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Development of a solar reflector coating on AA6061 alloy by plasma electrolytic oxidation

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Abstract

A spacecraft consists of various components which will function with maximum efficiency only when their operating temperature is maintained within certain specified ranges. Passive thermal control elements play an important role in maintaining the temperature of spacecraft components within the specified ranges by suitable selection of thermo-optical properties of the surfaces namely absorptance and emittance. Plasma electrolytic oxidation of AA 6061 is studied as a method to develop a solar reflector coating for space applications. The coatings are developed by making use of a silicate-based electrolyte. The influence of electrolyte composition, average current density, processing time, positive on-time and pulse frequency on the thermo-optical behaviour of the coating is studied. The thickness of the PEO coating is optimized so as to attain thermo-optical properties similar or better than conventional sulphuric acid anodizing. The optimized coating is subjected to adhesion and humidity tests as well as various space simulation tests such as thermal cycling and thermo-vacuum performance tests to evaluate the suitability of the coating as a thermal control surface for space application. Coatings obtained by PEO process and conventional sulphuric acid anodizing are further characterized using SEM, EDX, XPS, XRD and nanoprofilometry to have a comparative study of their morphology, microstructure and composition.

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References

  1. Kraus Allan D, Bar-Cohen Avram (1983) Thermal analysis and control of electronic equipment. McGraw-Hill, New York

    Google Scholar 

  2. Barg G, Djordjevic N, Hall S (1988) The development of Prometheus: an expert system tool for preliminary design of spacecraft thermal control systems from the Proceedings of the first international conference on Industrial and Engineering applications of artificial intelligence and Expert Systems. ACM Press: 380–387

  3. Joseph G (2015) Chapter 10-Journey from ground to space from a system engineer’s guide to building an earth observation camera. CRC Press: 303–325

  4. Gilmore DG (2002) Spacecraft thermal control handbook, 2nd edn. The Aerospace Corporation Press, El Segundo

    Google Scholar 

  5. Karam RD (1998) Satellite thermal control for system engineers. In: Zarchan P (ed) Progress in astronautics and aeronautics, 181st edn. AIAA, Cambridge

    Google Scholar 

  6. Meseguer J, Pérez-Grande I, Sanz-Adréz A (2012) Spacecraft Thermal Control. Woodhead Publishing, Cambridge

    Book  Google Scholar 

  7. Sharma AK, Bhojraj H, Kaila VK, Narayanamurthy H (1997) Anodizing and inorganic black coloring of aluminum alloys for space applications. Metal Finish 95(12):14–20

    Article  CAS  Google Scholar 

  8. Wernick S, Pinner R, Sheasby PG (1987) The surface treatment and finishing of aluminium and its alloys, 5th edn. ASM International, Materials Park

    Google Scholar 

  9. Henninger JH (1984) Solar absorptance and thermal emittance of some common spacecraft thermal-control coatings. Imprint: National Aeronautics and Space Administration, Scientific and Technical Information Branch, Washington DC

  10. Siva Kumar C, Sharma AK, Mahendra KN, Mayanna SM (2000) Studies on anodic oxide coating with low absorptance and high emittance on aluminum alloy 2024. Sol Energy Mater Sol Cells 60:51–57

    Article  CAS  Google Scholar 

  11. Shao L, Li H, Jiang B, Liu C, Gu X, Chen D (2018) A comparative study of corrosion behavior of hard anodized and micro arc oxidation coatings on 7050 aluminium alloy. Metals 8(3):165. https://doi.org/10.3390/met8030165

    Article  CAS  Google Scholar 

  12. Rama Krishna L, Sudha Purnima A, Sundararajan G (2006) A comparative study of tribological behavior of microarc oxidation and hard-anodized coatings. Wear 261:1095–1101

    Article  CAS  Google Scholar 

  13. Yerokhin AL, Nie X, Leyland A, Matthews A, Dowey SJ (1999) Plasma electrolysis for surface engineering. Surf Coat Technol 122:73–93

    Article  CAS  Google Scholar 

  14. Walsh FC, Low CTJ, Wood RJK, Stevens KT, Archer J, Poeton AR, Ryder A (2009) Plasma electrolytic oxidation (PEO) for production of anodised coatings on lightweight metal (Al, Mg, Ti) alloys. Trans Inst Met Finish 87:122–135

