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Electrical conductivity, differential scanning calorimetry, X-ray diffraction, and 7Li nuclear magnetic resonance studies of n-C x H(2x+1)OSO3Li (x = 12, 14, 16, 18, and 20)

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Abstract

Electrical conductivity (σ), differential scanning calorimetry (DSC), and X-ray diffraction (XRD) measurements of n-C x H (2x+1) OSO 3Li (x= 12, 14, 16, 18, and 20) crystals were performed as a function of temperature. In addition, σ, DSC, and XRD observations of n-C x H (2x+1) OSO 3Na and n-C x H (2x+1) OSO 3K (x= 12, 14, 16, 18, and 20) crystals were carried out for comparison. DSC results of the salts revealed several solid-solid phase transitions with large entropy changes (ΔS). For n-C 18 H 37 OSO 3Li and n-C 20 H 41 OSO 3Li salts, each melting point produced a small ΔS mp value compared with the total entropy change in the solid phases (ΔS tr1+ΔS tr2). Additionally, Li + ion diffusion was detected in the highest temperature solid phases. For K salts, larger σ values were detected for potassium alkylsulfates compared with those reported for alkyl carboxylate. 7Li NMR spectra of n-C 18 H 37 OSO 3Li crystals recorded in the low-temperature phase showed large asymmetry parameters, suggesting the Li + ions are localized at asymmetric sites in the crystals.

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Authors and Affiliations

  1. Graduate School of Nanobioscience, Yokohama City University, Kanazawa-ku, Yokohama, 236-0027, Japan

    Satoru Hirakawa & Hisashi Honda

  2. International College of Arts and Sciences, Yokohama City University, Kanazawa-ku, Yokohama, 236-0027, Japan

    Yoshiaki Morimoto & Hisashi Honda

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  1. Satoru Hirakawa
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  2. Yoshiaki Morimoto
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  3. Hisashi Honda
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Correspondence to Hisashi Honda.

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Proceedings of the 5th Joint International Conference on Hyperfine Interactions and International Symposium on Nuclear Quadrupole Interactions (HFI/NQI 2014) Canberra, Australia, 21–26 September 2014

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Hirakawa, S., Morimoto, Y. & Honda, H. Electrical conductivity, differential scanning calorimetry, X-ray diffraction, and 7Li nuclear magnetic resonance studies of n-C x H(2x+1)OSO3Li (x = 12, 14, 16, 18, and 20). Hyperfine Interact 230, 101–113 (2015). https://doi.org/10.1007/s10751-014-1087-7

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