Abstract
The precipitation behavior of niobium component out of niobium-doped anatase-type TiO2 and structural change in the course of heating were investigated. The samples were directly formed under hydrothermal conditions at 240 °C for 5 h in the presence of aqueous ammonia via crystallization from co-precipitates that were obtained from precursor solutions of TiOSO4 and NbCl5. The as-prepared niobium-doped anatase-type titania nanoparticles showed bluish color and absorption in the visible region, which was confirmed to be due to the presence of Ti(III) in the solid solutions using electron paramagnetic resonance measurement. The niobium-doped anatase-type titania existed stably without an appearance of any other phases after heating up to 500 °C for 1 h. In the course of heating at 500–800 °C, continual and clear decrease in the lattice parameters a0 and c0 of the anatase was observed, which was followed by the precipitation of Nb2O5 and TiNb2O7 out of the niobium-doped anatase, but the anatase phase was maintained without anatase-to-rutile phase transformation up to 850–1,000 °C. The anatase-to-rutile phase transformation was gradually retarded when the niobium content increased.
Similar content being viewed by others
References
Fox MA, Dulay MT (1993) Chem Rev 93:341
O’Regon B, Gratzel M (1991) Nature 353:737
Ferroni M, Guidi V, Martinelli G, Faglia G, Nelli P, Sberveglieri G (1996) Nanostruct Mater 7:709
Shannon RD, Pask JA (1965) J Am Ceram Soc 48:391
Shannon RD, Pask JA (1964) Am Miner 49:1707
Mackenzie KJD (1975) Trans J Br Ceram Soc 74:77
Suyama Y, Kato A (1978) J Ceram Soc Jpn 86:119 [in Japanese]
Hishida S, Tanaka M, Yanagida H (1978) J Ceram Soc Jpn 86:631
Leduc CA, Campbell JM, Rossin JA (1996) Ind Eng Chem Res 25:2473
Gennari FC, Pasquevich DM (1998) J Mater Sci 33:1571. doi:https://doi.org/10.1023/A:1017515804370
Hirano M, Joji T, Inagaki M, Iwata H (2004) J Am Ceram Soc 87:35
Hirano M, Ota K, Ito T (2005) J Am Ceram Soc 88:3303
Oliveri G, Ramis G, Busca G, Escribano VS (1993) J Mater Chem 3:1239
Rao CNR, Turner A, Honig JM (1959) J Phys Chem 11:173
Ding XZ, Liu XH (1998) J Mater Res 13:2556
Deo G, Turek AM, Wachs IE, Machej T, Haber J, Das N, Eckert H, Hirt AM (1992) Appl Catal A 91:27
Dutta PK, Ginwalla A, Hogg B, Patton BR, Chwieroth B, Liang Z, Gouma P, Mills M, Akbar S (1999) J Phys Chem B 103:4412
Hirano M, Ota K, Iwata H (2004) Chem Mater 16:3725
Czanderna AW, Rao CNR, Honig JM (1958) Trans Faraday Soc 54:1069
Yoganarasimhan SR, Rao CNR (1962) Trans Faraday Soc 58:1579
Hirano M, Morikawa H (2003) Chem Mater 15:2561
Hirano M, Matsushima K (2006) J Am Ceram Soc 89:110
Hirano M, Nakahara C, Ota K, Tanaike O, Inagaki M (2003) J Solid State Chem 170:39
Hirano M, Date K (2005) J Am Ceram Soc 88:2604
Tanabe K, Okazaki S (1995) Appl Catal A Gen 133:191
Zhang Z, Wang CC, Zakaria R, Ying JY (1998) Phys Chem B 102:10871
Zakrzewska K, Radecka M, Rekas M (1997) Thin Solid Films 310:161
Sharma RK, Bhatnagar MC (1999) Sens Actuators B 56:215
Hirano M, Matsushima K (2006) J Nanosci Nanotechnol 6:762
Hirano M, Ito T (2006) J Nanosci Nanotecnol 6:3820
Hirano M, Ito T (2008) Mater Res Bull 43:2196
Spurr RA, Myers H (1957) Anal Chem 29:760
Criado BJ, Real C (1983) J Chem Soc Faraday Trans 1 79:2765
Acknowledgements
The authors thank Shingo Sato for his assistance. The present work was partly supported by Grant-in Aids No. 21560703 for Scientific Research from the Ministry of Education, Culture, Sports, Science, and Technology of Japan.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hirano, M., Ichihashi, Y. Phase transformation and precipitation behavior of niobium component out of niobium-doped anatase-type TiO2 nanoparticles synthesized via hydrothermal crystallization. J Mater Sci 44, 6135–6143 (2009). https://doi.org/10.1007/s10853-009-3848-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-009-3848-2