    Article  CAS  Google Scholar 

  15. Zhang Y, Fan W, Du HQ, Zhao YW (2017) Plasma electrolytic oxidation coatings for aluminum alloys. Mater Perform 56(9):38–41

    Google Scholar 

  16. Matykina E, Arrabal R, Mohedano M, Mingo B, Gonzalez J, Pardo A, Merino MC (2017) Recent advances in energy efficient PEO processing of aluminium alloys. Trans Nonferrous Met Soc China 27(7):1439–1454

    Article  CAS  Google Scholar 

  17. Martin J, Nomine A, Ntomprougkidis V, Migot S, Bruyere S, Soldera F, Belmonte T, Henrion G (2019) Formation of a metastable nanostructured mullite during Plasma Electrolytic Oxidation of aluminium in Soft regime condition. Mater Des 180:10797

    Article  Google Scholar 

  18. Chen Q, Li W, Ling K, Yang R (2019) Investigation of growth mechanism of plasma electrolytic oxidation coating on Al-Ti double layer composite plate. Materials 12:272. https://doi.org/10.3390/ma12020272

    Article  PubMed Central  Google Scholar 

  19. Clyne TW, Troughton SC (2018) A recent work on discharge characteristics during plasma electrolytic oxidation of various metals. Int Mater Rev 64(3):127–162

    Article  Google Scholar 

  20. Shrestha S, Dunn BD (2007) Advanced plasma electrolytic oxidation treatment for protection of lightweight materials and structures in a space environment. Surface World 11:40–44

    Google Scholar 

  21. Mısırlı C, Şahin M, Sözer U Effect of micro arc oxidation coatings on the properties of aluminium alloys. Chapter 4 of aluminium alloys-new trends in fabrication and applications published by INTECH http://dx.doi.org/10.5772/53135

  22. Dehnavi Vahid, Luan Ben Li, Liu Xing Yang, Shoesmith David W, Rohani Sohrab (2015) Correlation between plasma electrolytic oxidation treatment stages and coating microstructure on aluminum under unipolar pulsed DC mode. Surf Coat Technol 269:91–99

    Article  CAS  Google Scholar 

  23. Hussein RO, Nie X, Northwood DO (2013) An investigation of ceramic coating growth mechanisms in plasma electrolytic oxidation (PEO) processing. Electrochim Acta 112:111–119

    Article  CAS  Google Scholar 

  24. Pezzato L, Rigon M, Martucci A, Brunelli K, Katya D, Dabala M (2019) Plasma electrolytic oxidation (PEO) as pre-treatment for sol-gel coating on aluminium and magnesium alloys. Surf Coat Technol 366:114–123

    Article  CAS  Google Scholar 

  25. Somasundaram Soniya, Pillai Anju M, Rajendra A, Aravindram P, Murali Krishna P, Sharma AK (2018) Space qualification and characterization of high emittance black nickel coating on copper and stainless-steel substrates. Sol Energy Mater Sol Cells 174:163–171

    Article  CAS  Google Scholar 

  26. Pillai Anju M, Rajendra A, Sharma AK (2012) Pulse electrodeposition of nanocrystalline nickel on AA6061 for space applications. Trans Inst Metal Finish 90(1):44–51

    Article  CAS  Google Scholar 

  27. Sharma AK (2005) Surface engineering for thermal control of spacecraft. Surf Eng 21(3):249–253

    Article  CAS  Google Scholar 

  28. Griffin MD, French JR (2004) Spacecraft environment. Chapter 3 of space vehicle design. 2nd. American Institute of Aeronautics and Astronautics, Inc., Reston, ISBN 1-56347-539-l

  29. Liu YJ, Xu JY, Lin W, Gao C, Zhang JC, Chen XH (2013) Effects of different electrolyte systems on the formation of micro-arc oxidation ceramic coatings of 6061 aluminum alloy. Rev Adv Mater Sci 33:126–130

    Google Scholar 

  30. Dehnavi V (2014) Surface modification of aluminum alloys by plasma electrolytic oxidation. Thesis from The University of Western Ontario

  31. Hussein RO, Nie X, Northwood DO, Yerokhin A, Matthews A (2010) Spectroscopic study of electrolytic plasma and discharging behaviour during the plasma electrolytic oxidation (PEO) process. J Phys D 43:105203. https://doi.org/10.1088/0022-3727/43/10/105203

