Skip to main content
SpringerLink
Log in

A New Organic-Inorganic Hybrid Nanocomposite, BEDT-TTF Intercalated into Layered FePS3

  • Original Research Article
  • Published:
Journal of inclusion phenomena and macrocyclic chemistry Aims and scope Submit manuscript

Abstract

A new inorganic–organic hybrid compound, Fe0.76PS3(BEDT-TTF)0.48 (BEDT-TTF=bis(ethylenedithio)tetrathiafulvalene), has been synthesized by the reaction of the pre-intercalate Fe0.90PS3(Phen)0.41 (phen=1,10-phenanthroline) with (BEDT-TTF)2Ix. The powder X-ray diffraction (XRD) results show that the expansion of the lattice spacing (Δ d) is about 4.0 Å compared with the pristine FePS3, indicating that the molecular ring plane of the guest is parallel to the layer of the host. The infrared spectrum of the intercalate shows the existence of BEDT-TTF as a guest between the interlayer region of the layered FePS3. The room-temperature electrical conductivity of the compressed pellet of Fe0.76PS3(BEDT-TTF)0.48 is about 10−7 S/cm, which is in the same order of magnitude as that of the pristine FePS3(10−7 S/cm). The magnetic properties measured with a SQUID-magnetometer indicate that Fe0.76PS3(BEDT-TTF)0.48 exhibits the paramagnetism from 120 to 300 K and Curie-Weiss Law was obeyed above 140 K, but a strong antiferromagnetic phase transition occurs at TN of 100 K.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P.G. Lacroix R. Clement K. Nakatani J. Zyss I. Ledoux (1994) Science 263 558 Occurrence Handle10.1126/science.263.5147.658

    Article  Google Scholar 

  2. S. Floquet S. Salunke M.L. Boillot R. Clement F. Varret K. Boukheddaden E. Riviere (2002) Chem. Mater. 14 IssueID10 4164 Occurrence Handle10.1021/cm0211406 Occurrence Handle1:CAS:528:DC%2BD38Xms1Wntr8%3D

    Article  CAS  Google Scholar 

  3. N. Arun S. Vasudevan K.V. Ramanathan (2000) J. Am. Chem. Soc. 122 6028 Occurrence Handle10.1021/ja991357+ Occurrence Handle1:CAS:528:DC%2BD3cXjvVOlsr4%3D

    Article  CAS  Google Scholar 

  4. A. Leaustic E. Riviere R. Clement (2003) Chem. Mater. 15 IssueID25 4784 Occurrence Handle10.1021/cm031037w Occurrence Handle1:CAS:528:DC%2BD3sXoslKrtbo%3D

    Article  CAS  Google Scholar 

  5. W. Klingen R. Ott H. Hahn Z. Anorg (1973) Allg. Chem. 396 271 Occurrence Handle10.1002/zaac.19733960305 Occurrence Handle1:CAS:528:DyaE3sXptF2jsw%3D%3D

    Article  CAS  Google Scholar 

  6. E. Prouzet G. Ouvrard R. Brec (1986) Mater. Res. Bull. 21 195 Occurrence Handle10.1016/0025-5408(86)90206-0 Occurrence Handle1:CAS:528:DyaL28Xhtl2lu7s%3D

    Article  CAS  Google Scholar 

  7. R. Brec (1986) Solid State Ionics 22 3 Occurrence Handle10.1016/0167-2738(86)90055-X Occurrence Handle1:CAS:528:DyaL2sXhtFanu74%3D

    Article  CAS  Google Scholar 

  8. R. Clement: J. Chem. Soc., Chem. Commun. 647 (1980).

  9. R. Clement J.J. Girerd I.M. Badarau (1980) Inorg. Chem. 19 2852 Occurrence Handle10.1021/ic50211a079 Occurrence Handle1:CAS:528:DyaL3cXls1SiurY%3D

    Article  CAS  Google Scholar 

  10. P.A. Joy S. Vasudevan (1992) J. Am. Chem. Soc. 114 7792 Occurrence Handle10.1021/ja00046a027 Occurrence Handle1:CAS:528:DyaK38Xls1aktLc%3D

    Article  CAS  Google Scholar 

  11. J. Qin C. Yang K. Yakushi Y. Nakazawa K. Ichimura (1996) Solid State Commun. 100 IssueID6 427 Occurrence Handle10.1016/0038-1098(96)00371-7 Occurrence Handle1:CAS:528:DyaK28Xmslegt70%3D

    Article  CAS  Google Scholar 

  12. A. Leaustic J.P. Audiere D. Cointereau R. Clement L. Lomas F. Varret H. Constant-Machado (1996) Chem. Mater. 8 1954 Occurrence Handle10.1021/cm960059y Occurrence Handle1:CAS:528:DyaK28XksFahsrs%3D

    Article  CAS  Google Scholar 

  13. P. Day M. Kurmoo (1997) J. Mater. Chem. 7 1291 Occurrence Handle10.1039/a608508c Occurrence Handle1:CAS:528:DyaK2sXls1Whurk%3D

    Article  CAS  Google Scholar 

  14. K. Murato M. Tokumoto H. Anzai H. Bando G. Sarro K. Kajimura T. Ishiguro (1985) J. Phys. Soc. Jpn. 54 1236 Occurrence Handle10.1143/JPSJ.54.1236

