Abstract
ZnO tetrapods were prepared by Zn-vapour deposition at 740 °C in Argon and subsequent oxidation in air for 1–30 min. The photoluminescence (PL) and cathodoluminescence (CL) spectra were measured from ZnO particles collected at various distances from the Zn source representing decreasing dimensions. The ZnO tetrapods showed a green emission centred at 516 nm (2.40 eV) band and the exciton emission at 387 nm (3.20 eV). The measured data suggested that the green emission is strongly increased for particle sizes below 500 nm, whereas the exciton emission is dominant for particle size larger than 500 nm. Spatially resolved CL-measurement on individual tetrapod legs showed, that the green emission increases with decreasing ZnO leg diameter. To our knowledge, the local CL spectroscopic measurements were correlated with the dimensions of the individual ZnO tetrapods for the first time.
Similar content being viewed by others
References
Huang MH, Wu Y, Feick H, Tran N, Weber E, Yang P (2001) Adv Mater 13:113
Huang MH, Mao S, Feick H, Yan H, Wu Y, Kind H, Weber E, Russo R, Yang P (2001) Science 292:1897
Reynolds DC, Look DC, Jogai B (1996) Solid State Comm 99:873
Xu C, Kim M, Chun J, Kim DE (2005) Nanotechnology 16:104
Lyu SC, Zhang Y, Ruh H, Lee HJ, Shim HW, Suh EK, Lee CJ (2002) Chem Phys Lett 363:134
Zhang J, Yu W, Zhang L (2002) Phys Lett A 299:276
Chen Z, Shan Z, Cao MS, Lu L, Mao SX (2004) Nanotechnology 15:365
Tseng YK, Huang CJ, Cheng HM, Lin IN, Liu KS, Chen IC (2003) Adv Funct Mater 13:811
Kong XY, Ding Y, Yang R, Wang ZL (2004) Science 27:1348
Leung YH, Djurisic AB, Gao J, Xie MH, Chan WK (2004) Chem Phys Lett 385:155
Wan Q, Song ZT, Liu WL, Lin CL, Wang TH (2004) Nanotechnology 15:559
Dai Y, Zhang Y, Bai YQ, Wang ZL (2003) Chem Phys Lett 375:96
Park J, Choi HH, Siebein K, Singh RK (2003) J Cryst Growth 258:342
Vayssieres L (2003) Adv Mater 15:464
Govender K, Boyle D, Kenway PB, O’Brien P (2004) J Mater Chem 16:2575
Yan H, He R, Pham J, Yang P (2003) Adv Mater 15:402
Dai Y, Zhang Y, Li QK, Nan CW (2002) Chem Phys Lett 358:83
Fan HJ, Scholz R, Kolb FM, Zacharias M, Gösele U (2004) Solid State Comm 130:517
Gao T, Huang Y, Wang T (2004) J Phys Cond Mater 16:115
Yu WD, Li XM, Gao XD (2004) Chem Phys Lett 390:296
Dai Y, Zhang Y, Li QK, Nan CW (2002) Chem Phys Lett 375:83
Van Dijken A, Meulenkamp EA, Vanmaekelbergh D, Meijerink A (2000) J Lum 87–89:454
Zhong H, Wang J, Pan M, Wang S, Li Z, Xu W, Chen X, Lu W (2006) Mat Chem Phys 97:390
Li H, Hackenschmied P, Epelbaum B, Batentschuk M (2002) Mat Sci Eng B Solids B94:32
Urbieta A, Fernández P, Piqueras J, Hardalov C, Sekiguchi T (2001) J Phys D Appl Phys 34:2945
Fernández P, García JA, Remón A, Piqueras J, Muñoz V, Triboulet R (1998) Semicond Sci Tech 13:410
Saito N, Haneda H, Koumoto K (2004) Microelectr J 35:349
Lorenz M, Lenzer J, Kaidshev EM, Hochmuth H, Grundmann M (2004) Ann Phys (Leipzig) 1–2:39
Grym J, Fernández P, Piqueras J (2005) Nanotechnology 16:931
Wu JJ, Liu SC (2002) Adv Mater 14:215
Lima SAM, Sigoli FA, Jafelicci M Jr, Davolos MR (2001) Int J Inorg Mat 3:749
Acknowledgements
The authors are grateful to E. Völkl for the technical assistance on the CL-measurements. Financial support of the German Science Foundation (DFG) and the University of Erlangen-Nuremberg is gratefully acknowledged. C.R. Rambo thanks CNPq-Brazil for the financial support.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zollfrank, C., Rambo, C.R., Batentschuk, M. et al. Spatially resolved luminescence properties of ZnO tetrapods. J Mater Sci 42, 6325–6330 (2007). https://doi.org/10.1007/s10853-006-1253-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-006-1253-7