (No. 2014JQJH102). Distinguished Taishan Scholars in Climbing Plan (No. tspd20161006).

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Authors and Affiliations

  1. College of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao, 266590, China

    Jianxu Ding, Ying Zhao, Songjie Du, Yingshuang Sun, Hongzhi Cui, Xiaoyuan Zhan, Xiaohua Cheng & Lin Jing

  2. State Key Laboratory of Mining Disaster Prevention and Control Co-founded by Shandong Province and the Ministry of Science and Technology, Shandong University of Science and Technology, Qingdao, 266590, China

    Jianxu Ding

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  1. Jianxu Ding
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  2. Ying Zhao
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  3. Songjie Du
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  4. Yingshuang Sun
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  5. Hongzhi Cui
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  6. Xiaoyuan Zhan
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  7. Xiaohua Cheng
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  8. Lin Jing
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Correspondence to Jianxu Ding or Hongzhi Cui.

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Ding, J., Zhao, Y., Du, S. et al. Controlled growth of MAPbBr3 single crystal: understanding the growth morphologies of vicinal hillocks on (100) facet to form perfect cubes. J Mater Sci 52, 7907–7916 (2017). https://doi.org/10.1007/s10853-017-0995-8

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  • DOI: https://doi.org/10.1007/s10853-017-0995-8

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