    Article  Google Scholar 

  15. H. Ito T. Kondo H. Sasaki G. Satio T. Ishiguro (1999) Synth. Met. 103 1818 Occurrence Handle10.1016/S0379-6779(98)00465-2 Occurrence Handle1:CAS:528:DyaK1MXksFOit74%3D

    Article  CAS  Google Scholar 

  16. J.F. Bringley J.M. Fabre B.A. Averill (1990) J. Am. Chem. Soc. 112 4577 Occurrence Handle10.1021/ja00167a084 Occurrence Handle1:CAS:528:DyaK3cXit1ymsL0%3D

    Article  CAS  Google Scholar 

  17. E. Coronado J.R. Galan-Mascaros C.J. Gomez-Garcia V. Laukhin (2000) Nature 408 470 Occurrence Handle10.1038/35044035

    Article  Google Scholar 

  18. M. Kurmoo A.W. Graham P. Day S.J. Coles M.B. Hursthouse J.L. Cauifield J. Singleton F.L. Pratt W. Hayes L. Ducasse P. Guionneau (1995) J. Am. Chem. Soc. 117 12209 Occurrence Handle10.1021/ja00154a022 Occurrence Handle1:CAS:528:DyaK2MXpsFSitLk%3D

    Article  CAS  Google Scholar 

  19. M.R. Antonio and B.A. Averill: J. Chem. Soc., Chem. Commun. 382 (1981).

  20. M. Soma and Y. Soma: Chem. Lett. 405 (1988).

  21. P. Lacroix, J.P. Audiere, and R. Clement: J. Chem. Soc., Chem. Commun. 536 (1989).

  22. L. Lomas P. Lacroix J.P. Audiere R. Clement (1991) J. Mater. Chem. 1 475 Occurrence Handle10.1039/jm9910100475 Occurrence Handle1:CAS:528:DyaK3MXmt1WlsLc%3D

    Article  CAS  Google Scholar 

  23. J.F. Bringley J.M. Fabre B.A. Averill (1990) J. Am. Chem. Soc. 112 4577 Occurrence Handle10.1021/ja00167a084

    Article  Google Scholar 

  24. C. Yang J. Qin K. Yakushi Y. Nakazawa K. Ichimura (1999) Synth. Met. 102 1482 Occurrence Handle10.1016/S0379-6779(98)00675-4 Occurrence Handle1:CAS:528:DyaK1MXksFKhtLs%3D

    Article  CAS  Google Scholar 

  25. A. Leaustic J.P. Audiere D. Cointereau R. Clement L. Lomas F. Varret H. Constant-Machado (1996) Chem. Mater. 8 1954 Occurrence Handle10.1021/cm960059y Occurrence Handle1:CAS:528:DyaK28XksFahsrs%3D

    Article  CAS  Google Scholar 

  26. B.E. Taylor J. Steger A. Wold (1973) J. Solid State Chem. 7 461 Occurrence Handle10.1016/0022-4596(73)90175-8 Occurrence Handle1:CAS:528:DyaE3sXkvF2qsb8%3D

    Article  CAS  Google Scholar 

  27. X. Chen C. Yang J. Qin K. Yakushi Y. Nakazawa K. Ichimura (2000) Chin. J. Chem. 18 510 Occurrence Handle1:CAS:528:DC%2BD3cXls1entLw%3D

    CAS  Google Scholar 

  28. A.E. Harvey SuffixJr. J.A. Smart E.S. Amis (1955) Anal. Chem. 27 26 Occurrence Handle10.1021/ac60097a009 Occurrence Handle1:CAS:528:DyaG2MXislaqsQ%3D%3D

    Article  CAS  Google Scholar 

  29. T. Coradin R. Clement P.G. Lacroix K. Nakatani (1996) Chem. Mater. 8 2153 Occurrence Handle10.1021/cm960060x Occurrence Handle1:CAS:528:DyaK28XksFahsrg%3D

    Article  CAS  Google Scholar 

  30. A. Leaustic J.P. Audiere P.G. Lacroix R. Clement L. Lomas A. Michalowicz W.R. Dunham A.H. Francis (1995) Chem. Mater. 7 1103 Occurrence Handle10.1021/cm00054a009 Occurrence Handle1:CAS:528:DyaK2MXlvFWltbY%3D

    Article  CAS  Google Scholar 

  31. P.A. Joy S. Vasudevan (1992) Phys. Rev. B 46 5425 Occurrence Handle10.1103/PhysRevB.46.5425 Occurrence Handle1:CAS:528:DyaK38XlvVent7k%3D

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Wuhan University, Wuhan, 430072, China

    Xingguo Chen, Huiqiong Zhou, Li Zou, Chuluo Yang & Jingui Qin

  2. Department of Materials Science and Engineering, Science University of Tokyo in Yamaguchi, Yamaguchi, Onoda, 756-0884, Japan

    Makoto Inokuchi

Authors
  1. Xingguo Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Huiqiong Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Li Zou
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Chuluo Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Jingui Qin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Makoto Inokuchi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jingui Qin.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, X., Zhou, H., Zou, L. et al. A New Organic-Inorganic Hybrid Nanocomposite, BEDT-TTF Intercalated into Layered FePS3 . J Incl Phenom Macrocycl Chem 53, 205–209 (2005). https://doi.org/10.1007/s10847-005-2025-8

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10847-005-2025-8

Keywords

Search

Navigation