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Tin-doped spinel-related oxides of composition M3O4 (M = Mn, Fe, Co)

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Abstract

Tin-doped compounds of spinel-related M3O4 (M = Fe, Mn, Co) have been studied by 119Sn and 57Fe Mössbauer spectroscopy in the temperature range of 20–600 K. The 119Sn Mössbauer spectra recorded down to 20 K from the non-iron-containing compounds of Co3O4 and Mn3O4 contained only doublets showing no transfer of magnetic properties from cobalt or manganese to the dopant tin ions. In contrast, the tin-doped-(FeCo)3O4 and (FeMn)3O4 gave 119Sn and 57Fe Mössbauer spectra, which showed magnetic hyperfine interactions. The Curie temperature has been estimated for the former sample.

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Correspondence to Orn Helgason.

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Helgason, O., Berry, F.J., Moyo, T. et al. Tin-doped spinel-related oxides of composition M3O4 (M = Mn, Fe, Co). Hyperfine Interact 168, 1165–1169 (2006). https://doi.org/10.1007/s10751-006-9417-z

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  • DOI: https://doi.org/10.1007/s10751-006-9417-z

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