Skip to main content
Log in

Second Inflection Point of the Surface Tension of Water

  • Published:
International Journal of Thermophysics Aims and scope Submit manuscript

Abstract

The theme of a second inflection point of the temperature dependence of the surface tension of water remains a subject of controversy. Using data above 273 K, it is difficult to get a proof of existence of the second inflection point, because of experimental uncertainties. Data for the surface tension of supercooled water and results of a molecular dynamics study were included into the exploration of existence of an inflection point. A new term was included into the IAPWS equation to describe the surface tension in the supercooled water region. The new equation describes the surface tension values of ordinary water between 228 K and 647 K and leads to the inflection point value at a temperature of about 1.5 °C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Gittens G.J.: J. Colloid Interface Sci 30, 406 (1969)

    Article  Google Scholar 

  2. Drost-Hansen W.: Ind. Eng. Chem. 57, 18 (1965)

    Article  Google Scholar 

  3. Lü Y., Wei B.: Appl. Phys. Lett. 89, 164106 (2006)

    Article  ADS  Google Scholar 

  4. Fuentevilla D.A., Anisimov M.A.: Phys. Rev. Lett. 97, 195702 (2006)

    Article  ADS  Google Scholar 

  5. Mishima O.: Proc. Jpn. Acad. Ser. B 26, 165 (2010)

    Article  Google Scholar 

  6. Bertrand C.E., Anisimov M.A.: J. Phys. Chem. B 115, 14099 (2011)

    Article  Google Scholar 

  7. Holten V., Bertrand C.E., Anisimov M.A., Sengers J.V.: J. Chem. Phys. 136, 094507 (2012)

    Article  ADS  Google Scholar 

  8. Floriano M.A., Angell C.A.: J. Phys. Chem. 94, 4199 (1990)

    Article  Google Scholar 

  9. P.T. Hacker, Experimental values of the surface tension of supercooled water, Tech. Note 2510, National Advisory Committee for Aeronautics, Washington, D.C. (1951)

  10. Ohsaka K., Trinh E.H.: Int. J. Thermophys. 16, 545 (1995)

    Article  ADS  Google Scholar 

  11. T.F. Young, W.D. Harkins, Surface-tension data for certain pure liquids between 0 and 360 °C and for all types of solutions at all temperatures, in International Critical Tables, vol. IV, ed. by E.W. Washburn (1928), p. 446

  12. Lü Y., Wei B.: Sci. China Ser. G 49, 616 (2006)

    Article  Google Scholar 

  13. van der Waals J.D.: Thermodynamische Theorie der Kapillarität unter Voraussetzung stetiger Dichteänderung. Z. Phys. Chem. 13, 657 (1894)

    Google Scholar 

  14. Ferguson A., Kennedy S.J.: Trans. Faraday Soc. 32, 1474 (1936)

    Article  Google Scholar 

  15. N.B. Vargaftik, B.N. Volkov, L.D. Voljak, J. Phys. Chem. Ref. Data 12, 817 (1983)

    Google Scholar 

  16. IAPWS Release on Surface Tension of Ordinary Water Substance, September, (1994), www.iapws.org/relguide/surf.pdf. Accessed September 1994

  17. Feeney M.R., Debenedetti P.G.: Ind. Eng. Chem. Res. 42, 6396 (2003)

    Article  Google Scholar 

  18. J. Hrubý, V. Holten, A Two-structure model of thermodynamic properties and surface tension of supercooled water, in Proceedings of 14th International Conference on the Properties of Water and Steam in Kyoto (2004), p. 241

  19. V. Holten, Water nucleation. Wave tube experiments and theoretical considerations. Ph.D. Thesis, Technische Universiteit Eindhoven, 2009

  20. Debenedetti P.G.: Metastable Liquids Concepts and Principles. Princeton University Press, Princeton (1996)

    Google Scholar 

  21. H. Pruppacher, J. Klett, Microphysics of Clouds and Precipitation, 2nd edn. (Kluwer Academic, Dordrecht, 1997), ISBN: 978-0-7923-4211-3

  22. E.L. Andreas, Handbook of physical constants and functions for use in atmospheric boundary layer studies, ERDC/CRREL M-05-1 Tech. Rep. (2005)

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jana Kalova.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kalova, J., Mares, R. Second Inflection Point of the Surface Tension of Water. Int J Thermophys 33, 992–999 (2012). https://doi.org/10.1007/s10765-012-1238-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10765-012-1238-5

Keywords

Navigation