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Structural, magnetic and Mössbauer studies of Ndfexmn1-Xo3 perovskite Manganites

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Abstract

The influence of Fe-doping on the structural and magnetic properties of NdFexMn1-xO3 (x = 0.1, 0.3, 0.5, 0.7, 0.9 and 1.0) nanoparticles was investigated. Auto-combustion sol-gel technique was used to synthesize the compounds. X-Ray diffraction refinement indicated that all samples were formed a single-phased orthorhombic structure with Pbnm space group. The M-T curves measurements at an applied magnetic field of 0.2 T demonstrated that all compounds undergo antiferromagnetic (AFM) to paramagnetic (PM) transition as the temperature increased in which the Nèel temperature was observed below ⁓10 K for all compounds except for NdFe0.3Mn0.7O3 compound (62 K). 57Fe transmission Mӧssbauer spectra were measured at room temperature (295 K) and liquid nitrogen temperature (78 K) for all compounds. The magnetic ordering of these compounds was highly dependent on iron content. The compounds with low iron concentration at 295 K and at 78 K were characterized by a dominant paramagnetic high-spin Fe3+ doublet. The hyperfine magnetic field distribution was responsible for the broadening of the magnetic sextet of the room temperature Mӧssbauer spectrum with x = 0.7. The 57Fe Mӧssbauer spectra with higher iron doping at both 295 K and 78 K demonstrated well resolved magnetic sextet with a hyperfine magnetic field increased linearly with increasing x.

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Acknowledgements

The authors would like to thank the central analytical and applied research unit (CAARU) for performing XRD measurements.

Notations

RA relative Mössbauer subspectrum area.

δ 57Fe Mössbauer isomer shift with respect to that of α-Fe at room temperature.

Δ 57Fe quadrupole splitting.

ε 57Fe first-order quadrupole shift.

B hf 57Fe hyperfine magnetic field.

〈Bhf〉 mean value of the 57Fe hyperfine magnetic field in the case of a hyperfine magnetic field distribution.

FWHM full width at half maximum.

W L Lorentzian FWHM.

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Authors and Affiliations

  1. Physics Department, College of Science, Sultan Qaboos University, P.O. Box 36, Code 123, Al-Khoud, Sultanate of Oman

    I. Z. Al-Yahmadi, A. M. Gismelseed, F. Albzour, F. Al Ma’Mari, A. D. Al-Rawas, S. Al-Harthi, A. A. Yousif, H. M. Widatallah, M. E. Elzain & M. T. Z. Myint

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  1. I. Z. Al-Yahmadi
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  2. A. M. Gismelseed
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  3. F. Albzour
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  4. F. Al Ma’Mari
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  5. A. D. Al-Rawas
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  6. S. Al-Harthi
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  7. A. A. Yousif
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  8. H. M. Widatallah
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  9. M. E. Elzain
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  10. M. T. Z. Myint
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Correspondence to I. Z. Al-Yahmadi.

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This article is part of the Topical Collection on Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2021), 5-10 September 2021, Brasov, Romania

Edited by Victor Kuncser

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Al-Yahmadi, I.Z., Gismelseed, A.M., Albzour, F. et al. Structural, magnetic and Mössbauer studies of Ndfexmn1-Xo3 perovskite Manganites. Hyperfine Interact 242, 41 (2021). https://doi.org/10.1007/s10751-021-01777-9

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  • DOI: https://doi.org/10.1007/s10751-021-01777-9

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