The effect of multilayer nanoparticles consisting of a conducting spherical core and two shells, dielectric and metallic, on nonradiative energy transfer from organic luminophore molecules to acceptor molecules is studied. The dipole polarizability of the nanoparticle is examined with and without taking into account the degeneracy of the electron gas of the conducting components. The rate of transfer of the energy of electronic excitation between molecules near multilayer nanoparticles and the rate of transfer directly to the nanoparticles are calculated in the quasistatic (near field) approximation of electrodynamics. Multilayer nanoparticles are found to have a significant effect on the decay kinetics of excited singlet states of the donor molecules.
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 81, No. 3, pp. 396–401, May–June, 2014.
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Kucherenko, M.G., Chmereva, T.M. & Gadaeva, E.K. Effect of Multilayer Spherical Nanoparticles with a Conducting Core on Fluorescence Quenching of Organic Luminophores. J Appl Spectrosc 81, 416–421 (2014). https://doi.org/10.1007/s10812-014-9947-0
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DOI: https://doi.org/10.1007/s10812-014-9947-0