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TiO2-mediated photoelectrochemical decoloration of methylene blue in the presence of peroxodisulfate

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Abstract

Nanosized TiO2 films on stainless steel were prepared by electrophoretic deposition and characterized by X-ray diffraction analysis and photo-voltammetry. The decoloration of methylene blue (MB) dye was used as a test reaction for the evaluation of photoelectrocatalytic activity of the prepared TiO2 coatings. The influence of applied potential and potassium peroxodisulfate on the rate of MB decoloration was investigated. The possible mechanisms of MB oxidation under various experimental conditions are discussed.

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References

  1. J. Winkler, Titanium Dioxide (Vincentz, Hannover, 2003) 128 pp.

  2. Linsebigler A.L., Lu G., Yates J.T. (1995). Chem Rev. 95:735

    Article  CAS  Google Scholar 

  3. Hoffmann M.R., Martin S.T., Choi W., Bahnemann D.W., (1995). Chem. Rev. 95:69

    Article  CAS  Google Scholar 

  4. Peral J., Xavier D.X., Ollis D.F., (1997). J. Chem. Technol. Biotechnol. 75:117

    Article  Google Scholar 

  5. Bhatkhande D.S., Pangarkar V.G., Beenackers A., (2001). J. Chem. Technol. Biotechnol. 77:102

    Article  Google Scholar 

  6. Fujishima A., Rao T.N., Tryk D.A., (2001). J. Photochem. Photobiol. C: Chem. Rev. 1:1

    Article  Google Scholar 

  7. Kabra K., Chaudhary R., Sawhney R.L., (2004). Ind. Eng. Chem. Res. 43:7683

    Article  CAS  Google Scholar 

  8. Bak T., Nowotny J., Rekas M., Sorrell C.C., (2002). Int. J. Hydrogen Energ. 27 : 991

    Article  CAS  Google Scholar 

  9. Grätzel M. (2003). J. Photochem., Photobiol. C: Chem. Rev. 4 :145

    Article  Google Scholar 

  10. Byrne J.A., Eggins B.R., Brown N.M.D., McKinney B., Rouse M. (1998). Appl. Catal. B. 17:25

    Article  CAS  Google Scholar 

  11. Boccaccini A.R., Zhitomirsky I. (2002). Curr. Opin. Solid State Mater. Sci. 6 :251

    Article  CAS  Google Scholar 

  12. Moreno R., Ferrari B. (2000). Am. Ceram. Soc. Bull. 79: 44

    CAS  Google Scholar 

  13. Bickley R.I., Gonzales-Carreno T., Lees J.S., Palmisano L., J. D. Tilley R. (1991). J. Solid State Chem. 92: 178

    Article  CAS  Google Scholar 

  14. J.G. Calvert and J.G. Pitts Jr, Photochemistry (Wiley, New York, 1966) 899 pp.

  15. Spurr R.A., Myers H., (1957). Anal. Chem. 29:760

    Article  CAS  Google Scholar 

  16. L.V. Azaroff, Elements of X-ray Crystallography (McGraw-Hill Book Co., New York, 1968), 202 pp.

  17. Pigments. Highly dispersed metallic oxides produced by the AEROSIL process (Degussa Technical Bulletin N. 56, 1984).

  18. K. Rajeshwar, in A.J. Bard, M. Stratmann and S. Licht (eds), ‘Encyclopedia of Electrochemistry’, Vol. 6 (Wiley-VCH, 2002) pp. 3–53

  19. Betova I., Bojinov M., Laitinen T., Makela K., Pohjanne P., Saario T. (2002). Corros. Sci. 44:2675

    Article  CAS  Google Scholar 

  20. Gartner W.W. (1959). Phys. Rev. 116: 84

    Article  CAS  Google Scholar 

  21. Mintsouli I., Philippidis N., Poulios I., Sotiropoulos S. (2006). J. Appl. Electrochem. 36:463

    Article  CAS  Google Scholar 

  22. Jiang D., Zhao H., Zhang S., John R. (2006) J. Photochem. Photobiol. A: Chem. 177 : 253

    Article  CAS  Google Scholar 

  23. fGeorgieva J., Armyanov S., Valova E., Poulios I., Sotiropoulos S. (2006). Electrochim. Acta 51:2076

    Article  CAS  Google Scholar 

  24. Gnaser H., Savina M.R., Calaway W.F., Tripa C.E., Veryovkin I.V., Pellin M.J. (2005). Int. J. Mass Spectrom 245 : 61

    Article  CAS  Google Scholar 

  25. Houas A., Lachheb L., Ksibi M., Elaloui E., Guillard C., Herrmann J.M. (2001). Appl. Catal. B. 31:145

    Article  CAS  Google Scholar 

  26. Lakshmi S., Renganathan R., Fujita S. (1995). J. Photochem. Photobiol. A: Chem. 88 :163

    Article  CAS  Google Scholar 

  27. Kleinschmit P., Bertsch-Frank B., Lehmann T., Panster P. (1991) in Elvers B., Hawkins S., Schulz G. (eds), Ullmann’s encyclopedia of industrial chemistry Vol. A19. VCH Verlagsgeselschaft, Weinheim, pp 177–197

    Google Scholar 

  28. A.A. Berlin, V.N. Kislenko, Persulfate Oxidation of Organic Compounds (Svit, L’vov, 1991) 140 pp. (in Russian).

  29. E. Valatka, Phenol Destructive Oxidation: Kinetics and Technological Aspects, Dissertation, University of Technology, Kaunas (2000) (in Lithuanian).

  30. Guillard C., Lachheb H., Houas A., Ksibi M., E. Elaloui and J. M. Herrmann, (2003). J.Photochem. Photobiol. A: Chem. 158 : 27

    Article  CAS  Google Scholar 

  31. Lachheb H., Puzenat E., Houas A., Ksibi M., Elaloui E., Guillard C., Herrmann J.M. (2002). Appl. Catal. B. 39 : 75

    Article  CAS  Google Scholar 

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Valatka, E., Kulėšius, Ž. TiO2-mediated photoelectrochemical decoloration of methylene blue in the presence of peroxodisulfate. J Appl Electrochem 37, 415–420 (2007). https://doi.org/10.1007/s10800-006-9272-2

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  • DOI: https://doi.org/10.1007/s10800-006-9272-2

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