    Article  CAS  Google Scholar 

  32. Hussein RO, Northwood DO, Nie X (2010) Coating growth behavior during the plasma electrolytic oxidation process. J Vac Sci Technol, A 28:766–773

    Article  CAS  Google Scholar 

  33. Alwitt RS, Xu J, Mcclung RC (1993) Stresses in sulfuric acid anodized coatings on aluminum. Electrochem Soc 140(5):1241–1246

    Article  CAS  Google Scholar 

  34. Shahzad Majid, Chaussumier Michel, Chieragatti Rémy, Mabru Catherine, Rezai-Aria Farhad (2012) Effect of sealed anodic film on fatigue performance of 2214-T6 aluminum alloy. Surf Coat Technol 206:2733–2739

    Article  CAS  Google Scholar 

  35. Zhu Yuan Yuan, Ding Gu Qiao, Ding Jian Ning, Yuan Ning Yi (2010) AFM, SEM and TEM studies on porous anodic alumina. Nanoscale Res Lett 5(4):725–734

    Article  CAS  Google Scholar 

  36. He CC, Heslin TH (1995) Preventing cracking of anodized coatings. NASA Technical Memorandum 104622, Goddard Space Flight Center, Greenbelt

  37. Yong-jun Guan, Yuan Xia (2006) Correlation between discharging property and coatings microstructure during plasma electrolytic oxidation. Trans Nonferrous Met Soc China 16:1097–1102

    Article  Google Scholar 

  38. Khan RHU, Yerokhin AL, Pilkington T, Leyland A, Matthews A (2005) Residual stresses in plasma electrolytic oxidation coatings on Al alloy produced by pulsed unipolar current. Surf Coat Technol 200:1580–1586

    Article  CAS  Google Scholar 

  39. Datcheva Maria, Cherneva Sabina, Stoycheva Maria, Iankov Roumen, Stoychev Dimitar (2011) Determination of anodized aluminum material characteristics by means of nanoindentation measurements. Mater Sci Appl 2:1452–1464

    CAS  Google Scholar 

  40. Abdel-Salam Omar E, Shoeib Madiha A, Elkilany Hagar Ashour (2017) Characterization of the hard-anodizing layers formed on 2014-T3 Al alloy in sulphuric acid electrolyte containing sodium lignin sulphonate. Egypt J Petrol. https://doi.org/10.1016/j.ejpe.2017.07.014

    Article  Google Scholar 

  41. Cheng Tsung-Chieh, Chou Chu-Chiang (2015) The electrical and mechanical properties of porous anodic 6061-T6 aluminum alloy oxide film. J Nanomater. https://doi.org/10.1155/2015/371405

    Article  Google Scholar 

  42. Reddy N, Bera P, Reddy VR, Sridhara N, Dey A, Anandan C, Sharma AK (2014) XPS study of sputtered alumina thin films. Ceramic Int 40:11099–11107

    Article  CAS  Google Scholar 

  43. Podder J, Evitts RW, Besant RW (2014) Effect of lead chloride on the growth and surface properties of potassium chloride crystals from aqueous solutions. Surf Rev Lett, 21 Article No. 1450054

  44. Hughes AE, Hedges MM, Sexton BA (1990) Reactions at the Al/SiO2/SiC layered interface. J Mater Sci 25:4856–4865

    Article  CAS  Google Scholar 

  45. Lakshmi RV, Bera P, Anandan C, Basu BJ (2014) Effect of the size of silica nanoparticles on wettability and surface chemistry of sol–gel superhydrophobic and oleophobic nanocomposite coatings. Appl Surf Sci 320:780–786

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors express their sincere gratitude to Dr. Parthasarathy Bera, National Aerospace Laboratories, Bangalore, for conducting detailed XPS analysis of the samples and interpreting the data.

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Correspondence to Anju M. Pillai.

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Pillai, A.M., Rajendra, A., Sharma, A.K. et al. Development of a solar reflector coating on AA6061 alloy by plasma electrolytic oxidation. J Appl Electrochem 49, 1239–1254 (2019). https://doi.org/10.1007/s10800-019-01362-7

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  • DOI: https://doi.org/10.1007/s10800-019-01362-7

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